2021 Vol. 40, No. 2

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CONTENTS
2021, 40(2)
Abstract:
Material field structure of ore-forming elements and deep prospecting potential of Xitieshan lead-zinc deposit, Qinghai Province
Wei Junhao, Li Peng, Li Yibang, Chen Dingjie, Wang Haifeng, Zhong Yongsheng, Feng Zhixing
2021, 40(2): 1-12. doi: 10.19509/j.cnki.dzkq.2021.0203
Abstract:
The Xitieshan lead-zinc deposit in Qaidam, Qinghai Province, is a large-scale SEDEX deposit in China. The host rocks are mainly marble and schist, the marble-style ore-bodies mainly exist in the shallow part and the schist-style ore-bodies mainly exist in the deep part. This paper systematically describes the spatial symbiosis relationship between lead-zinc ore-body and pyrite in different ore types and the three-dimensional spatial change rule of ore-body spatial shape. The material field structure and change trend of Pb, Zn, Ag, Au and other ore-forming elements in the mining area are systematically analyzed by the local singularity analysis method and correlation analysis method. Both analysis methods show different structural characteristics of the material field of elements, that is, Pb, Zn and Au are still obviously enriched to the depth along the side direction of the ore-body as a whole, and are not affected by marble. In the schist, the concentration of elements is still very strong, and Ag is obviously discontinuous in the mineralization space from the shallow to the deep. The element zoning in the horizontal direction of Xitieshan lead-zinc mine is Mn-Fe-S-Ag-Pb-Zn-S-Au from the far (hydrothermal center) to the near, and Mn-S-Ag-Pb-Zn-S-Au from the top to the bottom in the vertical direction. At the same time, we systematically study the change rule of element enrichment structure in the ore forming field, analyze and discuss the prospecting potential in the deep part of Xitieshan.
Research advances on rare metal pegmatite deposits
Ran Zilong, Li Yanjun
2021, 40(2): 13-23. doi: 10.19509/j.cnki.dzkq.2021.0018
Abstract:
The pegmatite deposit is one of the most important types of rare metal deposits in the world, and it is also one of the most popular interests in the international deposit research.Significant advances have been made in the latest decades, including the classification, source of ore-forming fluids and materials, pegmatite diagenesis mode and enrichment mechanism of rare metals.Ore-related pegmatites have closely temporal-spatial relationship with parental magmatism in general.However, some pegmatites do not show this relative genetic relationship.Studies indicate that the ore-forming melts/fluids of rare-metal pegmatite deposits have properties such as low viscosity, rich water, high dispersibility, and rich alkali, leading to extreme enrichment of elements such as P, F, and B in pegmatite, which migrates and enriches together with rare metals in various complexes or compounds.Li-Cs-Ta type (LCT) pegmatites are closely related to S-type granites.The ore-forming materials are mainly originated from marine sediments like black shale, whereas Nb-Y-F type (NYF) pegmatites are generally associated with A-type granites, which are all derived from the same magmatism.Granitic magma fractional crystallisation and partial melting of crustal or mantle-derived rocks are the two significant formation modes of pegmatites.Meanwhile, three enrichment mechanisms, including fluid immiscibility, highly crystalline differentiation of the flux-rich granite slurry and hydrothermal metasomatism, are widely used to interpret the formation of rare metal pegmatite deposits.
Cenozoic stratigraphic correlation and the lower limit of Quaternary in Guanzhong Basin
Song Yougui, Lan Minwen, Liu Huifang, Zhang Maosheng, Fu Xiaofen, Ning Qiangqiang
2021, 40(2): 24-35. doi: 10.19509/j.cnki.dzkq.2021.0204
Abstract:
Thick Cenozoic sediments in Guanzhong Basin provide excellent geological records for the study of the regional tectonics, sediment environment evolution and paleoclimate change.However, there are still controversies about the Cenozoic stratigraphic division and the lower boundary of Quaternary in Guanzhou Basin.Based on paleomagnetism and paleontology strata from drilling cores and outcrop sections, we reappraise and reestablish the Cenozoic strata framework in Guanzhong Basin.According to fluvial-lacustrine deposits and eolian red clay-loess sequences, the authors discuss the lower limit of Quaternary in Guanzhong Basin. Evidence from lithology, magnetostratigraphy, biostratigraphy and climate change supporting the lower limit of Quaternary strata should be confined to the boundary of "Yellow Sanmen" and "Green Sanmen" in the traditional Sanmen Formation or the boundary of eolian loess and red clay sediments around M/G boundary, and the paleomagnetic age is 2.6 Ma.Based on palaeomagnetic data of drilling cores, outcrops and previous literature, we revise the Cenozoic chronostratigraphic chart in Guanzhong Basin and amend or reallocate the ages of different strata from Eocene to Holocene.We propose that Neogene and Quaternary deposits in the Guanzhong Basin can be generally classified into two sets of different genesis sediments e.g.eolian and fluvial-lacustrine sequences.The eolian deposits can be extended to the Miocene period, which is older than previous conventional knowledge, and this Miocene eolian red clay sequences can be named as Duangjiapo Formation.This study is helpful to understand the formation and evolution of the sedimentary environment, paleoclimatic change, basin resource exploitation and geological engineering construction in Guanzhong Basin.
