渤南洼陷不同来源原油分布规律及主要控制因素

韩金虎; 郭小文; 王学军; 王永诗; 何生

doi:10.19509/j.cnki.dzkq.2020.0607

渤南洼陷不同来源原油分布规律及主要控制因素

doi: 10.19509/j.cnki.dzkq.2020.0607

基金项目:

"十三五"国家科技重大专项 2016ZX05006-003-001

详细信息

作者简介:
韩金虎(1995-), 男, 现正攻读地质工程专业硕士学位, 主要从事油气地球化学研究工作。E-mail:hjh1027@126.com

通讯作者:
郭小文(1980-), 男, 教授, 主要从事油气地质与油气成藏机理研究。E-mail:cuggxw@163.com

中图分类号: P588.12
计量
- 文章访问数: 705
- PDF下载量: 3341
- 被引次数: 0
出版历程
- 收稿日期: 2020-02-27

Distribution rule and main controlling factors of crude oil from different sources in Bonan Sag

摘要

摘要: 为揭示渤南洼陷沙三段、沙四段烃源岩来源原油的分布规律及主要控制因素，通过族组分分离、气相色谱（GC）、气相色谱-质谱（GC-MS）等测试分析原油和烃源岩地球化学特征，进行原油成因分类，确定不同来源原油的分布规律，进而探讨影响油气分布的主要因素。研究表明，沙三段、沙四段烃源岩对原油的贡献程度不同。依据生物标志化合物指标将原油划分为Ⅰ、Ⅱ、Ⅲ 3类，其中Ⅱ类油细分为Ⅱ₁和Ⅱ₂ 2个亚类。油源对比结果表明：Ⅰ类油来源于沙三段烃源岩，主要分布在洼陷中心；Ⅱ₁类油来源于沙四段膏岩层间的泥岩，Ⅱ₂类油来源于沙四段盐层下部的泥岩，此类油主要分布在洼陷边缘部位；Ⅲ类油为混合来源，且以沙三源为主，其分布与断层的展布有关。结合洼陷地质特征分析，认为断层及沙四段上部存在的膏盐岩是影响不同来源原油分布的主要因素。
- 生物标志化合物 /
- 油源对比 /
- 原油分布 /
- 控制因素 /
- 渤南洼陷
Abstract: In order to reveal the distribution rule and main controlling factors of crude oil from the Es₃ and Es₄ source rocks in Bonan Sag, group separation, gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS) and other means were used to analyze the geochemical characteristics of crude oil and source rock, carry out the genetic classification of crude oil, determine the distribution rule of crude oil from different sources, and then explore the main factors of oil distribution.The results show that the contribution of source rocks in Es₃ and Es₄ intervals to crude oil is different.Based on the biomarker parameters, crude oil is classified into three groups (Ⅰ, Ⅱ and Ⅲ), of which group Ⅱ oil is subdivided into group Ⅱ₁ and group Ⅱ₂ oil. Oil-source correlation suggests that group Ⅰ oil originates from the Es₃ source rock; group Ⅱ₁ oil is derived from mudstone interlayer between the gypsum rock of the Es₄ interval, group Ⅱ₂ oil is from mudstone of the lower part of gypsum layer of the Es₄ interval; group Ⅲ oil is from mixed source rocks in both of the Es₃ and Es₄ intervals, mainly from Es₃ source rocks, and its distribution is related to faults.Combined with the analysis of geological features of Bonan Sag, it is considered that fault and gypsum salt rocks of the upper Es₄ interval are the main factors affecting the distribution of crude oil from different sources.
- biomarkers /
- oil-source correlation /
- oil distribution /
- controlling factors /
- Bonan Sag

HTML全文

图 1 沾化凹陷构造位置(a)及渤南洼陷构造单元图(b)

Figure 1. Structural location of Zhanhua Depression (a) and structural unit map of Bonan Sag (b)

下载: 全尺寸图片幻灯片

图 2 渤南洼陷烃源岩有机质类型(a，b)与成熟度相关图(c)

Figure 2. Plots of organic matter types (a, b) and vitrinite reflectance (c) of source rocks in Bonan Sag

下载: 全尺寸图片幻灯片

图 3 渤南洼陷烃源岩w(TOC)及HI分布直方图

Figure 3. Distribution histogram of TOC (a) and HI (b) of source rocks in Bonan Sag

