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海南岛北部种植园土壤中多环芳烃的质量分数、来源及生态风险

杨剑洲 龚晶晶 马生明 赵锦华 王振亮 苏磊 胡树起 唐世新

杨剑洲, 龚晶晶, 马生明, 赵锦华, 王振亮, 苏磊, 胡树起, 唐世新. 海南岛北部种植园土壤中多环芳烃的质量分数、来源及生态风险[J]. 地质科技通报, 2021, 40(6): 268-275. doi: 10.19509/j.cnki.dzkq.2021.0626
引用本文: 杨剑洲, 龚晶晶, 马生明, 赵锦华, 王振亮, 苏磊, 胡树起, 唐世新. 海南岛北部种植园土壤中多环芳烃的质量分数、来源及生态风险[J]. 地质科技通报, 2021, 40(6): 268-275. doi: 10.19509/j.cnki.dzkq.2021.0626
Yang Jianzhou, Gong Jingjing, Ma Shengming, Zhao Jinhua, Wang Zhenliang, Su Lei, Hu Shuqi, Tang Shixin. Contents, sources and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in agricultural soils of plantations in northern Hainan Island[J]. Bulletin of Geological Science and Technology, 2021, 40(6): 268-275. doi: 10.19509/j.cnki.dzkq.2021.0626
Citation: Yang Jianzhou, Gong Jingjing, Ma Shengming, Zhao Jinhua, Wang Zhenliang, Su Lei, Hu Shuqi, Tang Shixin. Contents, sources and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in agricultural soils of plantations in northern Hainan Island[J]. Bulletin of Geological Science and Technology, 2021, 40(6): 268-275. doi: 10.19509/j.cnki.dzkq.2021.0626

海南岛北部种植园土壤中多环芳烃的质量分数、来源及生态风险

doi: 10.19509/j.cnki.dzkq.2021.0626
基金项目: 

自然资源部中国地质调查局地质调查项目 DD20190305

详细信息
    作者简介:

    杨剑洲(1990-), 男, 工程师, 主要从事生态地球化学方面的研究工作。E-mail: yjianzhou@mail.cgs.gov.cn

    通讯作者:

    龚晶晶(1989-), 男, 工程师, 主要从事生态地质研究工作。E-mail: gjingjing@mail.cgs.gov.cn

  • 中图分类号: X53

Contents, sources and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in agricultural soils of plantations in northern Hainan Island

  • 摘要: 海南岛是我国主要的热带农作物种植基地,对海南岛种植园土壤污染物评估具有重要意义。对海南岛北部种植园土壤中的16种多环芳烃(PAHs)质量分数、来源及生态风险进行评估。使用气相色谱-质谱联用技术对咖啡、香蕉、山药、甘蔗、橙子、百香果和石榴种植园中100件表层土壤样品进行PAHs质量分数测定。结果表明,研究区种植园土壤平均∑16PAHs为37.6 ng/g,低于我国土壤背景值和荷兰无污染土壤限值(< 200 ng/g)。三环、四环和五环PAHs为主要组成成分,分别占据∑16PAHs质量分数的25.8%,26.8%和23.5%。源识别显示,种植园内PAHs主要来自机动车尾气排放,部分来自石油产品的泄露及煤和生物质的低温燃烧。生态风险评价结果显示,等效毒性当量∑16BaPeq低于国家标准,表明土壤中PAHs污染物水平处于可接受范围。

     

  • 图 1  采样点分布

    Figure 1.  Location of sampling points

    图 2  种植园土壤中PAHs环数分布

    Figure 2.  Ring distribution of PAHs in soil of plantations

    图 3  土壤PAHs多特征比值

    Figure 3.  Concentration ratios of PAHs in the soil samples

    图 4  种植园土壤中PAHs的因子载荷

    Figure 4.  Factor loading diagram of PAHs in the soil samples

    表  1  种植园表层土壤中PAHs浓度和∑16BaPeq毒性浓度

    Table  1.   Concentrations of ∑16BaPeq and PAHs in surface soil of various plantations