Experimental study about the gas slip flow in Longmaxi shales from the southern Sichuan Basin
Hu Degao, Yang Feng, Shu Zhiguo, Zheng Aiwei, Zheng He, Lü Bin
2021, 40(2): 36-41. doi: 10.19509/j.cnki.dzkq.2021.0202
Abstract:
In order to clarify the gas slip flow effect and its influencing mechanism of shale gas reservoirs, low-temperature nitrogen adsorption measurements were performed on the Silurian Longmaxi Formation shales from the Sichuan Basin. Pore structure characteristics of shales were described based on nitrogen adsorption-desorption isotherms. Non-steady state gas flow experiments on gas shales were carried out to obtain the apparent permeability coefficients of helium and nitrogen. The effects of pore pressure, gas types, confining pressure on gas slippage were discussed. Results show that gas slippage cannot be neglected when the pore pressure is less than 2.5 MPa. The Klinkenberg corrected permeability coefficients of shales are gas-dependent due to the "molecular sieving effect". The Klinkenberg corrected permeability of helium on shales is larger than that of using nitrogen. Gas slippage factors are also related to gas types. Helium slippage factor of shales is about 1.7 times of nitrogen slippage factor. The effective transport pore diameter of helium on shales with the confining pressure being 10-40 MPa ranges from 113 to 166 nm, while that of nitrogen is between 66 and 99 nm. These values are significantly larger than that derived from low-temperature nitrogen adsorption. A power function is utilized to fit the gas slippage factor and permeability of shales and can be used to predict gas flow in shales.
Tectonic evolution and depositional response in southern continental marginal basins of South China Sea during period of rift-drift-foreland: A case study from the Liyue Basin
Pei Jianxiang, Zhang Cheng, Wang Yahui, Wang Kang, Liu Juan, Wang Shaokai
2021, 40(2): 42-53. doi: 10.19509/j.cnki.dzkq.2021.0205
Abstract:
Based on the analysis of tectonics-stratigraphy-sedimentology in Liyue Basin, this paper finds out the characteristics of tectonic evolution and sedimentary fillings, reveals the genetic relationship between the basin evolution and the spreading of the South China Sea (SCS), and provides the reference for the study on the marginal sea evolution of the SCS.The Cenozoic tectonic-sedimentary evolution of the Liyue Basin could be divided into three distinct stages: the first stage characterized by continental marginal rifting and littoral-neritic clastic sedimentation from Paleocene to Early Oligocene, the second stage characterized by detaching-drifting and neritic carbonate sedimentation from Late Oligocene to Early Miocene, and the third stage featured with peripheral foreland flexure subsidence and regional differential sedimentation since Middle Miocene.In the first stage from Paleocene to Early Oligocene, the southeastward subduction of the Proto-South China Sea (PSCS) resulted in the passive rifting of the ancient South China Plate under the action of horizontal extension, and then the formation of the Liyue Rifting Basin.During this period dominated by the littoral-neritic depositional environment from Paleocene to Early Oligocene, controlled by detrital sediments supply and the PSCS action, a series of relatively large-scale braided river deltas developed in the northwestern basin, however, few small-scale fan deltas developed on the edge of the isolated uplifts in the eastern and southern basin adjacent to the PSCS.In the second stage from Late Oligocene to Early Miocene, accompanying with the PSCS continuous subduciton and the SCS initialization and spreading, the Liyue Basin located on the Liyue-Balawan Plate detached from the South China ancient continent, and then southwards drifted with slow subsidence and weak faulting.During this period dominated by the neritic- bathyal depositional environment from Late Oligocene-Early Miocene, due to the scarcely detrital sediment supply, large-scale carbonate platforms and reefs developed in the northern basin, while the bathyal environment was generally founded in the south.In the third stage since Middle Miocene, the process that the SCS spreading had being ceased and the Liyue-Balawan block was subducting towards Philippine island arc, led to the beginning of the evolution of the foreland basin in the Liyue Basin, characterized by asymmetric flexure subsidence, increasing water depth, and enhanced fault activity.During this period dominated by the bathyal- neritic depositional environment, it is the predominant feature that the carbonate platforms and reefs and deepwater gravity flow deposits have respectively being developed in the north and partial south of the Liyue Basin.It could be concluded that the tectonic-sedimentary evolution in Liyue Basin was closely related to the subduction-extinction of the PSCS and the spreading-closure of the SCS.
