胶莱盆地东北缘前垂柳金矿床S、Pb同位素组成：对成矿物质来源的指示

韩小梦; 郭云成; 段留安; 王建田; 赵鹏飞; 王利鹏; 喻光明

doi:10.19509/j.cnki.dzkq.tb20220659

胶莱盆地东北缘前垂柳金矿床S、Pb同位素组成：对成矿物质来源的指示

doi: 10.19509/j.cnki.dzkq.tb20220659

1.
中国地质调查局烟台海岸带地质调查中心, 山东烟台 264000
2.
自然资源部深部金矿勘查开采技术创新中心/山东省深部金矿探测大数据应用开发工程实验室, 山东威海 264209
3.
中国地质调查局自然资源综合调查指挥中心, 北京 100032

基金项目:

国家重点研发计划 2022YFC2903605

中国地质调查局金矿重点勘查区资源潜力评价工程项目“山东牟平辽上金矿资源潜力评价” DD20230392

重点勘查区战略性矿产资源勘查工程“胶西北地区金矿资源勘查”项目 ZD20220315

详细信息

作者简介:
韩小梦(1987—), 男, 工程师, 主要从事矿产勘查、矿床学研究工作。E-mail: 943062435@qq.com

通讯作者:
段留安(1976—), 男, 正高级工程师, 主要从事矿产勘查、矿床地球化学等方面研究工作。E-mail: liuanduan@163.com

中图分类号: P618.51
计量
- 文章访问数: 494
- PDF下载量: 49
- 被引次数: 0
出版历程
- 收稿日期: 2022-11-25

S and Pb isotopic compositions of the Qianchuiliu Gold Deposit on the northeastern margin of the Jiaolai Basin: Implication on the source of ore-forming material

1.
Yantai Geological Survey Center of Coastal Zone, China Geological Survey, Yantai Shandong 264000, China
2.
Ministry of Natural Resources Technology Innovation Center for Deep Gold Resources Exploration and Mining/Shandong Provincial Engineering Laboratory of Application and Development of Big Data for Deep Gold Exploration, Weihai Shandong 264209, China
3.
Command Center of Natural Resources Comprehensive Survey, China Geological Survey, Beijing 100032, China

摘要

摘要:
前垂柳金矿为胶东胶莱盆地东北缘新发现的蚀变岩型金矿床，金矿体主要赋存于牧牛山岩体(二长花岗岩)、荆山群地层和鹊山岩体(糜棱岩化二长花岗岩)之间厚大的构造蚀变带内，截止目前推测资源量达到中型规模，但矿床的成矿物质来源尚不明确。基于前人研究及野外调查，选择典型矿体中含金黄铁矿作为研究对象，开展了S、Pb同位素分析，探讨了矿床的成矿物质来源。测试结果显示：矿石硫化物δ³⁴S值总体为10.13‰~12.39‰，极差为2.26‰，平均值10.98‰，均一程度高，具高δ³⁴S值特征，反映了深部成矿流体上侵过程中混染了更多的地层中的硫，显示了荆山群地层对成矿有一定贡献；矿石铅同位素²⁰⁶Pb/²⁰⁴Pb比值为17.149~18.886，²⁰⁷Pb/²⁰⁴Pb比值为15.482~15.677，²⁰⁸Pb/²⁰⁴Pb比值为37.860~40.073，显示前垂柳金矿铅为壳幔混合来源，且具有下地壳铅的特征。该矿床S、Pb同位素特征显示成矿物质来源为壳幔混源，与周边辽上、蓬家夼等典型矿床成矿物质来源一致，反映了该区燕山期大规模成矿事件，预示了胶莱盆地东北缘具有较大的找矿潜力。
- 胶莱盆地东北缘 /
- 前垂柳金矿 /
- S同位素 /
- Pb同位素 /
- 物质来源
Abstract:
The Qianchuiliu Gold Deposit on the northeastern margin of the Jiaolai Basin is a newly discoverd altered rock type gold deposit, and is a medium-sized gold deposit hosted in the structural alteration zone between Muniushan, Jingshan Group and Queshan monzonitic granites. However, the source of ore-forming materials and the ore genesis are not clear. Based on previous field and analytical studies, the authors conducted sulfur and lead isotopic analyses on gold-bearing pyrite from typical ores as the research target. The δ³⁴S values are high and homogeneous ranging from 10.13‰-12.39‰, with an average of 10.98‰ and polar odds of 2.26‰. These sulfur isotopic results reveal a mixing process of sulfur in the Jingshan Group during the upwelling of deep ore-forming fluid. The ratios of ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb vary from 17.149-18.886, 15.482-15.677, and 37.860-40.073, respectively, suggesting a crust-mantle mixed source. In conclusion, sulfur and lead isotope analysis results of the Qianchuiliu Gold Deposit show a crust-mantle mixed source and are similar to those of typical gold deposits in this region. The gold deposits on the northeastern margin of the Jiaolai Basin formed at the large-scale Yanshanian metallogenic event, indicating great prospecting potential in this area.
- northeastern margin of the Jiaolai Basin /
- Qianchuiliu Gold Deposit /
- sulfur isotope /
- lead isotope /
- material source

