全球钴矿资源时空分布及成因类型

付浩; 王加昇; 李金龙; 王博; 叶彬; 李梦玲

doi:10.19509/j.cnki.dzkq.tb20220431

全球钴矿资源时空分布及成因类型

doi: 10.19509/j.cnki.dzkq.tb20220431

付浩^1,,
王加昇^1, ,,
李金龙²,
王博¹,
叶彬¹,
李梦玲^{3a, 3b, 3c, 4}

1.
昆明理工大学国土资源工程学院, 昆明 650093
2.
云南省煤田地质局, 昆明 650034
3a.
中国科学院青海盐湖研究所, 西宁 810008
3b.
中国科学院盐湖资源综合高效利用重点实验室, 西宁 810008
3c.
中国科学院青海省盐湖地质与环境重点实验室, 西宁 810008
4.
中国科学院大学, 北京 100049

基金项目:

云南省科技计划项目 202202AG050006

自然资源部三江成矿作用及资源勘查利用重点实验室开放基金 ZRZYBSJSYS2021002

云南省"万人计划青年拔尖人才"专项云人设通[2020]150号

详细信息

作者简介:
付浩, E-mail: fuhao1202@sina.cn

通讯作者:
王加昇, E-mail: jiashengwang@126.com

中图分类号: P617;P618.62
计量
- 文章访问数: 995
- PDF下载量: 317
- 被引次数: 0
出版历程
- 收稿日期: 2022-08-07
- 录用日期: 2022-10-06
- 修回日期: 2022-10-05

Spatiotemporal distribution and genesis types of global cobalt resources

FU Hao^1
,,
WANG Jiasheng^{1
, ,},
LI Jinlong²,
WANG Bo¹,
YE Bin¹,
LI Mengling^{3a, 3b, 3c, 4}

1.
Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Bueau of Coalfield Geology of Yunnan Province, Kunming 650034, China
3a.
Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
3b.
Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Chinese Academy of Sciences, Xining 810008, China
3c.
Qinghai Provincial Key Laboratory, Chinese Academy of Sciences, Xining 810008, China
4.
University of Chinese Academy of Sciences, Beijing 100049, China

More Information

Author Bio:
FU Hao, E-mail: fuhao1202@sina.cn

Corresponding author: WANG Jiasheng, E-mail: jiashengwang@126.com

摘要

摘要:
钴是重要的战略性矿产资源，在航空航天、电动车电池制造等工业领域具有不可替代的作用。钴矿是我国紧缺的矿种之一，可被工业利用的钴资源主要集中在全球少数几个国家，我国钴矿资源严重依赖进口。因此，加强钴矿资源研究，降低被"卡脖子"风险，事关我国经济可持续发展大计。系统综述了钴的地球化学性质和矿物类型，对钴矿床的类型及形成机制进行了细致总结，对全球和我国钴矿床的时空分布规律进行了全面梳理，此外，还对钴矿床研究中存在的问题进行了深入分析，并对钴矿床成矿时代及其动力学背景、钴的来源、钴元素迁移富集机制和钴的赋存状态等未来研究方向进行了展望，旨在为我国钴矿床的研究提供参考，同时也为国内钴矿资源的勘探开发提供新的思路。
- 钴 /
- 战略性矿产 /
- 时空分布 /
- 成因类型
Abstract: Significance
Cobalt is an important strategic mineral resource and plays an irreplaceable role in aerospace, battery and other industries. Cobalt is mainly concentrated in few countries around the world and is one of the scarcest mineral resources in China. The cobalt ore resources in China are heavily dependent on imports. Therefore, research on cobalt ore resources is vital to reduce the bottleneck risk and to sustain the economic development.
Progress
This paper systematically reviewed geochemical properties and mineral types of cobalt and the genetic types, formation mechanisms, and spatiotemporal distribution of cobalt deposits in the world and China.
Conclusions and prospects
The existing problems of cobalt deposits are comprehensively summarized in the study and future research should be focused on the ore-forming age and the dynamic background of cobalt deposits, the source, migration and enrichment mechanism, and the occurrence of cobalt. This study aims to provide a new reference for the study of cobalt deposits and the exploration and development of cobalt resources in China.
- cobalt /
- strategic mineral resources /
- spatiotemporal distribution /
- genesis type
注释:

所有作者声明不存在利益冲突。

HTML全文

图 1 钴矿资源储量(数据来自文献[7-8])