Main controlling factors and development model of the Miocene marine source rocks in Yinggehai Basin
Xu Jianyong, Zhao Niubin, Xu Shikun, Zhao Xinwei
2021, 40(2): 54-63. doi: 10.19509/j.cnki.dzkq.2021.0206
Abstract:
The Miocene marine source rock is the main oil and gas supplier of the Yinggehai Basin and the typical representative of the Cenozoic marine source rocks in China.Based on comprehensive analysis of geological, geochemical and paleontological data and the study of the geochemical characteristics of the source rocks, the paper discusses the main controlling factors and establishes models of the development of the Miocene marine source rocks in Yinggehai Basin.The results show that medium-good Miocene marine source rocks are developed with strong lateral and vertical heterogeneity in Yinggehai Basin.And the Miocene marine source rocks in Yinggehai Basin are influenced by paleoclimate, paleoproductivity, water medium conditions, sedimentation rate and sea level changes.Two models of the type of marine terrestrial source represented by Meishan Formation and Sanya Formation in Yingdong slope belt and the type of marine endogenous type represented by Meishan Formation in Dongfang area and Ledong area are developed, in contrast, the latter hydrocarbon generation conditions are more excellent.
Diagenetic densification of Chang 8 sandstone reservoirs and its relationship with hydrocarbon accumulation in Tiebiancheng area, Jiyuan Oilfield, Ordos Basin
Kang Yu, Chen Gang, Zhang Weigang, Huang Junping, Xia Xiaoyu, Huo Jianwei
2021, 40(2): 64-75. doi: 10.19509/j.cnki.dzkq.2021.0207
Abstract:
Based on multiple testing data from the casting slice, cathodoluminescence, scanning electron microscopy, X-ray diffraction, HPMI, reservoir physical property, and fluid inclusion thermometry, systematic research was conducted to investigate the petrologic features, reservoir properties, diagenetic porosity evolution, and temporal relations between the densification and oil charging process of the Chang 8 sandstone reservoirs of the Upper Triassic Yanchang Formation in Tiebiancheng area of Jiyuan Oilfield, Ordos Basin. The results show that the Chang 8 reservoirs in the study area are mainly composed of fine-grained lithic feldspar sandstones with low maturity of composition and texture, featuring unconventional tight reservoirs with an average porosity of 7.34% and permeability of 0.112×10-3μm2, which generally reach the middle diagenetic stage A. The diagenetic porosity evolution of the Chang 8 reservoirs mainly experienced three stages: porosity reduction by compaction and cementation in early diagenetic stage A-B, porosity increase by dissolution and reduction by cementation in middle diagenetic stage A1, and porosity reduction to densification by cementation in middle diagenetic stage A2 to B1. Until the end of the Early Cretaceous, all the occurred compaction and cementation made the reservoir porosity decrements approach 21.14% and 14%, respectively, while the porosity increment by dissolution was only about 1.76%. At the beginning of two episodic large-scale oil charging events that occurred at 125 and 105 Ma during the middle to late period of the Early Cretaceous, the porosity of the Chang 8 sandstone reservoirs decreased to 7.82% under the influence of late cementation. It became a typical ultra-low porosity and ultra-low permeability tight sandstone reservoir, thus most likely indicating that the densification of the Chang 8 reservoirs occurred earlier than the hydrocarbon accumulation in this study.