HTML全文

图 1 前垂柳金矿区及周边金矿区地质简图^[1]

1.水库；2.第四系；3.下白垩统陆相沉积岩、火山岩；4.古元古界变质岩；5.前寒武纪侵入岩；6.晚侏罗世二长花岗岩；7.早白垩世花岗闪长岩；8.燕山晚期岩脉；9.地质界线；10.断裂；11.韧性剪切带；12.金矿床(点)；13.钼矿床；14.铜矿点；15.铅锌矿点；16.胶莱盆地东北缘前垂柳矿区位置；Ⅰ.华北板块；Ⅰ₁.胶莱-胶北断隆；Ⅰ₁¹.胶北断隆；Ⅰ₁².胶莱断陷；Ⅱ.秦岭-大别-苏鲁碰撞造山带；Ⅱ₁.胶南-威海断隆；Ⅱ₁¹.文登-威海断拱；Ⅱ₁².胶莱断陷；Ⅱ₁³.胶南-临沭断拱

Figure 1. Geological map of the Qianchuiliu Gold Mining area and nearby gold mineral deposits

下载: 全尺寸图片幻灯片

图 2 前垂柳金矿区16线和32线钻孔剖面图

Figure 2. Drilling profile of Line 16 and Line 32 in the Qianchuiliu Gold Mine area

下载: 全尺寸图片幻灯片

图 3 前垂柳金矿床矿石照片和显微照片

Figure 3. Photographs and photomicrographs of the Qianchuiliu Gold Deposit

下载: 全尺寸图片幻灯片

图 4 胶莱盆地东北缘典型金矿床硫化物δ³⁴S值对比分布图(图中数据综合本文及文献[31-37])

Figure 4. Distribution of sulfide δ³⁴S values of typical gold deposits on northeastern margin of the Jiaolai Basin

下载: 全尺寸图片幻灯片

图 5 前垂柳金矿床与区域典型金矿床硫同位素对比直方图(图中数据综合本文及文献[31-37])

Figure 5. Comporing histograms of sulfur isotopes in the Qianchuiliu Gold Deposit and regional gold deposits

下载: 全尺寸图片幻灯片

图 6 前垂柳金矿床矿石铅同位素模式图(a~b)及构造环境判别图(c~d)(底图据文献[42]; 投影点数据综合本文及文献[33-39])

Figure 6. Plumbotectonic model of lead isotope (a-b) and diagram for discriminating the tectonic setting (c-d) of the Qianchuiliu Gold Deposit

下载: 全尺寸图片幻灯片

图 7 前垂柳金矿床矿石铅同位素Δγ-Δβ成因判别图解(底图据文献[42]; 投影点数据综合本文及文献[33-39])

1.地幔源铅; 2.上地壳源铅; 3.上地壳与地幔混合的俯冲铅: 3a.岩浆作用铅; 3b.沉积作用铅; 4.化学沉积型铅; 5.海底热水作用铅; 6.中深变质作用Pb; 7.深变质下地壳铅; 8.造山带铅; 9.古老页岩上地壳铅; 10.退变质铅

Figure 7. Δγ-Δβ genetic classification diagram showing ore mineral lead isotopic distribution in the Qianchuiliu Gold Deposit