    组分 百香果园(n=10) 福橙园(n=32) 甘蔗园(n=5) 咖啡园(n=12) 番石榴园(n=12) 山药园(n=19) 香蕉园(n=10) 种植园(n=100) TEF
    范围 平均值 范围 平均值 范围 平均值 范围 平均值 范围 平均值 范围 平均值 范围 平均值 范围 平均值
    wB/(ng·g-1)
    Nap n.d.~3.1 1.6 1.1 ~5.5 2.8 1.8 ~3.4 2.7 n.d.~5.3 4.1 n.d.~6.8 4.9 0.9 ~3.0 2.1 0.9 ~3.4 1.8 n.d.~6.8 2.8 0.001
    Ane 0.7 ~0.8 0.8 n.d.~1.7 0.8 0.8 ~1.0 0.9 n.d.~3.0 2.0 0.8 ~1.2 0.9 0.7 ~2.6 1.2 n.d.~1.1 0.9 n.d.~3 1.0 0.001
    Any 0.3 ~0.5 0.4 n.d.~0.7 0.5 n.d.~0.5 0.4 2.5 ~3.0 2.7 n.d.~0.6 0.5 0.3 ~0.7 0.4 0.3 ~1.9 1.3 n.d.~3 0.9 0.001
    Flo 1.4 ~3.4 2.0 0.7 ~2.0 1.3 1.8 ~7.7 3.3 2.8 ~3.9 3.4 1.6 ~2.3 1.9 1.0 ~4.9 2.1 1.4 ~4.2 2.5 0.7~7.7 2.1 0.001
    Phe 5.1 ~10.8 8.0 2.0 ~7.5 3.9 9.3 ~14.2 12.2 n.d.~10.4 9.5 3.2 ~23.6 7.8 1.9 ~9.6 5.0 n.d.~8.3 5.8 n.d.~23.6 6.2 0.001
    Ant 0.8 ~4.2 2.0 n.d.~4.9 1.1 1.3 ~4.7 2.1 n.d.~10.0 6.6 n.d.~1.1 0.5 n.d.~2.3 0.8 n.d.~7.1 2.6 n.d.~10 1.6 0.010
    Fla 1.2 ~5.8 3.1 0.4 ~14.5 2.5 5.3 ~10.4 7.6 4.4 ~6.5 5.4 1.2 ~17.2 6.6 0.4 ~5.0 1.8 1.1 ~3.9 2.8 0.4~17.2 3.5 0.001
    Pyr 0.5 ~2.3 1.3 0.3 ~10.7 1.6 2.0 ~5.3 3.1 4.0 ~5.7 4.6 0.7 ~3.9 2.0 0.2 ~2.1 0.8 0.6 ~2.7 2.1 0.2~10.7 2.0 0.001
    BaA 0.3 ~0.7 0.5 n.d.~6.9 1.4 0.4 ~1.0 0.7 9.1 ~9.7 9.4 0.5 ~2.2 1.1 0.3 ~1.2 0.5 0.4 ~4.8 3.5 n.d.~9.7 2.2 0.100
    Chry 0.9 ~3.3 2.0 n.d.~10.9 2.4 2.5 ~5.1 3.7 1.6 ~7.1 2.6 1.7 ~7.1 4.3 0.3 ~4.6 1.8 0.9 ~3.0 1.6 n.d.~10.9 2.5 0.010
    BbF 1.2 ~2.8 2.0 n.d.~9.4 3.0 2.3 ~3.7 2.8 6.9 ~16.7 8.5 2.1 ~6.4 4.1 1.1 ~5.1 2.5 1.2 ~4.4 3.4 n.d.~16.7 3.6 0.100
    BkF 0.6 ~1.5 1.1 n.d.~6.8 2.0 1.2 ~2.1 1.8 6.6 ~11.6 7.6 1.4 ~4.7 2.7 0.5 ~3.5 1.5 0.5 ~4.0 3.0 n.d.~11.6 2.7 0.100
    BghiP 1.5 ~1.9 1.7 1.0 ~4.1 1.9 1.6 ~2.0 1.8 n.d.~8.4 5.4 1.8 ~3.5 2.2 1.5 ~2.6 1.9 1.6 ~2.6 2.3 n.d.~8.4 2.4 0.010
    InP 2.3 ~2.8 2.5 2.4 ~5.3 3.1 2.4 ~2.7 2.6 8.4 ~13.2 9.3 2.6 ~4.9 3.3 2.4 ~3.5 2.8 2.4 ~4.6 3.8 2.3~13.2 3.8 0.100
    DaA n.d. - n.d.~3.8 - n.d. - n.d. - n.d. - n.d.~3.2 - n.d. - n.d.~3.8 - 1.000
    BaP n.d.~1.6 1.5 n.d.~6.5 2.2 1.4 ~1.5 1.5 n.d.~8.8 8.1 1.5 ~2.7 1.8 n.d.~2.0 1.6 1.4 ~4.2 3.3 n.d.~8.8 2.8 1.000
    16PAHs 18.7 ~39.4 29.8 7.0 ~89.4 28.3 38.3 ~54.8 47.0 52.4 ~97.5 79.1 24.5 ~80.3 44.5 12.2 ~43.1 25.7 17.4 ~46.2 37.2 7.0~97.5 37.6 -
    7BaPeq 0.5~2.3 1.8 0~12.0 3.0 2.1~2.5 2.3 2.3~~14.0 10.9 2.2~4.0 3.0 0.2~6.0 2.4 1.9~6.0 4.7
    16BaPeq 0.5~2.4 1.9 0.01~12.1 3.0 2.2~2.6 2.4 2.4~14.1 11.0 2.3~4.6 3.0 0.2~6.1 2.4 1.9~6.0 4.7 0.01~14.1 3.900
    注:n为样本量;n.d.表示低于检出限
    下载: 导出CSV
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