Research on hydrothermal petroleum and its organic matter
You Jiyuan, Liu Yiqun, Li Yijun, Zhou Dingwu, Li Zhexuan, Yang Yiyao
2021, 40(2): 76-87. doi: 10.19509/j.cnki.dzkq.2021.0208
Abstract:
The causes of oil and natural gas formation have long been controversial about organic and inorganic causes. In recent years, the discovery of hydrothermal genesis in different oceans around the world has further provided new thinking for the exploration of oil and gas genesis. On the basis of reviewing the basic theory of organic oil-producing hypothesis, inorganic oil-producing hypothesis and the dispute between the two, authors focused on the characteristics and research progress of hydrothermally derived petroleum and its organic matter. Then combined with the study of hydrothermal jet deposition in the source rocks of Santanghu Basin and Ordos Basin, the following important insights were obtained: ①The organic matter derived from hydrothermal oil is derived from terrestrial higher plants and lower ocean organisms, the latter being thermophilic, poisonous, and high temperature resistant organisms living around hydrothermal vents. ②Hydrothermal oil does not need to be buried to continuously provide heat, and submarine hydrothermal activities provide material and heat for it. ③In the process of physicochemical interaction between organic matter and deep-source thermal material fluid, organic matter is "instantaneously" (short time) pyrolyzed into oil and partially converted into petroleum-like products. The study of hydrothermally oil and its organic matter can not only deepen people's understanding of the causes of oil and gas, but also have great significance for the exploration and development of unconventional oil.
Sedimentary characteristics and controlling factors of the Ba 66 fan in Bayindulan Sag
Yue Jiaheng, Huang Chuanyan, Cao Lanzhu, Wang Hongxia, Zheng Ronghua, Wu Jianping, Xiang Xin, Liu Hui
2021, 40(2): 88-98. doi: 10.19509/j.cnki.dzkq.2021.0209
Abstract:
Based on the data of core, thin sections, logging and 3D seismic, the sedimentary characteristics, controlling factors and sedimentary model of Ba 66 fan are studied systematically to determine the types and characteristics of the fan.The study shows that Ba 66 fan is a fan delta rapidly deposited by torrent after short-distance transport, and the hydrodynamic force of the fan is mainly driven by gravity.The extension distance of the fan is short on the plane.The fan is lobate as a whole and has the facies feature of " large plain, small front".The main characteristics of the fan are as follows: the maturity of the rock is low, and the disorderly massive glutenite is the typical lithofacies; The fan has the logging characteristics of high amplitude, odonation and abrupt contact.The fan bodies can be divided into plain, front (including proximal, middle and distal), pre-delta or lacustrine facies according to the characteristics of seismic facies, such as random hills, front accumulations, and sheets.The analysis shows that the development of fan delta in the slope belt is mainly controlled by the background environment of the depression and paleogeomorphology: ①The background conditions such as source of uplift area, narrow lake basin (no gentle slope) and wide lake surface ensure the supply of source and short-distance transportation conditions for the formation of fan delta; ②Grooves provide space for sand body development. The slope break changes the slope, divides the accommodation space, and controls the distribution of facies, and the low bulge under the water affects the plane distribution of the fan.Finally, the deposition model of Ba 66 fan is constructed.
Stability evaluation of basalt platform in Zhejiang Province: A case study of Diyayuan landslide in Shengzhou City
Zhang Yu, Xu Xinghua, Lu Yanping, Feng Hangjian, Tang Xiaoming, Yin Kunlong
2021, 40(2): 99-110. doi: 10.19509/j.cnki.dzkq.2021.0210
Abstract:
Basalt platform is a special type of landslide, however, its stability has received little attention before.This paper takes the Diyayuan landslide in Shengzhou city as the research object, and uses the method of three-dimensional numerical simulation to analyze and evaluate its stability.Then the rainfall recurrence period was determined based on the P-Ⅲ distribution curve, and the geotechnical software MIDAS was used to simulate the landslide stability and the 3D motion simulation platform DAN3D software was used to calculate the landslide impact range; finally, sensitivity analysis was carried out for the stability factors affecting the landslide The results show that different rainfall intensity has great influence on the stability of Diyayuan landslide.At this time, the stability coefficient of landslide is 0.946, the failure probability is 65.25%, and the maximum impact range increases by 36.83%; the angle of internal friction and rainfall are the main factors affecting the stability of Diyayuan landslide The analysis shows that the stability of basalt platform landslide is obviously correlated with the development of diatomite slip zone, joint and fissure surface, and the hysteresis of rainfall infiltration.The results of this paper can provide reference for the stability evaluation of similar landslide.