下载: 全尺寸图片幻灯片

表 1 前垂柳金矿床矿石硫同位素组成

Table 1. Sulfur isotope composition of the Qianchuiliu Gold Deposit

样品编号	采样位置	矿石中黄铁矿赋存特征	测试矿物	δ³⁴S/%
ZK3201-64	32线ZK3201孔117.2 m	细脉状黄铁矿	黄铁矿	11.20
ZK3201-97	32线ZK3201孔204.2 m	条带状黄铁矿	黄铁矿	11.23
ZK3201-128	32线ZK3201孔258.2 m	细脉状石英自形黄铁矿	黄铁矿	10.28
ZK3201-131	32线ZK3201孔262.1 m	细脉状石英黄铁矿	黄铁矿	12.39
ZK3201-338	32线ZK3201孔577 m	细脉状石英黄铁矿	黄铁矿	11.46
ZK3201-340	32线ZK3201孔579 m	细脉状石英黄铁矿	黄铁矿	10.13
ZK3201-343	32线ZK3201孔583 m	细脉状石英黄铁矿	黄铁矿	10.94
ZK1603-391	16线ZK1603孔543.16 m	细脉状黄铁矿	黄铁矿	10.80
ZK1603-393	16线ZK1603孔546.16 m	网脉状石英黄铁矿	黄铁矿	10.80
ZK1603-395	16线ZK1603孔548.46 m	网脉状石英黄铁矿	黄铁矿	10.60
ZK1603-401	16线ZK1603孔555.06 m	网脉状石英黄铁矿	黄铁矿	10.30
ZK1603-403	16线ZK1603孔557.46 m	网脉状石英黄铁矿	黄铁矿	11.10
ZK1603-405	16线ZK1603孔560.26 m	网脉状石英黄铁矿	黄铁矿	10.90
ZK1603-407	16线ZK1603孔562.96 m	网脉状石英黄铁矿	黄铁矿	11.10
ZK1603-409	16线ZK1603孔565.86 m	网脉状石英黄铁矿	黄铁矿	11.20
ZK1603-411	16线ZK1603孔568.76 m	网脉状石英黄铁矿	黄铁矿	11.40
ZK1603-413	16线ZK1603孔571.76 m	网脉状石英黄铁矿	黄铁矿	10.90

下载: 导出CSV

表 2 前垂柳金矿床矿石铅同位素组成

Table 2. Lead isotope composition of the Qianchuiliu Gold Deposit

样品编号	测试矿物	²⁰⁶Pb/²⁰⁴Pb	²⁰⁷Pb/²⁰⁴Pb	²⁰⁸Pb/²⁰⁴Pb	μ	ω	κ	Δα	Δβ	Δγ
ZK1603-391	黄铁矿	17.149	15.482	37.860	9.41	40.58	4.17	62.22	15.29	52.05
ZK1603-392	黄铁矿	17.178	15.498	37.917	9.44	40.82	4.18	63.74	16.31	53.49
ZK1603-393	黄铁矿	17.941	15.540	38.432	9.40	38.61	3.98	67.17	15.45	44.73
ZK1603-394	黄铁矿	17.544	15.515	38.000	9.41	38.91	4.00	64.79	15.46	44.54
ZK1603-395	黄铁矿	17.390	15.497	37.995	9.40	39.71	4.09	63.23	14.96	48.55
ZK1603-399	黄铁矿	18.625	15.618	38.626	9.48	36.30	3.71	75.66	18.67	32.25
ZK1603-401	黄铁矿	17.753	15.535	38.227	9.42	38.81	3.99	66.68	15.91	45.01
ZK1603-402	黄铁矿	17.953	15.555	38.488	9.43	38.92	3.99	68.62	16.48	46.66
ZK1603-403	黄铁矿	18.886	15.677	39.676	9.57	39.56	4.00	88.21	22.39	58.86
ZK1603-404	黄铁矿	18.797	15.645	39.185	9.52	37.83	3.85	83.09	20.30	45.75
ZK1603-407	黄铁矿	18.019	15.566	38.600	9.44	39.11	4.01	69.75	17.01	48.16
ZK1603-408	黄铁矿	18.059	15.566	39.527	9.44	42.82	4.39	69.76	16.85	71.99
ZK1603-411	黄铁矿	18.474	15.644	40.073	9.54	43.26	4.39	77.88	20.95	77.37
ZK1603-412	黄铁矿	17.790	15.562	38.756	9.47	41.20	4.21	69.25	17.70	59.66
ZK1603-413	黄铁矿	18.552	15.613	39.395	9.48	39.72	4.05	75.00	18.52	54.87
注：Pb同位素特征参数μ为²³⁸U/²⁰⁴Pb、ω为²³²Th/²⁰⁴Pb、κ为Th/U、Δα为[α/α_m(t)-1]×1 000、Δβ为[β/β_m(t)-1]×1 000、Δγ为[γ/γ_m(t)-1]×1 000，其中α、β、γ为测定值、α_m(t)、β_m(t)、γ_m(t)为t时的地幔值，各参数使用GeoKit软件计算得到^[26-27]

下载: 导出CSV

参考文献(46)

[1]	郭云成, 段留安, 韩小梦, 等. 胶东前垂柳金矿区花岗岩锆石U-Pb年代学和地球化学特征及其地质意义[J]. 现代地质, 2022, 36(3): 876-897. https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ202203009.htm Guo Y C, Duan L A, Han X M, et al. Zircon U-Pb dating and geochemical characteristics of the granites from the the Qianchuiliu Gold Mining area in the Jiaodong Peninsula and its geological significance[J]. Geosciencs, 2022, 36(3): 876-897(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ202203009.htm
[2]	陈原林, 李欢, 郑朝阳, 等. 胶莱盆地龙口-土堆金矿床成因: 微量元素特征与C-H-O-S同位素约束[J]. 矿床地质, 2021, 40(5): 977-996. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ202105006.htm Chen Y L, Li H, Zheng C Y, et al. Genesis of Longkou-Tudui Gold Deposit, Jiaolai Basin: Constraints of trace element characteristics and C-H-O-S isotopes[J]. Mineral Deposits, 2021, 40(5): 977-996(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ202105006.htm
[3]	李大兜. 胶莱盆地东北缘龙口-土堆金矿区矿床成因及成矿模式研究[J]. 现代矿业, 2020, 36(9): 6-11. https://www.cnki.com.cn/Article/CJFDTOTAL-KYKB202009004.htm Li D D. Study on genesis and metallogenic model of Longkou-Tudui Gold Deposit in northeastern margin of Jiaolai Basin[J]. Modern Mining, 2020, 36(9): 6-11(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KYKB202009004.htm
[4]	赵宝聚, 高明波, 李亚东, 等. 胶莱盆地东北缘龙口-土堆矿区金矿床成矿规律研究[J]. 地质学报, 2019, 93(增刊1): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE2019S1001.htm Zhao B J, Gao M B, Li Y D, et al. Study on metallogenic regularity of gold deposits in Longkou-Tudui mining area on the northeastern margin of Jiaolai Basin[J]. Acta Geologica Sinica, 2019, 93(S1): 1-11(in Chinese wit-h English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE2019S1001.htm
[5]	宋明春, 杨立强, 范宏瑞, 等. 找矿突破战略行动十年胶东金矿成矿理论与深部勘查进展[J]. 地质通报, 2022, 41(6): 903-935. https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD202206001.htm Song M C, Yang L Q, Fan H R, et al. Current progress of metallogenic research and deep prospecting of gold deposits in the Jiaodong Peniusula during 10 years for exploration breakthrough strategic action[J]. Geological Bulletin of China, 2022, 41(6): 903-935(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD202206001.htm
[6]	丁正江, 孙丰月, 赵财胜, 等. 山东胶莱盆地东北缘地区金矿成矿系列[J]. 矿床地质, 2010, 29(增刊1): 919-920. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ2010S1460.htm Ding Z J, Sun F Y, Zhao C S, et al. Gold mineralization series in northeast margin of Jiaolai Basin, Shandong[J]. Mineral Deposits, 2010, 29(S1): 919-920(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ2010S1460.htm
[7]	Li J J, Zhang P P, Li G H, et al. Formation of the Liaoshang Gold Deposit, Jiaodong Peninsula, eastern China: Evidence from geochronology and geochemistry[J]. Geological Journal, 2020, 55: 5903-5913. doi: 10.1002/gj.3718
[8]	李国华, 丁正江, 纪攀, 等. 胶莱盆地东北缘地区金矿特征及找矿方向[J]. 地质与勘探, 2016, 52(6): 1029-1036. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKT201606003.htm Li G H, Ding Z J, Ji P, et al. Features and prospecting direction of the gold deposits in the northeastern margin of the Jiaolai Basin[J]. Geology and Exploration, 2016, 52(6): 1029-1036(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZKT201606003.htm
