Volume 41 Issue 4
Jul.  2022
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Zhang Xiaoping, Wu Zhihua, Chen Jiamu, Zhang Xiaojun, Liu Wenhao, Wang Linling, Zhou Miao, Qi Yutong, Wu Yunhui. Occurrence state and migration mechanism of arsenic in metal mines[J]. Bulletin of Geological Science and Technology, 2022, 41(4): 138-148. doi: 10.19509/j.cnki.dzkq.2022.0121
Citation: Zhang Xiaoping, Wu Zhihua, Chen Jiamu, Zhang Xiaojun, Liu Wenhao, Wang Linling, Zhou Miao, Qi Yutong, Wu Yunhui. Occurrence state and migration mechanism of arsenic in metal mines[J]. Bulletin of Geological Science and Technology, 2022, 41(4): 138-148. doi: 10.19509/j.cnki.dzkq.2022.0121

Occurrence state and migration mechanism of arsenic in metal mines

doi: 10.19509/j.cnki.dzkq.2022.0121
  • Received Date: 22 Apr 2021
    Available Online: 07 Sep 2022
  • Environmental pollution often occurs in the process of mining, beneficiation and smelting of metal mines.Arsenic pollution caused by acid mine drainage (AMD) is one of the most serious pollution problems of heavy metals. At present, the understanding of the evolution process of secondary minerals is insufficient. This paper summarizes the occurrence form of arsenic in metal sulfide.The specific chemical process of activation and migration in different minerals are discussed.Three rules of form transformation are concluded. ①Pyrite and arsenopyrite are the most common arsenic-bearing minerals in metal sulfide mines; ②Arsenic is activated by the oxidation and dissolution of primary minerals, existing mainly in the form of arsenate and arsenite in AMD of which arsenite is more migratory. ③Adsorptive precipitation of secondary minerals in AMD (such as ferro-vanadium, goethite, scallion, etc.) can slow the migration rate and reduce the migration amount of arsenic but cannot prevent the migration process. The migration mechanism of arsenic in the mine environment is reviewed, and new treatment schemes and research directions are proposed.

     

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