下载: 全尺寸图片幻灯片

图 4 渤南洼陷沙三段、沙四段典型原油饱和烃组分气相色谱图

Figure 4. Gas chromatographic diagram of typical saturated hydrocarbon components of crude oil in the Es₃ and Es₄ intervals of Bonan Sag

下载: 全尺寸图片幻灯片

图 5 渤南洼陷沙三段、沙四段典型原油饱和烃质谱图

萜烷m/z=191;甾烷m/z=217; Ts.C₂₇ 18α-三降藿烷; Tm.C₂₇ 17α-三降藿烷; C₂₉.C₂₉藿烷; C₃₀.C₃₀藿烷; C₃₁~C₃₅.C₃₁~C₃₅升藿烷; Gam.伽马蜡烷; C₂₁ St.孕甾烷; C₂₂ St.升孕甾烷; C₂₇~C₂₉ St.C₂₇~C₂₉甾烷)

Figure 5. Saturated hydrocarbon mass spectrometry of typical crude oil in the Es₃ and Es₄ intervals of Bonan Sag

下载: 全尺寸图片幻灯片

图 6 C₂₉20S/(20S+20R)和C₂₉αββ/(ααα+αββ)相关图

Figure 6. Plot of C₂₉20S/(20S+20R) and C₂₉αββ/(ααα+αββ)

下载: 全尺寸图片幻灯片

图 7 渤南洼陷沙三段、沙四段典型烃源岩饱和烃质谱图(符号含义同图 5)

Figure 7. Saturated hydrocarbon mass spectrometry of typical source rocks in the Es₃ and Es₄ intervals of Bonan Sag

下载: 全尺寸图片幻灯片

图 8 渤南洼陷沙三段、沙四段原油及烃源岩生物标志物参数对比图

Figure 8. Comparison of crude oil and source rock biomarker parameters in the Es₃ and Es₄ intervals of Bonan Sag

下载: 全尺寸图片幻灯片

图 9 渤南洼陷不同油源井位及膏盐岩分布范围

Figure 9. Location of different oil source wells and distribution range of gypsum rocks in Bonan Sag

下载: 全尺寸图片幻灯片

图 10 渤南洼陷义171井-义160井剖面原油类型分布(剖面位置见图 1-b)

Ed.东营组；Es_1~4.沙一至四段；Es₃^s、Es₃^z、Es₃^x.沙三段上、中、下亚段

Figure 10. Distribution of crude oil types of profile Yi171-Yi160 wells in Bonan Sag

下载: 全尺寸图片幻灯片

参考文献(48)