Joint bending stiffness and internal force calculation of assembled pipe jacking
Feng Xin, Zhang Peng, Ma Baosong, Zhou Hao
2021, 40(2): 111-117. doi: 10.19509/j.cnki.dzkq.2021.0019
Abstract:
With the increasing of the cross section area of pipe jacking, the transportation problem of pipe is becoming more and more serious.And the assembled pipe jacking technology can effectively solve this problem.Based on the existing assembled structural joints, the connection method of the assembled pipe transverse joint is put forward.Then, the bending stiffness model of transverse joint in bolt assembled pipe is established, and the structural calculation method of assembled pipe is put forward with reference to the beam-spring model of shield segment.The results of internal force show that the internal force distribution of assembled and integral pipe is basically the same; the bending moment of the side wall of the assembled pipe is less than that of the integral pipe, while the bending moment at the top and bottom is greater than that of the integral pipe and there is no sharp change in their internal forces; in terms of internal force distribution and value, the assembled pipe is available.
Experimental study on solid-free anti-sloughing drilling fluid suitable for deep core drilling projects
Zhu Xuming, Wu Xiaoming, Zheng Wenlong, Jiang Ziwei, Dina Mulati
2021, 40(2): 118-124. doi: 10.19509/j.cnki.dzkq.2021.0211
Abstract:
To deal with the problems of wellbore collapse, mud making and mud lining in drilling strings, a solid-free anti-collapse drilling fluid with polyvinyl alcohol as inhibitor was developed. The inhibition effect of commonly used inhibitors was studied by shale hot rolling recovery test, critical addition of bentonite test, and mud boulder soaking test. The types and dosage of viscosifiers and water loss reducers were determined by compatibility test, and the influence of different pollutants on the comprehensive properties of the formulated drilling fluid were compared. Experimental results showed that compared with the conventional inorganic salt such as NaCl and KCl, polyvinyl alcohol had a stronger inhibition effect which was positively correlated with polymerization degree. XC, SPNH and FT-1 could be used as viscosifier and water loss reducers to prepare the drilling fluid, respectively. The performance of formula drilling fluid under the pollution of 35%NaCl, 4% CaCl2 and 12% calcium bentonite can be stable in the temperature of 110 ℃, indicating that the prepared drilling fluid can be used in the strong mud making strata, fractured strata, salt bed and other complex strata in the depth of 3 000 m.
Vertical soil pressure calculation model of rectangular box jacking considering grouting effect
Zhou Hao, Zhou Qianmiao, Tan Lixin, Zhang Peng, Ma Baosong
2021, 40(2): 125-130. doi: 10.19509/j.cnki.dzkq.2021.0201
Abstract:
In view of the current situation that there are few studies on the calculation model of the vertical soil pressure on the rectangular box jacking, the calculation model of the soil pressure on the rectangular box jacking considering the grouting effect is established based on the Terzaghi soil pressure calculation theory and combined with the characteristics of the rectangular box jacking engineering, and an improved calculation formula of the soil pressure on the rectangular box jacking is proposed.Based on the real-time monitoring data of vertical soil pressure in a rectangular box jacking project in Suzhou, the variation rules were explored and the accuracy of the calculation formula was verified.The results show that the shear zone in the soil is generated from both sides of the pipe wall and develops in the vertical direction, and can penetrate to the surface; under the critical state, the frictional angle of the shear zone is fully developed, and the friction coefficient of the shear zone is calculated by the critical internal friction angle and its sinusoidal value; under different grouting pressures, "active soil arch" and "passive soil arch" may appear above the pipeline.The comparative analysis between the calculated value and the measured value shows that the improved calculation method can better envelop the vertical earth pressure range of the rectangular box pipe.
Synthesis of thioarsenate compounds and their occurrence characteristics in groundwater: A case study of Datong Basin
Zhao Xin, Sun Shutang, Xie Xianjun
2021, 40(2): 131-137. doi: 10.19509/j.cnki.dzkq.2021.0141
Abstract:
As an important occurrence form of arsenic in sulfur-rich groundwater, thioarsenate plays a very important role in its migration and transformation. However, the standard synthesis method of thioarsenate is complex and the occurrence characteristics and influencing factors in low temperature groundwater are rarely reported. In this paper, firstly, the synthesis method of thioarsenate reference material was improved, the standard reference material of thioarsenate was synthesized by hydrothermal method, and the analytical method of thioarsenate based on HPLC-ICPMS was established. The detection limit of this method was 0.01 μg/L. The effects of different preservation conditions on the stability of thioarsenate compounds were discussed. It was found that quick freezing of dry ice at -20℃ was the best way to keep the stability of thioarsenate samples in groundwater. The above method was used to analyze thioarsenate in groundwater in Datong Basin. The results showed that thioarsenate was detected in 40% of the water samples, and the highest concentrate was 209.90 μg/L. The weak alkaline reduction condition is beneficial to the occurrence of thioarsenate, and the sulfide concentration plays an important role in controlling the formation of thioarsenate. The in-depth study of thioarsenate in groundwater is helpful to reveal the law of migration and transformation of arsenic in sulfur-rich groundwater and is of great significance to enrich the genetic theory of high-arsenic groundwater.