[9]	Tan J, Wei J H, He H Y, et al. Noble gases in pyrites from the Guocheng-Liaoshang gold belt in the Shandong Province: Evidencefor a mantle source of gold[J]. Chemical Geology, 2018, 480: 105-115. doi: 10.1016/j.chemgeo.2017.09.027
[10]	Zhang Y W, Hu F F, Fan H R, et al. Fluid evolution and gold precipitation in the Muping Gold Deposit(Jiaodong, China): Insights from in-situ trace elements and sulfur isotope of sulfides[J]. Journal of Geochemical Exploration, 2020, 218: 106617. doi: 10.1016/j.gexplo.2020.106617
[11]	耿科, 李大鹏. 胶东西涝口金矿深部110 Ma角闪辉长岩脉及其对成矿时代的约束[J]. 矿床地质, 2020, 39(6): 974-994. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ202006002.htm Geng K, Li D P. 110 Ma hornblende gabbro dyke in deep part of Xilaokou Gold Deposit, Jiaodong and its constraints on metallogenic time[J]. Mineral Deposit, 2020, 39(6): 974-994(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ202006002.htm
[12]	税棚. 胶莱盆地东北缘郭城-辽上金矿地质特征及成因机制[D]. 北京: 中国地质大学(北京), 2019. Shui P. Geological characteristics and genetic mechanism of Guocheng-Liaoshang Gold Mine on the northeast margin of Jiaolai Basin[D]. Beijing: China University of Geosciences (Beijing), 2019(in Chinese with English abstract).
[13]	Cheng N N, Hou Q L, Shi M Y, et al. New insight into the genetic mechanism of shear zone type gold deposits from Muping-Rushan metallogenic belt(Jiaodong Peninsula of Eastern China)[J]. Minerals, 2019, 9(12): 775. doi: 10.3390/min9120775
[14]	李国华, 丁正江, 宋明春, 等. 胶东新类型金矿: 辽上黄铁矿碳酸盐脉型金矿[J]. 地球学报, 2017, 38(3): 423-429. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201703012.htm Li G H, Ding Z J, Song M C, et al. The Liaoshang pyrite-carbonate veined deposit: A new type of gold deposit in Jiaodong Peninsula[J]. Acta Geoscientica Sinica, 2017, 38(3): 423-429(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201703012.htm
[15]	王德恩, 门业凯, 贾三石, 等. 胶东郭城金矿稀土元素地球化学特征及其对成矿的指示意义[J]. 稀土, 2014, 35(3): 6-12. https://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201403003.htm Wang D E, Men Y K, Jia S S, et al. REE geochemical characters of the Guocheng Gold Deposit, eastern Shandong Province and its significance to mineralizations[J]. Chinese Rare Earths, 2014, 35(3): 6-12(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201403003.htm
[16]	Tan J, Wei J H, Audétat A, et al. Source of metals in the Guocheng Gold Deposit, Jiaodong Peninsula, North China Craton: Link to Early Cretaceous mafic magmatism originating from Paleoproterozoic metasomatized lithospheric mantle[J]. Ore Geology Reviews, 2012, 48: 70-87. doi: 10.1016/j.oregeorev.2012.02.008
[17]	Liu X Y, Tan J, He H Y, et al. Origin of the Tudui-Shawang Gold Deposit, Jiaodong Peninsula, North China Craton: Constraints from fluid inclusion and H-O-He-Ar-S-Pb isotopic compositions[J]. Ore Geology Reviews, 2021, 35: 104-125. http://www.sciencedirect.com/science/article/pii/S0169136821001505
[18]	薄军委, 丁正江, 宋明春, 等. 胶东辽上金矿床C, O, S, Pb同位素组成及矿床成因[J]. 岩石矿物学杂志, 2021, 40(2): 321-336. https://www.cnki.com.cn/Article/CJFDTOTAL-YSKW202102010.htm Bo J W, Ding Z J, Song M C, et al. C, O, S and Pb isotopic compositions and genesis of the Liaoshang Gold Deposit in Jiaodong Peninsula[J]. Acta Petrologica et Mineralogica, 2021, 40(2): 321-336(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-YSKW202102010.htm
[19]	段留安, 魏有峰, 陈雄军, 等. 山东胶莱盆地东北缘前垂柳矿区金矿资源潜力分析[J]. 黄金科学技术, 2020, 28(5): 701-711. https://www.cnki.com.cn/Article/CJFDTOTAL-HJKJ202005013.htm Duan L A, Wei Y F, Chen X J, et al. Potential analysis of gold resources in Qianchuiliu mining area, northeast margin of Jiaolai Basin, Shandong Province[J]. Gold Science and Technology, 2020, 28(5): 701-711(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-HJKJ202005013.htm
[20]	Duan L A, Guo Y C, Han X M, et al. Discovery of a medium-scale tectonic altered rock type gold deposit (13.5 t) on the northeastern margin of Jiaolai Basin, Shandong Province, China and its new application of exploration direction[J]. China Geology, 2022, 5(3): 543-545. http://qikan.cqvip.com/Qikan/Article/Detail?id=7107948910
[21]	吕军阳, 胡秉谦, 王福江, 等. 山东省乳山市西涝口矿区金矿勘探报告[R]. 山东烟台: 山东省第六地质矿产勘查院, 2018. Lü J Y, Hu B Q, Wang F J, et al. Gold exploration report in Xilaokou Mine, Rushan City, Shandong Province[R]. Yantai, Shandong: The Sixth Geological and Mineral Exploration Institute of Shandong Province, 2018(in Chinese).
[22]	李国华, 王志新. 山东省烟台市牟平区辽上矿区深部及外围金矿勘探报告[R]. 山东烟台: 山东省第三地质矿产勘查院, 2016. Li G H, Wang Z X. Exploration report on deep and peripheral gold mine in Liaoshang Mining area, Muping district, Yantai City, Shandong Province[R]. Yantai, Shandong: Shandong Province Third Institute of Geology and Mineral Exploration, 2016(in Chinese).
[23]	Guo J H, Chen F K, Zhang X M, et al. Evolution of syn- to post-collisional magmatism from north Sulu UHP belt, eastern China: Zircon U-Pb geochronology[J]. Acta Petrologica Sinica, 2005, 21(4): 1281-1301. http://www.cqvip.com/qk/94579x/20054/20945053.html
[24]	Deng J, Yang L, Li R, et al. Regional structural control on the distribution of world-class gold deposits: An overview from the Giant Jiaodong Gold Province, China[J]. Geological Journal, 2019, 54(1): 378-391. http://www.onacademic.com/detail/journal_1000040283706310_c347.html
[25]	刘汉彬, 金贵善, 李军杰, 等. 铀矿地质样品的稳定同位素组成测试方法[J]. 世界核地质科学, 2013, 30(3): 174-179. https://www.cnki.com.cn/Article/CJFDTOTAL-GWYD201303011.htm Liu H B, Jin G S, Li J J, et al. Determination of stable isotope composition in uranium geological samples[J]. World Nuclear Geoscience, 2013, 30(3): 174-179(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-GWYD201303011.htm
[26]	路远发. GeoKit: 一个用VBA构建的地球化学工具软件包[J]. 地球化学, 2004, 33(5): 459-464. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200405003.htm Lu Y F. GeoKi: A geochemical toolkit for Microsoft Excel[J]. Geochimica, 2004, 33(5): 459-464(inChinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200405003.htm
[27]	吴开兴, 胡瑞忠, 毕献武, 等. 矿石铅同位素示踪成矿物质来源综述[J]. 地质地球化学, 2002, 30(3): 73-81. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200203012.htm Wu K X, Hu R Z, Bi X W, et al. Ore lead isotopes as a tracer for ore-forming material sources: a review[J]. Geology Geochemistry, 2002, 30(3): 73-81(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200203012.htm
[28]	于学峰, 张天祯, 王虹, 等. 山东省矿床成矿系列研究[J]. 矿床地质, 2016, 35(1): 169-184. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201601011.htm Yu X F, Zhang T Z, Wang H, et al. A study of minerogenetic series of mineral deposits in Shandong Province[J]. Mineral Deposits, 2016, 35(1): 169-184(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201601011.htm
[29]	吴开兴, 胡瑞忠, 毕献武, 等. 矿石铅同位素示踪成矿物质来源综述[J]. 地质地球化学, 2002(3): 73-81. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200203012.htm Wu K X, Hu R Z, Bi X W, et al. Ore lead isotopes as a tracer for ore-forming material sources: A review[J]. Geology Geochemistry, 2002(3): 73-81in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200203012.htm
[30]	Mao J W, Wang Y T, Li H M, et al. The relationship of mantle-derived fluids to gold metallogenesis in the Jiaodong Peninsula: Evidence from D-O-C-S isotope systematics[J]. Ore Geology Reviews, 2008, 33(3/4): 361-381. http://www.sciencedirect.com/science/article/pii/S0169136807000364
[31]	聂飞, 刘书生, 董国臣, 等. 辽西二道沟金矿成矿物质来源: 来自S-Pb同位素证据[J]. 现代地质, 2018, 32(6): 1283-1291. https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ201806016.htm Nie F, Liu S S, Dong G C, et al. The ore-forming material of the Erdaogou Gold Deposit in west Liaoning Province: Evidence from S-Pb isotopes[J]. Geoscience, 2018, 32(6): 1283-1291(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-XDDZ201806016.htm
[32]	柳志进, 张新勇, 戚静洁, 等. 胶东山后金矿流体包裹体及H-O-S同位素特征[J]. 地质科技情报, 2017, 36(6): 190-196. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201706021.htm Liu Z J, Zhang X Y, Qi J J, et al. Fluid inclusion and H-O-S isotope characters of Shanhou Gold Ore in Jiaodong[J]. Geological Science and Technology Information, 2017, 36(6): 190-196(in Chinese with English ab-stract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201706021.htm
[33]	孙兴丽. 山东胶莱盆地西涝口金矿床的特征和成因[D]. 北京: 中国地质大学(北京), 2014. Sun X L. Geological characteristics and genesis of the Xilaokou Gold Deposit in the margin of the Jiaolai Basin, Shandong[D]. Beijing: China University of Geosciences (Beijing), 2014(in Chinese with English abstract).
[34]	梁辉, 韩作振, 王立功, 等. 胶东辽上金矿床的流体包裹体、氢-氧-碳-硫-铅同位素特征及矿床成因[J]. 地质通报, 2022, 41(6): 1053-1067. https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD202206012.htm Liang H, Han Z Z, Wang L G, et al. The fluid inclusions, H-O-C-S-Pb isotopic characteristics and genesis of the Liaoshang Gold Deposit in Jiaodong Peninsula[J]. Geological Bulletin of China, 2022, 41(6): 1053-1067(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD202206012.htm
[35]	张连昌, 沈远超, 曾庆栋, 等. 山东中生代胶莱盆地北缘金矿床硫铅同位素地球化学[J]. 矿物岩石地球化学通报, 2001, 20(4): 380-384. https://www.cnki.com.cn/Article/CJFDTOTAL-KYDH200104048.htm Zhang L C, Shen Y C, Zeng Q D, et al. Sulfur and lead isotopic geochemistry of gold deposits at the northern margin of Jiaolai Basin, east Shandong[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2001, 20(4): 380-384(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KYDH200104048.htm
[36]	李杰, 安梦莹, 宋明春, 等. 胶东金矿硫同位素组成特征及其来源[J]. 地质通报, 2022, 41(6): 994-1008. https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD202206008.htm Li J, An M Y, Song M C, et al. Sulfur isotopic composition and its source of Jiaodong Gold Deposit[J]. Geological Bulletin of China, 2022, 41(6): 994-1008(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD202206008.htm
[37]	黄德业. 胶东金矿成矿系列硫同位素研究[J]. 矿床地质, 1994, 13(1): 75-87. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ401.007.htm Huang D Y. Study on the series of sulfur isotopes of Jiaodong Gold Mine[J]. Mineral Deposit, 1994, 13(1): 75-87(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ401.007.htm
[38]	张铭, 谭俊. 王怀洪, 等. 山东范家庄金矿床S-Pb同位素组成及对成矿物质来源的示踪[J]. 地质科技情报, 2019, 38(4): 124-133. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201904013.htm Zhang M, Tan J, Wang H H, et al. Sulfur and lead isotopic compositions of the Fanjiazhuang Gold Deposit and their implications for sources of ore-forming materials, Shandong Province[J]. Geological Science and Technology Information, 2019, 38(4): 124-133(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201904013.htm
[39]	李红梅, 魏俊浩, 王启, 等. 山东土堆-沙旺金矿床同位素组成特征及矿床成因讨论[J]. 地球学报, 2010, 31(6): 791-802. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201006004.htm Li H M, Wei J H, Wang Q, et al. Isotopic composition features and ore-forming mechanism of the Tudui-Shawang Gold Deposit in Shandong Province[J]. Acta Geoscientica Sinica, 2010, 31(6): 791-802(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201006004.htm
[40]	Raveggi M, Giles D, Foden J, et al. Lead and Nd isotopic evidence for a crustal Pb source of the giant Broken Hill Pb-Zn-Ag Deposit, New South Wales, Australia[J]. Ore Geology Reviews, 2015, 65(2): 228-244. http://www.sciencedirect.com/science?_ob=ShoppingCartURL&_method=add&_eid=1-s2.0-S016913681400225X&originContentFamily=serial&_origin=article&_ts=1469064534&md5=8845211368c6e932b70a2e5c165f9350
[41]	Stasey J S, Kramers J D. Approximation of terrestrial lead isotope evolution by a two stage model[J]. Earth and Planetary Science Letters, 1975, 26(2): 207-221. http://ieg.or.kr/include/file_down.php?save_path=/data1/ref&filename=00030026002000207.pdf&filename2=00030026002000207.pdf
[42]	Zartman R E, Doe B R. Plumbotectonics: The model[J]. Tectonophysics, 1981, 75(1/2): 135-162. http://www.sciencedirect.com/science/article/pii/0040195181902134
[43]	朱炳泉, 李献华, 戴谟, 等. 地球科学中同位素体系理论与应用: 兼论中国大陆壳幔演化[M]. 北京: 科学出版社, 1998: 216-230. Zhu B Q, Li X H, Dai M, et al. Theory and application of isotope system in earth science: On Chinese mainland shell and mantle evolution[M]. Beijing: Science Press, 1998: 216-230(in Chinese).
[44]	杨立强, 邓军, 王中亮, 等. 胶东中生代金成矿系统[J]. 岩石学报, 2014, 30(9): 2447-2467. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201409001.htm Yang L Q, Deng J, Wang Z L, et al. Mesozoic gold metallogenic system of the Jiaodong Gold Province, eastern China[J]. Acta Petrologica Sinica, 2014, 30(9): 2447-2467(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201409001.htm
[45]	梁亚运, 刘学飞, 李龚健, 等. 胶东地区脉岩成因与金成矿关系的研究: 年代学及Sr-Nd-Pb同位素的约束[J]. 地质科技情报, 2014, 33(3): 10-24. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201403003.htm Liang Y Y, Liu X F, Li G J, et al. Petrogenesis and connection with gold deposits of dikes in Jiaodong Peninsula, eastern of North China Craton: Constraint on geochronology and Sr-Nd-Pb isotope[J]. Geological Science and Technology Information, 2014, 33(3): 10-24(in Chinese with English abstract). https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201403003.htm
[46]	Goss S C, Wilde S A, Wu F Y, et al. The age, isotopic signature and significanee of the youngest Mesozoic granitoids in the Jiaodong terrane, Shandong Province, North China Craton[J]. Lithos, 120(3/4): 309-326. http://www.sciencedirect.com/science?_ob=ShoppingCartURL&_method=add&_eid=1-s2.0-S0024493710002215&originContentFamily=serial&_origin=article&_ts=1491946587&md5=f6e5721a5daa60eba1868ec8b3fec8ae