[1]	傅家谟, 盛国英, 许家友, 等.应用生物标志化合物参数判识古沉积环境[J].地球化学, 1991, 20(1):1-12.
[2]	张成艳, 成小英, 董海良, 等.库赛湖沉积物中正构烷烃的分布特征及古环境意义[J].地质科技情报, 2015, 34(1):72-77.
[3]	倪春华, 包建平, 梁世友.渤海湾盆地渤中凹陷原油成熟度的多参数综合评价[J].石油实验地质, 2009, 31(4):399-402.
[4]	王崇敬, 张鹤, 李世宇, 等.基于分子标志物的有机质成熟度评价参数选择及其适用范围分析[J].地质科技情报, 2018, 37(4):208-217.
[5]	国朋飞, 何生, 朱书奎, 等.利用三环萜烷对比泌阳凹陷生物降解油油源[J].石油实验地质, 2015, 37(1):80-87. http://qikan.cqvip.com/Qikan/Article/Detail?id=663784740
[6]	Peters K E, Walters C C, Moldowan J M.The biomarker guide(Volume 2):Biomarkers and isotopes in petroleum exploration and earth history[M].Cambridge:University Press, 2005.
[7]	雷闯, 叶加仁, 彭明超, 等.潜江凹陷北部潜江组油气运移特征[J].地质科技情报, 2014, 33(3):133-139.
[8]	Liu G, Chen Z, Wang X, et al.Migration and accumulation of crude oils from Permian lacustrine source rocks to Triassic reservoirs in the Mahu Depression of Junggar Basin, NW China:Constraints from pyrrolic nitrogen compounds and fluid inclusion analysis[J].Organic Geochemistry, 2016, 101:82-98. doi: 10.1016/j.orggeochem.2016.08.013
[9]	白玉彬, 罗静兰, 郝孝荣, 等.鄂尔多斯盆地蟠龙油田延长组烃源岩地球化学特征[J].地质科技情报, 2013, 32(4):19-24.
[10]	Dong T, He S, Liu G, et al.Geochemistry and correlation of crude oils from reservoirs and source rocks in southern Biyang Sag, Nanxiang Basin, China[J].Organic Geochemistry, 2015, 80:18-34. doi: 10.1016/j.orggeochem.2014.12.006
[11]	费雯丽, 郭小文.库车坳陷克拉苏冲断带轻质原油地球化学特征及成因[J].地质科技情报, 2016, 35(2):185-191. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzkjqb201602036
[12]	罗家群, 蒲洪果, 李丽娟, 等.泌阳凹陷梨树凹区块油气成藏期次与成藏过程[J].地质科技情报, 2017, 36(3):118-121.
[13]	Chen Z, Wang T, Li M, et al.Biomarker geochemistry of crude oils and Lower Paleozoic source rocks in the Tarim Basin, western China:An oil-source rock correlation study[J].Marine and Petroleum Geology, 2018, 96:94-112. doi: 10.1016/j.marpetgeo.2018.05.023
[14]	XiaoH, Li M, Liu J, et al.Oil-oil and oil-source rock correlations in the Muglad Basin, Sudan and South Sudan:New insights from molecular markers analyses[J].Marine and Petroleum Geology, 2019, 103:351-365. doi: 10.1016/j.marpetgeo.2019.03.004
[15]	朱光有, 金强, 高志卫, 等.沾化凹陷复式生烃系统及其对油气成藏的控制作用[J].海洋地质与第四纪地质, 2004, 24(1):105-111.
[16]	Wang Y, Li M, Pang X, et al.Fault-fracture mesh petroleum plays in the Zhanhua Depression, Bohai Bay Basin:Part 1.Source rock characterization and quantitative assessment[J].Organic Geochemistry, 2005, 36(2):183-202. doi: 10.1016/j.orggeochem.2004.08.003
[17]	刘超, 李伟, 吴智平, 等.渤海海域渤南地区新生代断裂体系与盆地演化[J].高校地质学报, 2016, 22(2):317-326.
[18]	张枝焕, 曾艳涛, 张学才.山东沾化凹陷渤南洼陷沙四段原油的地球化学特征及油源分析[J].现代地质, 2004, 18(4):578-585.
[19]	刘士林, 李原, 郭利果, 等.渤南洼陷沙三段原油地球化学特征及油源对比[J].大庆石油地质与开发, 2006, 25(4):1-3.
[20]	单体珍.渤南洼陷古近系沙四段烃源岩特征[J].海洋地质前沿, 2012, 28(4):44-49.
[21]	朱立群, 李江海.渤南洼陷沙四下段红层原油地球化学特征及油源探讨[J].天然气地球科学, 2014, 25(增刊1):124-130. http://www.cqvip.com/QK/97226X/2014S1/84687588504849528349485051.html
[22]	王大洋.渤南洼陷沙三下亚段烃源岩地球化学特征及差异性研究[J].南京大学学报:自然科学版, 2019, 55(6):924-933.
[23]	朱光有, 金强, 张水昌, 等.陆相断陷盆地复式成烃及成藏系统研究:以济阳坳陷沾化凹陷为例[J].石油学报, 2004, 25(2):12-18.
[24]	宋国奇, 刘华, 蒋有录, 等.沾化凹陷渤南洼陷沙河街组原油成因类型及分布特征[J].石油实验地质, 2014, 36(1):33-38, 45.
[25]	Wang M, Wilkins R W T, Song G, et al.Geochemical and geological characteristics of the Es₃^L lacustrine shale in the Bonan Sag, Bohai Bay Basin, China[J].International Journal of Coal Geology, 2015, 138:16-29. doi: 10.1016/j.coal.2014.12.007