Pollution assessment and source analysis of heavy metals in agricultural soil around Zijiang River estuary
Liu Wenhui, Ma Teng, Li Junqi, Wu Xiancang, Yu Haotian
2021, 40(2): 138-146. doi: 10.19509/j.cnki.dzkq.2021.0212
Abstract:
Zijiang River is the second largest tributary of Dongting Lake. The developed antimony (Sb) mine mining and smelting industry in the upper and middle reaches of Zijiang River bring serious heavy metal pollution risks to the lower reaches of Zijiang River and the Dongting Lake. Taking Zijiang river Estuary as the study area, 132 agriculture soil samples and 7 water samples of Zijiang River were collected, and then multi-methods of contamination assessment, spatial analysis and multivariate statistical analysis methods were comprehensively used to evaluate pollution status and sources of the heavy metal this site. The results showed that the average concentration of heavy metals in farmland soil in the study area was Zn>Cr>Ni>Pb>Cu>As>Sb>Cd, and the average concentration of heavy metals in upland fields was higher than that in paddy fields except for Pb. Sb, As and Cd were the main pollution elements. Besides, Sb reached the level of medium pollution and medium ecological risk, and the site was generally at a slight-medium ecological risk level. The Sb concentration of Zijiang river was relatively high, with an average of 10.51μg/L. Sb mainly came from the antimony mining industry in the upper and middle reaches, and was controlled by human activities such as high antimony concentration surface water irrigation, landfills and coal burning; Cd mainly came from human activities such as pesticides, fertilizers, household garbage and urban wastewater; Cr was mainly derived from soil parent material, while Cu, Zn, As, Ni, Pb were controlled by soil parent material and human activities.
Seasonal variations and influencing factors of dissolved organic carbon in pore water from the Dajiuhu peatland in Shennongjia
Zhang Zhiqi, Zhang Yiming, Huang Xianyu, Du Hua, Mo Jiayong, Qu Wanguo, Pi Ting
2021, 40(2): 147-155. doi: 10.19509/j.cnki.dzkq.2021.0213
Abstract:
Subtropical peatlands are an important component of the global peatlands and play essential roles in water regulation, carbon storage, and biodiversity.These peatlands are being subjected to the influences of global climate changes and human disturbances.Thus, it is vital to explore how the carbon dynamics of these subtropical peatlands respond to climate changes and human activities.Dissolved organic carbon (DOC) exits as labile carbon pools that are susceptive to external environmental disturbance.Under both impacts of climate change and human activities, DOC may be lost from peatlands through degradation or horizontal migration, potentially threatening the carbon storage function of peatlands.However, knowledge about the response of DOC to seasonal environmental changes in subtropical peatlands remains poor.In this study, the seasonal variations of DOC extracted from the peat porewater along a depth profile were investigated in the Dajiuhu peatland, a typical subalpine peatland in the subtropical China.Both DOC concentration and its ultra-visible (UV-Vis) spectral indices show apparently seasonal fluctuations, while some indices also display differences among depths.Correlation analysis reveals that the DOC concentration and UV-Vis indices correlate closely with the porewater conductivity and the concentration of ammoniacal nitrogen.This study demonstrates that seasonal variation is an essential phenomenon of the carbon dynamics in the Chinese subtropical peatlands.It is urgent to quantitatively evaluate how the seasonal changes affect the carbon uptake capacity and ecosystem services of the Chinese subtropical peatlands.