Figure 1. Cobalt ore resource reserves

下载: 全尺寸图片幻灯片

图 2 全球主要钴矿床分布图(1.矿床序号与表 2中矿床序号对应；2.富钴的海底Fe-Mn结核(结壳), 数据来自于文献[56])

Figure 2. Distribution map of major cobalt deposits in the world

下载: 全尺寸图片幻灯片

表 1 主要钴矿物^[22-24]

Table 1. Major cobalt minerals

矿物种类	矿物名称	化学式	钴w_B/%	颜色
砷化物	砷钴矿	CoAs₂	15~24	锡白色、钢灰色
砷化物	斜方砷钴矿	(Co, Fe, Ni)As₂	13~23	锡白色、铅灰色
硫化物	硫钴矿	Co₃S₄	57.95	亮灰色
	硫铜钴矿	CuCo₂S₄	28.56	钢灰色
	硫镍钴矿	(Co, Ni)₃S₄	29.00	亮钢灰色
	钴黄铁矿	(Fe, Co) S₂	33.00	浅黄色
	方硫钴矿	CoS₂	47.89	粉红色，灰色
	方硫镍钴矿	(Co, Ni)₃S₄	4~10	亮钢灰色
	钴镍黄铁矿	Co₉S₈	67.40	铜黄色
	硫锑钴镍矿	(Co, Ni)SbS	20.78	灰色
硫砷化物	辉钴矿	CoAsS	35.52	锡白色、铝灰色
	铁硫砷钴矿	(Co, Fe)AsS	26.76	锡白色
	钴毒砂	(Fe, Co)AsS	3~10	灰黑色
表生矿物	钴华	Co₃(AsO)₄·8H₂O	29.53	粉红色、鲜红色
	钴土矿	(Ni, Co)_2-xMn(O, OH)₄·nH₂O	1~25	褐色、黑色
	水钴矿	Co₂O₃·H₂O	64.10	淡蓝色、淡紫色
	菱钴矿	CoCO₃	49.55	玫瑰红
	钴孔雀石	(Cu, Co)₂(CO₃)(OH)₂	17.84	绿色、黑棕色

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表 2 世界主要钴矿床

Table 2. Major cobalt deposits in the world

矿床名称		国家	赋存形式	钴金属量/万t	规模	Co品位/%	矿体形态	含钴矿物	围岩蚀变	成矿年代	资料来源
岩浆岩型含(富) Co硫化物矿床	(1)Voisey′s Bay	加拿大	伴生	12.3	大型	0.12	层状、似层状、透镜状、脉状	含钴黄铁矿、含钴磁黄铁矿、钴镍黄铁矿	硅化、黑云母化、闪长岩化、碳酸盐化	1334 Ma中元古代	文献[39]
	(2)Kambalda	澳大利亚	伴生	—	大型	0.21	盆状、漏斗状、脉状	含钴镍黄铁矿、含钴黄铁矿	硅化、黑云母化	2 700 Ma古元古代-新太古代	文献[92]
	(3)Noril′sk-Talnakh	俄罗斯	伴生	79	大型	0.06	盆状、漏斗状、脉状	含钴镍黄铁矿、含钴黄铁矿	硅化、碳酸盐化、闪长岩化	347~226 Ma	文献[38, 93]
	(4)Sudbury	加拿大	伴生	100.6	大型	0.1	层状、透镜状	方硫镍钴矿、含钴砷镍矿	闪长岩化	—	文献[25, 94]
	(5)金川	中国	伴生	9.8	大型	0.07~0.2	似层状、透镜状	镍辉砷钴矿、铁镍辉钴矿、斜方辉砷钴矿、辉钴矿、含钴辉砷镍矿	黏土化、绿泥石化、蛇纹石化	(1 508±31) Ma	文献[46, 95]
	(6)Outokumpu	芬兰	—	7.3	大型	0.25	—	—	—	—	文献[40]
	(7)Dumont	加拿大	—	12.61	大型	0.011	—	—	—	—	文献[96]
	(8)Eagle	美国	—	—	—	0.08	—	含钴黄铁矿、含钴磁黄铁矿、钴镍黄铁矿	—	—	文献[56]
	(9)Raglan	加拿大	—	—	—	0.06	—	含钴黄铁矿、含钴磁黄铁矿、钴镍黄铁矿	—	—	文献[56]
热液型含(富) Co多金属矿床	(10)BouAzzer	摩洛哥	伴生	8.5	大型	1~2.5	脉状、巢状、柱状、透镜状	方钴矿、砷钴矿、斜方砷钴矿	碳酸盐化、蛇纹石化、硅化、绿泥石化	泥盆纪-石炭纪	文献[47]
	(11)Olympic Dam	澳大利亚	伴生	12.1	大型	0.02	层状、透镜状、脉状	含钴黄铁矿、含钴针铁矿	硅化、绢云母化、绿泥石化	中元古代	文献[48]
	(12)Windy Craggy	加拿大	伴生	20.5	大型	0.069	层状、似层状、脉状	含钴黄铁矿、含钴磁黄铁矿	绿泥石化、钠长石化、硅化	—	文献[2]
	(13)Sibaiskoye	俄罗斯	伴生	13	大型	0.13	板状、透镜状	含钴黄铁矿、含钴磁黄铁矿	硅化、绢云母化、碳酸盐化、绿泥石化	—	文献[97]
	(14)Magnitogorsk	俄罗斯	伴生	9	大型	0.018	层状、透镜状、脉状	含钴黄铁矿、含钴磁黄铁矿	硅化、碳酸盐化	元古代	文献[98]
沉积岩-变沉积岩容矿型Cu-Co矿床	(15)Blackbird	美国	伴生	12.3	大型	0.73	层状、似层状	钴铁矿、含钴毒砂、含钴黄铁矿	黑云母化、硅化、绿泥石化	(1 132±240)Ma中元古代	文献[60]
	(16)Kamoto	刚果	伴生	36.2	大型	0.39	层状、似层状	含钴黄铁矿、硫铜钴矿	碳酸盐化、硅化	(762±33)Ma早古生代-新元古代	文献[99, 57]
	(17)Chambishi	赞比亚	伴生	15	大型	0.10	层状、似层状	硫铜钴矿、含钴黄铁矿、含钴磁黄铁矿	绢云母化、绿泥石化、硅化、碳酸盐化	(504.8±2.2)Ma早古生代	文献[58-59]
	(18)Tenke-Fungurume	刚果	伴生	31	大型	0.1~1	层状、透镜状	硫铜钴矿、水钴矿、含钴孔雀石	硅化、碳酸盐化	新元古代	文献[24, 100]
	(19)Luishia	刚果	伴生	—	大型	0.20	层状、似层状、透镜状	硫铜钴矿、含钴黄铁矿、水钴矿	硅化、碳酸盐化、绿泥石化	(742±32)Ma新元古代	文献[101]
	(20)Luiswishi	刚果	伴生	—	大型	0.46	层状、似层状	硫铜钴矿	硅化、碳酸盐化、白云岩化	新元古代	文献[102]
	(21)Kamoya	刚果	伴生	5	大型	0.30	层状、似层状、透镜状	硫铜钴矿、碲硫镍钴矿	硅化、碳酸盐化、白云岩化、绿泥石化	880~735 Ma新元古代	文献[103]
	(22)Kansuki	刚果	共生	6	大型	0.75	层状、似层状、透镜状	水钴矿、菱钴矿	滑石化、绢云母化、赤铁矿化、高岭石化、硅化	880~750 Ma新元古代	文献[70, 103]
	(23)Kolwezi	刚果	伴生	—	小型	0.2	层状、似层状	硫铜钴矿、水钴矿、水钴铜矿、钴白云石、钴华	硅化、碳酸盐化、白云岩化	新元古代	文献[73]
	(24)Talvivaara	芬兰	伴生	31	大型	0.02	层状、似层状	含钴黄铁矿、含钴磁黄铁矿	硅化、滑石化、碳酸盐化、蛇纹石化	元古代	文献[67, 104]
	(25)Kimpe	刚果	伴生	3	大型	0.123	板状、脉状	硫钴矿、硫铜钴矿、水钴矿	硅化、白云石化、绢云母化、绿泥石化	880~550 Ma新元古代	文献[105]
	(26)Sicomines	刚果	伴生	61.6	大型	0.22	层状、似层状	硫铜钴矿、水钴矿、含钴黄铁矿	有硅化、白云岩化、绢云母化、碳酸盐化、滑石化	新元古代	文献[63]
风化型红土Ni-Co矿床	(27)Goro	新喀里多尼亚	伴生	39	大型	0.12	层状、似层状	水钻矿、钴土矿	—	中新世	文献[106, 108]
	(28)Nkamouna	喀麦隆	伴生	86	大型	0.25	层状、似层状	钴红土、含钴针铁矿	—	—	文献[77]
	(29)Moa Bay	古巴	伴生	52	大型	0.01~0.15	—	镍钴钡镁锰矿	—	—	文献[24]
	(30)Jacaré	巴西	伴生	64	大型	0.13	—	钴土矿	—	—	文献[56]
	(31)Sunrise	澳大利亚	—	13.56	大型	0.09	—	—	—	—	文献[96]
	(32)Murrin	澳大利亚	—	35	大型	0.076	—	—	—	—	文献[96]
	(33)Ambatovy Joint Venture	马达加斯加	—	12.16	大型	0.08	—	—	—	—	文献[96]
注：大型＞20 000 t，中型[2 000, 20 000] t，小型＜2 000 t^[27]

下载: 导出CSV

表 3 中国主要钴矿床

Table 3. Major cobalt deposits in China

矿床名称		赋存形式	钴金属量/万t	规模	Co品位/%	矿体形态	含钴矿物	围岩蚀变	成矿年代	资料来源
岩浆岩型含(富) Co硫化物矿床	(1)甘肃金川Ni-Cu-Co矿	伴生	9.8	大型	0.07~0.2	似层状、透镜状	镍辉砷钴矿、铁镍辉钴矿、斜方辉砷钴矿、辉钴矿、含钴辉砷镍矿	黏土化、绿泥石化、蛇纹石化	(1 508±31)Ma元古代	文献[46, 95]
	(2)云南白马寨Ni-Cu-(-PGE-Co)矿	伴生	0.3	中型	0.07	层状、似层状	镍辉砷钴矿	次闪石化、绿泥石化、滑石化	260 Ma二叠纪-三叠纪	文献[46]
	(3)新疆图拉尔根Ni-Cu-Co矿	伴生	0.51	中型	0.03	板状、透镜状	含钴磁黄铁矿、镍辉砷钴矿、钴辉砷镍矿	蛇纹石化、滑石化、透闪石化	(280±4)Ma晚石炭世-早二叠世	文献[109-110]
	(4)新疆黄山西Ni-Cu-Co矿	伴生	1~2	中型	0.04	层状、似层状、透镜状	钴黄铁矿、含钴磁黄铁矿	蛇纹石化、绿泥石化、碳酸岩化	晚石炭世-早二叠世	文献[45]
	(5)新疆黄山Ni-Cu-Co矿	伴生	—	大型	0.026	层状、似层状、透镜状	钴黄铁矿、含钴磁黄铁矿	蛇纹石化、绿泥石化、碳酸岩化	晚石炭世-早二叠世	文献[111-112]
	(6)内蒙古嘎仙Ni-Co矿	伴生	2.6	大型	0.06	层状、似层状、透镜状	钴镍黄铁矿、含钴黄铁矿、含钴磁黄铁矿	透闪石化、蛇纹石化、绿泥石化、碳酸盐化	白垩纪	文献[113]
	(7)新疆黄山东Ni-Cu-Co矿	伴生	1.4	中型	0.024	层状、似层状、透镜状	钴黄铁矿、含钴磁黄铁矿	蛇纹石化、绿泥石化、碳酸岩化	(288±5)Ma晚石炭世-早二叠世	文献[111, 114]
	(8)吉林红旗岭Ni-Cu-Co矿	伴生	0.31	中型	0.04	层状、似层状	含钴磁黄铁矿	次闪石化、绢云母化、滑石化	海西期-印支期	文献[45]
	(9)新疆葫芦Cu-Ni(-Co)矿	伴生	0.51	中型	0.03	层状、似层状、透镜状	含钴磁黄铁矿	蛇纹石化、碳酸岩化	274.5 Ma晚石炭世-早二叠世	文献[111, 115]
	(10)陕西煎茶岭Ni(-Co)矿	伴生	1	中型	0.026	透镜状、层状	含钴镍黄铁矿	蛇纹石化	元古代	文献[116-117]
	(11)青海夏日哈木Ni-Cu(-Co)矿	伴生	4.03	大型	0.028	透镜状、似层状	含钴辉砷镍矿、钴镍黄铁矿	蛇纹石化、绿泥石化、阳起石化	(406.1±2.7)Ma晚泥盆世-早石炭世	文献[43, 118]
	(12)四川攀枝花V-Ti-Fe(-Co)矿	伴生	2	中型	0.01~0.02	层状、似层状、透镜状	含钴磁黄铁矿、含钴黄铁矿	次闪石化、绿泥石化、蛇纹石化	晚古生代	文献[45]
	(13)新疆喀拉通克Cu-Ni(-Co)矿	伴生	—	—	—	透镜状、囊状、脉状	含钴黄铁矿	绿泥石化、绿帘石化、滑石化、硅化	(282±20)Ma二叠纪	文献[46, 119]
热液型含(富) Co多金属矿床	(14)青海德尔尼Cu-Co-Zn矿	共生	2.8	大型	0.1	透镜状、似层状	钴镍黄铁矿	蛇纹石化、碳酸盐化、硅化	海西期-印支期	文献[26, 45]
	(15)青海肯德克可Co-Bi-Au矿	共生	1.54	中型	0.064~0.46	层状、似层状	方钴矿、辉钴矿	矽卡岩化、硅化	早古生代	文献[91]
	(16)青海骆驼沟Co(Au)	独立	2	中型	0.06	似层状、透镜状	含钴黄铁矿、硫钴矿、硫铜钴矿	硅化、碳酸盐化	(429±29)Ma志留纪-泥盆纪	文献[97, 120-122]
	(17)新疆磁海Fe(Co)矿	伴生	1	中型	0.01~0.1	似层状、脉状	含钴黄铁矿、含钴磁黄铁矿、斜方砷钴矿、辉钴矿	钠长石化、黄铁石化、透辉石化	(281.9±2.2)Ma二叠纪-三叠纪	文献[123]
	(18)新疆阔尔真阔腊Au(-Co)矿	伴生	—	—	0.007~0.12	层状、透镜体状	含钴黄铁矿	硅化、碳酸岩化、绢云母化	海西期	文献[124]
	(19)湖北大冶铜绿山Fe-Cu(-Co)矿	伴生	—	—	—	似层状、透镜状	硫铜钴矿、含钴黄铁矿、辉钴矿、铁硫砷钴矿	矽卡岩化	燕山期	文献[125]
	(20)山西中条山胡-蓖型Cu-Co矿	伴生	0.53	中型	0.024	层状、似层状、透镜状	含钴黄铁矿、辉钴矿、钴铁矿	硅化、碳酸盐化	(1 844±25)Ma古元古代	文献[122]
	(21)云南新平大红山Fe-Cu-Co矿	伴生	0.27	中型	—	层状、似层状、透镜状	辉钴矿、硫钴矿、硫砷钴矿	硅化、碳酸盐化	—	文献[27]
	(22)江西五宝山Pb-Zn-Co矿床	独立	0.24	中型	0.024~1.15	似层状、透镜状	辉钴矿、钴毒砂、含钴黄铁矿、辉钴矿	硅化、绿泥石化	中生代	文献[126-127]
	(23)江西七宝山Pb-Zn-Co矿床	独立	0.2	小型	0.024~1.15	层状、似层状	含钴黄铁矿、辉钴矿	硅化	中生代	文献[128]
	(24)湖南普乐-横洞Co矿	独立	1.24	中型	0.04	层状、似层状	含钴黄铁矿、辉钴矿	硅化	125 Ma中生代	文献[129-130]
	(25)海南石碌Fe-Co-Cu矿	共生	1.18	中型	0.29	层状、似层状、透镜体状	含钴黄铁矿、含钴磁黄铁矿、辉钴矿	镁质矽卡岩化	330~240 Ma石炭纪-三叠纪	文献[52-53]
	(26)西藏玉龙Cu-Mo(-Co)矿	伴生	—	—	0.023	层状、似层状、透镜体状	含钴锰的水合氧化物、钴华、含钴黄铁矿	硅化、绿泥石化、绢云母化	40~35 Ma渐新世-始新世	文献[131-132]
	(27)西藏普桑果Cu-Pb-Zn-Co-Ni矿	伴生	0.025	小型	0.029	透镜状、脉状	辉砷钴镍矿	矽卡岩化、硅化、绿泥石化、碳酸盐化	喜山期	文献[50-51]
	(28)青海督冷沟Cu-Co矿	伴生	—	中型	0.02~1.31	脉状、透镜状、似层状	铁硫砷钴矿、铁硫砷镍钴矿、钴黄铁矿、钴镍黄铁矿、辉钴矿、硫钴镍矿	绢云母化、碳酸盐化、硅化	晚古生代	文献[133]
	(29)湖南井冲Cu-Co矿	共生	0.37	中型	0.027	层状、透镜状、脉状	含钴黄铁矿、钴铁矿	硅化、绿泥石化	晚侏罗世-白垩世	文献[134]
	(30)四川拉拉Cu-Co-Au矿	伴生	1.74	大型	0.022	似层状、透镜状	含钴黄铁矿、辉钴矿、硫钴镍矿、方硫镍钴矿	黄铜矿化、黄铁矿化、磁铁矿化、硅化、钠长石化	古元古代	文献[135]
	(31)云南易门老厂Cu-Co矿	伴生	—	中型	0.11	层状、似层状、脉状	辉钴矿、镍辉砷钴矿、含钴毒砂、杂水钴矿	硅化、白云岩化	元古代	文献[136]
	(32)甘肃康县阳坝Au-Cu-Co矿	伴生	—	—	0.01~0.04	似层状、扁豆状	含钴黄铁矿	硅化、绢云母化、黄铁矿化	—	文献[137]
	(33)新疆蕴都卡拉Au-Cu-Co矿	伴生	—	—	0.011	脉状、似层状、不规则状	辉钴矿、方钴矿	黄铜矿化、黄铁矿化、碳酸盐化、硅化、蛇纹石化、绿泥石化	—	文献[138]
	(34)云南兰坪白秧坪Cu(-Co) 矿	伴生	0.15	小型	0.025~0.094	似层状、脉状	辉钴矿、钴华、含钴黄铁矿、含钴砷黝铜矿	硅化、碳酸盐化、黄铁矿化	61.13 Ma古新世	文献[139]
	(35)内蒙古阿右旗卡休他他Fe-(-Au-Co)矿	伴生	0.22	中型	0.010	透镜状、囊状	斜方砷钴矿、辉钴矿、含镍辉钴矿、钴毒砂	矽卡岩化、硅化	—	文献[140]
	(36)新疆卡拉塔什含Cu砂页岩	伴生	—	小型	0.015	透镜状	含钴铜砂页岩、含钴辉铜矿	白云石化、硅化	元古代	文献[141]
沉积岩-变沉积岩容矿型Cu-Co矿床	(37)云南永平水泄-厂街Cu-Co矿	共生	0.29	中型	0.03~0.1	脉状、透镜状、囊状	含钴黄铁矿、镍辉砷钴矿、含钴毒砂、辉钴矿	硅化、黄铁矿化、菱铁矿化、重晶石化	—	文献[142]
	(38)吉林大横路Cu-Co矿	共生	5	大型	0.035~0.80	层状、似层状、分枝复合状	硫镍钴矿、辉钴矿、方钴矿、含钴黄铁矿	硅化、绢云母化、钠长石化、碳酸盐化、黄铁矿化	古元古代	文献[143]
	(39)辽宁营口周家Cu-Co矿	共生	0.2	中型	0.013~0.042	呈层状、似层状、扁豆状、透镜体状	含钴黄铁矿、硫钴矿、铜硫钴矿	硅化、绢云母化、绿泥石化、碳酸盐化	早元古代	文献[144-145]
	(40)辽宁营口上华Cu-Co矿	共生	—	中型	0.013~0.042	似层状、扁豆状	含钴黄铁矿、硫钴矿、铜硫钴矿	硅化、绢云母化、绿泥石化、碳酸盐化	早元古代	文献[144-145]
	(41)广西金秀罗丹Cu-Co矿	独立	—	小型	0.034~0.048	透镜状、串珠状	辉钴矿	硅化、绿泥石化、白云母化	—	文献[146]
风化型红土Ni-Co矿床	(42)云南元江-墨江Ni-Co矿	伴生	0.4	中型	0.03~0.04	层状、似层状	钴土矿	—	—	文献[27, 45]
	(43)海南文昌蓬莱钴土矿	伴生	0.89	中型	0.03	层状、似层状	钴土矿	—	—	文献[27, 45]
	(44)安定居丁钴土矿	伴生	1.4	中型	1.63	层状、似层状	钴土矿	—	—	文献[27, 45]
	(45)四川会理含钴蛇纹岩带	伴生	0.19	小型	0.01~0.02	层状、似层状	含钴的镍磁铁矿	蛇纹石化	—	文献[147]
	(46)贵州猫场杨家洞含钴铝土矿	伴生	—	小型	—	层状、似层状、透镜状	含钴黄铁矿	黏土化	—	文献[148]
	(47)贵州云峰含钴铝土矿	伴生	—	小型	0.021~0.038	似层状、透镜状	含钴黄铁矿、含钴的砷黄铁矿	黏土化	三叠纪	文献[149]
注：大型＞20 000 t，中型[2 000, 20 000] t，小型＜2 000 t^[27]

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参考文献(152)

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