[26]	Liu H, Jiang Y, Song G, et al.Overpressure characteristics and effects on hydrocarbon distribution in the Bonan Sag, Bohai Bay Basin, China[J].Marine and Petroleum Geology, 2017, 149:811-821.
[27]	文志刚, 周东红, 宋换新, 等.渤中凹陷油气勘探潜力分析:与东营凹陷和沾化凹陷类比[J].石油天然气学报, 2009, 31(6):55-58.
[28]	孟仟祥, 房嬛, 徐永昌, 等.柴达木盆地石炭系烃源岩和煤岩生物标志物特征及其地球化学意义[J].沉积学报, 2004, 22(4):729-736.
[29]	Powell T G, Mckirdy D M.Relationship between ratio of pristane to phytane, crude oil composition and geological environment in Australia[J].Nature, 1973, 243:37-39.
[30]	Chappe B, Albrecht P, Michaelis W.Polar lipids of archaebacteria in sediments and petroleums[J].Science, 1982, 217:65-66. doi: 10.1126/science.217.4554.65
[31]	Peters K E, Moldowan J M.The biomarker guide:Interpreting molecular fossils in petroleum and ancient sediments[M].New Jersey:Prentice Hall, 1993.
[32]	Bahram A, Khaled M, Mehdi F.Oil-oil correlation, geochemical characteristics, and origin of hydrocarbons from Mansourabad Oilfield, SW Iran[J].Journal of African Earth Sciences, 2018, 147:383-392. doi: 10.1016/j.jafrearsci.2018.06.008
[33]	Philp R P, Fan P, Lewis C A, et al.Geochemical characteristics of oils from Qaidam, Shangganning and Jianghan Basins, China[J].Journal of Southeast Asian Earth Sciences, 1991, 5(3):351-358.
[34]	韩小锋, 牛海青, 卜建军, 等.甘蒙地区北山盆地群中口子盆地侏罗系烃源岩特征及评价[J].地质科技情报, 2019, 38(5):46-53.
[35]	周洁.东海盆地西湖凹陷始新统平湖组煤系烃源岩地球化学特征[D].杭州: 浙江大学, 2012.
[36]	柯友亮, 王华, 甘华军, 等.准噶尔盆地南缘芦草沟组上段油页岩有机地球化学特征及其沉积意义[J].地质科技情报, 2019, 38(3):199-207.
[37]	傅家漠, 徐芬芳, 陈德玉, 等.茂名油页岩中生物输人的生物标志化合物[J].地球化学, 1985, 14(2):99-104.
[38]	黄第藩, 张大江, 李晋超.论4-甲基甾烷和孕甾烷的成因[J].石油勘探与开发, 1989, 16(3):8-15.
[39]	Hao F, Zhou X, Zhu Y, et al.Charging of oil fields surrounding the Shaleitian uplift from multiple source rock intervals and generative kitchens, Bohai Bay basin, China[J].Marine and Petroleum Geology, 2010, 27(9):1910-1926. doi: 10.1016/j.marpetgeo.2010.07.005
[40]	姚益民, 梁鸿德, 蔡治国, 等.中国油气区第三纪(Ⅳ):渤海湾盆地油气区分册[M].北京:石油工业出版社, 1994.
[41]	Venkatesan M I, Dahl J.Organic geochemical evidence for global fires at the Cretaceous/Tertiary boundary[J].Nature, 1989, 338(6210):57-60. doi: 10.1038/338057a0
[42]	Ourisson G, Rohmer M, Poralla K.Prokaryotic hopanoids and other polyterpenoid sterol surrogates[J].Annual Review of Microbiology, 1987, 41:301-333. doi: 10.1146/annurev.mi.41.100187.001505
[43]	Kleemann G, Poralla K, Englert G, et al.Tetrahymanol from the phototrophic bacterium Rhodopseudomonas palustris:First report of a gammacerane triterpene from a prokaryote[J].Microbiology, 1990, 136(12):2551-2553.
[44]	刘洪军, 段俊梅, 秦黎明, 等.准噶尔盆地腹部及西南缘白垩系烃源岩地球化学特征及沉积环境分析[J].地质科技情报, 2013, 32(4):25-30.
[45]	李博一, 刘洛夫, 卫倩倩, 等.准噶尔盆地白家海凸起二叠系、三叠系油气来源及成藏模式[J].地质科技情报, 2014, 33(5):141-148.
[46]	Hao F, Zhou X, Zhu Y, et al.Mechanisms for oil depletion and enrichment on the Shijiutuo uplift, Bohai Bay Basin, China[J].AAPG Bulletin, 2009, 93:1015-1037. doi: 10.1306/04140908156
[47]	Rohmer M.The hopanoids, prokaryotic triterpenoids and sterol surrogates[M]//Surface structures of microorganisms and their interactions with the mammalian host.Weinlein, Germany: VCH Publishing, 1987.
[48]	苏显烈, 薛培华.试论盐湖盆地的盐岩沉积特征[J].石油勘探与开发, 1990, 17(4):8-14.