Analogue experiments for the Shuangyushi area in the north western Sichuan Foreland Basin and their implications
Zhang Lianjin, Huang Jiaqiang, Luo Qiang, He Yu, Yu Hao, Yang Rongjun, Liang Xiao, Zhou Zheng, Deng Bin
2021, 40(2): 156-166. doi: 10.19509/j.cnki.dzkq.2021.0214
Abstract:
In this study, we conducted three sets of analouge experiments, i.e., the pilot experiment with homogeneous quartz sand with frontal ramp, scaled experiments with embedded layer of silicone and/or frontal ramp, for the Shuangyushi area in the north western Sichuan Foreland Basin.It suggests that the north western Sichuan Foreland Basin is dominated with two-layer style of deformation, in particular, with pop-up in deep strata which is controlled by the basal decollement and frontal ramp.It should be noted that the frontal ramp has significant influence on the undistributed deformation and related fault-style occurred at the overlying sequences, which are in favor of formation for a pathway system between Lower Cambrian Qiongzhushi Formation and Mesozoic carbonate/dolomite reservoir.In contrast to duplex as a result of multistage deformation in the thrust-and-fold-belt, the north western Sichuan Foreland Basin is characterized with gentle deformation, as a result of forelandward propagation deformation in Cenozoic, and thus with a better quality of hydrocarbon preservation.Analogue experiments have been a powerful and indispensable tool to help us understand the thrust-fold-belt and foreland basin, as well as their hydrocarbon accumulation, from nature to models.
Analysis method for in-situ trace element determination of magnetite by LA-ICP-MS
Luan Yan, Sun Xiaohui, Liu Minwu, He Ke
2021, 40(2): 167-175. doi: 10.19509/j.cnki.dzkq.2021.0215
Abstract:
Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) method is characterized by in-situ, high space resolution and high sensitivity. Therefore, the study of LA-ICP-MS in-situ trace elements analysis in magnetite has made a rapid progress and it is widely used in geological field in recent years. An analytical method for the trace elements determination of magnetite by LA-ICP-MS using Agilent 7700X inductively coupled plasma-mass spectrometry (ICP-MS) and Photo Machines Analyte Excite 193nm laser ablation was established at the laboratory of mineralization and dynamics, Chang′an University. This method adopts multiple external standards (BIR-1G, BHVO-2G, BCR-2G and GSE-1G) as calibration standards without an internal standard. Trace element compositions of the glass standard material NIST 612 and natural magmatic magnetite BC 28 were determined by the established method to evaluate its reliability. The results show that the relative standard deviation (RSD, N=30) of trace elements in NIST 612 ranges from 1.31% to 6.33%. Compared with the recommended values and the previous reference values obtained by LA-ICP-MS, the relative error of most elements in NIST 612 is smaller than 10%. The RSD (N=30) of most elements in BC 28 is lower than 10%, and the relative error of 11 important trace elements in BC 28 is smaller than 10% compared with the reported values by LA-ICP-MS. The above results show that in-situ trace element determination of magnetite can be carried out by using the method established in this study. The analysis data is accurate and reliable, and it has a great application potential.
Indication of elements geochemical characteristics of stream sediment to evaluation of regional denudation degree: A case study of the Dachang gold ore field in east Kunlun, Qinghai Province
Luan Yan, Sun Xiaohui, Liu Minwu
2021, 40(2): 176-185, 210. doi: 10.19509/j.cnki.dzkq.2021.0216
Abstract:
Using the elements geochemical characteristics in stream sediments survey, have the advantages of yofast, effective and low cost in different scale evaluation of denudation degree in Dachang gold ore field in east Kunlun, Qinghai Province.It also provides strong support for evaluating the regional metallogenic potential.We take a case study of the data of 1∶50 000 stream sediments survey in the Dachang gold ore field for processing and analysis, which is based on the theory of hydrothermal percolation halo banding, and the spatial zoning of the primary halo and the structural similarity with secondary anomalies of gold deposits in the area.Besides, we build the element association and elemental banding sequence with common features between the common mineralization element dispersed train and the primary halo.Three methods, including the elemental ratio method, the triangular graphic method and the elemental banding sequence method are used to set up the evaluation parameters of regional denudation degree.Finally, combined with the characteristics of the geology and mineral resources in the field, the denudation degree of 7 anomalous areas in the Dachang gold ore field and surrounding areas is evaluated, and it is believed that the denudation degree of Zalayibei, Geyonggongma, Dongda Hariwula, and Zhaodaebei areas is higher; the degree of denudation in the Dexiran area is medium; the degree of denudation in the Zarayi-Dachang and Zhaodaenan areas is lower.Meanwhile, it is believed that the use of the elemental geochemical characteristics of stream sediments and the combined use of multiple evaluation indicators can effectively and quickly carry out a moderate evaluation of the degree of regional denudation, provide support for the evaluation of mineralization potential, and have very important indications for prospecting and exploration.
Visualization of geological spatial distributing information in regional geochemical exploration data based on t-SNE algorithm: A case study of SW England
Chen Junlin, Yan Yan, Peng Runmin
2021, 40(2): 186-196. doi: 10.19509/j.cnki.dzkq.2021.0217
Abstract:
Regional geochemical prospecting data contains a lot of geological information. Extracting the geological spatial distributing information contained in these data is of great significance for regional geological research and mineral prospecting. Regional geochemical data usually includes dozens of elements, which belong to high-dimensional data. Geological spatial distributing information hidden in these high-dimensional data cannot be observed directly from the data. In order to solve this problem, we constructed a dimensionality reduction and visualization model of high-dimensional regional geochemical exploration data based on the t-Distributed Stochastic Neighbor Embedding (t-SNE) algorithm. t-SNE algorithm is a nonlinear dimensionality reduction method, which is especially suitable for dimensionality reduction and visualization of high-dimensional data. Select the elements that are sufficiently stable in lithology identification. Reduce the dimension of high-dimensional geochemical exploration data to 1D, 2D or 3D through the t-SNE algorithm, because the low-dimensional data less than 3D can be observed by human eyes easily. Express the output variables of dimension reduction algorithm as raster files, and visualize them by RGB color mixing and other methods, thus the spatial distribution information of geological bodies hidden in high-dimensional geochemical exploration data can be observed directly. The regional geochemical exploration data of stream sediments in a region of southwest England are taken as an example to evaluate the t-SNE algorithm in visualization of high-dimensional geochemical exploration data. The case study shows that: (1) The high-dimensional geochemical exploration data visualization results through t-SNE algorithm can represent the spatial distribution of geological bodies in the study area very well; (2) The visualization results are tightly related to two parameters: target dimension and perplexity of the t-SNE algorithm. The higher the target dimension was be reduced in the t-SNE algorithm, the more detailed the geological spatial information displayed. (3) The results of dimension reduction and visualization of geochemical exploration data based on the t-SNE algorithm are better than those based on principal component analysis (PCA). The research in this paper shows that the high-dimensional geochemical exploration data visualization method based on the t-SNE algorithm can display the spatial distribution information of geological bodies, which has certain guiding significance for inferring the spatial distribution of geological bodies.
Identification of Milankovich′s cycle and establishment of astronomical ruler: A case study from the first section of the Sangonghe Formation of Well Mo 21 in Mosuowan area
Xu Jian, Deleqiati Jianatayi
2021, 40(2): 197-207. doi: 10.19509/j.cnki.dzkq.2021.0218
Abstract:
According to Milankovich′s theory, astronomical forces influence the Earth′s climate change, and the sedimentary process records this change. According to Milankovich′s theory, cycles can be identified and separated, which is a powerful complement to traditional sequence stratigraphy. It has a high-level time and month implementation, which can realize high-resolution periodic identification and the establishment of high-precision isochronous stratigraphic framework. The Mosuowan area is one of the favorable areas for oil and gas exploration in the Junggar Basin. Among them, the first section of the Sangonghe Formation has developed effective and large-scale tight gas reservoirs. Using natural gamma log data, through frequency spectrum analysis and other methods, Milankovich signal identification and period division were performed on the target layer in the study area. Based on the 405 ka periodic filtering curve, a floating astronomical scale based on the geological age at the bottom boundary of the Sangonghe Formation is established.Studies have shown that there is a Milankovich′s cycle in the first section of the Sangonghe Formation. The short-term eccentricity 125 ka period controls the cycle with a thickness of approximately 29.73 m; the slope 54 ka period controls the cycle with a thickness of approximately 12.47 m; the precession 24 ka cycle controls the thickness with a cycle of approximately 5.62 m. The geological age of the first section of the Sangonghe Formation is about 189.951-190.800 Ma. A total of seven short-term base-level cycles have been identified, and seven fifth-order sequences have been divided. "Small-increasing-continuously decreasing-continuously increasing" trend, but the overall change is not large. There are three types of short-term datum cycle: B1, B2, and C1.This article details the Milankovich′s cycle identification process and the establishment of astronomical scales, providing a reference and basis for the high-resolution cycle division of the study area.
2021, 40(2): 208-210. doi: 10.19509/j.cnki.dzkq.2021.0219
Abstract: