胶莱盆地东北缘前垂柳金矿床S、Pb同位素组成：对成矿物质来源的指示

韩小梦; 郭云成; 段留安; 王建田; 赵鹏飞; 王利鹏; 喻光明

doi:10.19509/j.cnki.dzkq.tb20220659

胶莱盆地东北缘前垂柳金矿床S、Pb同位素组成：对成矿物质来源的指示

doi: 10.19509/j.cnki.dzkq.tb20220659

1.
中国地质调查局烟台海岸带地质调查中心, 山东烟台 264000
2.
自然资源部深部金矿勘查开采技术创新中心/山东省深部金矿探测大数据应用开发工程实验室, 山东威海 264209
3.
中国地质调查局自然资源综合调查指挥中心, 北京 100032

基金项目:

国家重点研发计划 2022YFC2903605

中国地质调查局金矿重点勘查区资源潜力评价工程项目“山东牟平辽上金矿资源潜力评价” DD20230392

重点勘查区战略性矿产资源勘查工程“胶西北地区金矿资源勘查”项目 ZD20220315

详细信息

作者简介:
韩小梦(1987—), 男, 工程师, 主要从事矿产勘查、矿床学研究工作。E-mail: 943062435@qq.com

通讯作者:
段留安(1976—), 男, 正高级工程师, 主要从事矿产勘查、矿床地球化学等方面研究工作。E-mail: liuanduan@163.com

中图分类号: P618.51
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出版历程
- 收稿日期: 2022-11-25

S and Pb isotopic compositions of the Qianchuiliu Gold Deposit on the northeastern margin of the Jiaolai Basin: Implication on the source of ore-forming material

1.
Yantai Geological Survey Center of Coastal Zone, China Geological Survey, Yantai Shandong 264000, China
2.
Ministry of Natural Resources Technology Innovation Center for Deep Gold Resources Exploration and Mining/Shandong Provincial Engineering Laboratory of Application and Development of Big Data for Deep Gold Exploration, Weihai Shandong 264209, China
3.
Command Center of Natural Resources Comprehensive Survey, China Geological Survey, Beijing 100032, China

摘要

摘要:
前垂柳金矿为胶东胶莱盆地东北缘新发现的蚀变岩型金矿床，金矿体主要赋存于牧牛山岩体(二长花岗岩)、荆山群地层和鹊山岩体(糜棱岩化二长花岗岩)之间厚大的构造蚀变带内，截止目前推测资源量达到中型规模，但矿床的成矿物质来源尚不明确。基于前人研究及野外调查，选择典型矿体中含金黄铁矿作为研究对象，开展了S、Pb同位素分析，探讨了矿床的成矿物质来源。测试结果显示：矿石硫化物δ³⁴S值总体为10.13‰~12.39‰，极差为2.26‰，平均值10.98‰，均一程度高，具高δ³⁴S值特征，反映了深部成矿流体上侵过程中混染了更多的地层中的硫，显示了荆山群地层对成矿有一定贡献；矿石铅同位素²⁰⁶Pb/²⁰⁴Pb比值为17.149~18.886，²⁰⁷Pb/²⁰⁴Pb比值为15.482~15.677，²⁰⁸Pb/²⁰⁴Pb比值为37.860~40.073，显示前垂柳金矿铅为壳幔混合来源，且具有下地壳铅的特征。该矿床S、Pb同位素特征显示成矿物质来源为壳幔混源，与周边辽上、蓬家夼等典型矿床成矿物质来源一致，反映了该区燕山期大规模成矿事件，预示了胶莱盆地东北缘具有较大的找矿潜力。
- 胶莱盆地东北缘 /
- 前垂柳金矿 /
- S同位素 /
- Pb同位素 /
- 物质来源
Abstract:
The Qianchuiliu Gold Deposit on the northeastern margin of the Jiaolai Basin is a newly discoverd altered rock type gold deposit, and is a medium-sized gold deposit hosted in the structural alteration zone between Muniushan, Jingshan Group and Queshan monzonitic granites. However, the source of ore-forming materials and the ore genesis are not clear. Based on previous field and analytical studies, the authors conducted sulfur and lead isotopic analyses on gold-bearing pyrite from typical ores as the research target. The δ³⁴S values are high and homogeneous ranging from 10.13‰-12.39‰, with an average of 10.98‰ and polar odds of 2.26‰. These sulfur isotopic results reveal a mixing process of sulfur in the Jingshan Group during the upwelling of deep ore-forming fluid. The ratios of ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb vary from 17.149-18.886, 15.482-15.677, and 37.860-40.073, respectively, suggesting a crust-mantle mixed source. In conclusion, sulfur and lead isotope analysis results of the Qianchuiliu Gold Deposit show a crust-mantle mixed source and are similar to those of typical gold deposits in this region. The gold deposits on the northeastern margin of the Jiaolai Basin formed at the large-scale Yanshanian metallogenic event, indicating great prospecting potential in this area.
- northeastern margin of the Jiaolai Basin /
- Qianchuiliu Gold Deposit /
- sulfur isotope /
- lead isotope /
- material source

HTML全文

图 1 前垂柳金矿区及周边金矿区地质简图^[1]

1.水库；2.第四系；3.下白垩统陆相沉积岩、火山岩；4.古元古界变质岩；5.前寒武纪侵入岩；6.晚侏罗世二长花岗岩；7.早白垩世花岗闪长岩；8.燕山晚期岩脉；9.地质界线；10.断裂；11.韧性剪切带；12.金矿床(点)；13.钼矿床；14.铜矿点；15.铅锌矿点；16.胶莱盆地东北缘前垂柳矿区位置；Ⅰ.华北板块；Ⅰ₁.胶莱-胶北断隆；Ⅰ₁¹.胶北断隆；Ⅰ₁².胶莱断陷；Ⅱ.秦岭-大别-苏鲁碰撞造山带；Ⅱ₁.胶南-威海断隆；Ⅱ₁¹.文登-威海断拱；Ⅱ₁².胶莱断陷；Ⅱ₁³.胶南-临沭断拱

Figure 1. Geological map of the Qianchuiliu Gold Mining area and nearby gold mineral deposits

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图 2 前垂柳金矿区16线和32线钻孔剖面图

Figure 2. Drilling profile of Line 16 and Line 32 in the Qianchuiliu Gold Mine area

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图 3 前垂柳金矿床矿石照片和显微照片

Figure 3. Photographs and photomicrographs of the Qianchuiliu Gold Deposit

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图 4 胶莱盆地东北缘典型金矿床硫化物δ³⁴S值对比分布图(图中数据综合本文及文献[31-37])

Figure 4. Distribution of sulfide δ³⁴S values of typical gold deposits on northeastern margin of the Jiaolai Basin

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图 5 前垂柳金矿床与区域典型金矿床硫同位素对比直方图(图中数据综合本文及文献[31-37])

Figure 5. Comporing histograms of sulfur isotopes in the Qianchuiliu Gold Deposit and regional gold deposits

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图 6 前垂柳金矿床矿石铅同位素模式图(a~b)及构造环境判别图(c~d)(底图据文献[42]; 投影点数据综合本文及文献[33-39])

Figure 6. Plumbotectonic model of lead isotope (a-b) and diagram for discriminating the tectonic setting (c-d) of the Qianchuiliu Gold Deposit

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图 7 前垂柳金矿床矿石铅同位素Δγ-Δβ成因判别图解(底图据文献[42]; 投影点数据综合本文及文献[33-39])

1.地幔源铅; 2.上地壳源铅; 3.上地壳与地幔混合的俯冲铅: 3a.岩浆作用铅; 3b.沉积作用铅; 4.化学沉积型铅; 5.海底热水作用铅; 6.中深变质作用Pb; 7.深变质下地壳铅; 8.造山带铅; 9.古老页岩上地壳铅; 10.退变质铅

Figure 7. Δγ-Δβ genetic classification diagram showing ore mineral lead isotopic distribution in the Qianchuiliu Gold Deposit

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表 1 前垂柳金矿床矿石硫同位素组成

Table 1. Sulfur isotope composition of the Qianchuiliu Gold Deposit

样品编号	采样位置	矿石中黄铁矿赋存特征	测试矿物	δ³⁴S/%
ZK3201-64	32线ZK3201孔117.2 m	细脉状黄铁矿	黄铁矿	11.20
ZK3201-97	32线ZK3201孔204.2 m	条带状黄铁矿	黄铁矿	11.23
ZK3201-128	32线ZK3201孔258.2 m	细脉状石英自形黄铁矿	黄铁矿	10.28
ZK3201-131	32线ZK3201孔262.1 m	细脉状石英黄铁矿	黄铁矿	12.39
ZK3201-338	32线ZK3201孔577 m	细脉状石英黄铁矿	黄铁矿	11.46
ZK3201-340	32线ZK3201孔579 m	细脉状石英黄铁矿	黄铁矿	10.13
ZK3201-343	32线ZK3201孔583 m	细脉状石英黄铁矿	黄铁矿	10.94
ZK1603-391	16线ZK1603孔543.16 m	细脉状黄铁矿	黄铁矿	10.80
ZK1603-393	16线ZK1603孔546.16 m	网脉状石英黄铁矿	黄铁矿	10.80
ZK1603-395	16线ZK1603孔548.46 m	网脉状石英黄铁矿	黄铁矿	10.60
ZK1603-401	16线ZK1603孔555.06 m	网脉状石英黄铁矿	黄铁矿	10.30
ZK1603-403	16线ZK1603孔557.46 m	网脉状石英黄铁矿	黄铁矿	11.10
ZK1603-405	16线ZK1603孔560.26 m	网脉状石英黄铁矿	黄铁矿	10.90
ZK1603-407	16线ZK1603孔562.96 m	网脉状石英黄铁矿	黄铁矿	11.10
ZK1603-409	16线ZK1603孔565.86 m	网脉状石英黄铁矿	黄铁矿	11.20
ZK1603-411	16线ZK1603孔568.76 m	网脉状石英黄铁矿	黄铁矿	11.40
ZK1603-413	16线ZK1603孔571.76 m	网脉状石英黄铁矿	黄铁矿	10.90

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表 2 前垂柳金矿床矿石铅同位素组成

Table 2. Lead isotope composition of the Qianchuiliu Gold Deposit

样品编号	测试矿物	²⁰⁶Pb/²⁰⁴Pb	²⁰⁷Pb/²⁰⁴Pb	²⁰⁸Pb/²⁰⁴Pb	μ	ω	κ	Δα	Δβ	Δγ
ZK1603-391	黄铁矿	17.149	15.482	37.860	9.41	40.58	4.17	62.22	15.29	52.05
ZK1603-392	黄铁矿	17.178	15.498	37.917	9.44	40.82	4.18	63.74	16.31	53.49
ZK1603-393	黄铁矿	17.941	15.540	38.432	9.40	38.61	3.98	67.17	15.45	44.73
ZK1603-394	黄铁矿	17.544	15.515	38.000	9.41	38.91	4.00	64.79	15.46	44.54
ZK1603-395	黄铁矿	17.390	15.497	37.995	9.40	39.71	4.09	63.23	14.96	48.55
ZK1603-399	黄铁矿	18.625	15.618	38.626	9.48	36.30	3.71	75.66	18.67	32.25
ZK1603-401	黄铁矿	17.753	15.535	38.227	9.42	38.81	3.99	66.68	15.91	45.01
ZK1603-402	黄铁矿	17.953	15.555	38.488	9.43	38.92	3.99	68.62	16.48	46.66
ZK1603-403	黄铁矿	18.886	15.677	39.676	9.57	39.56	4.00	88.21	22.39	58.86
ZK1603-404	黄铁矿	18.797	15.645	39.185	9.52	37.83	3.85	83.09	20.30	45.75
ZK1603-407	黄铁矿	18.019	15.566	38.600	9.44	39.11	4.01	69.75	17.01	48.16
ZK1603-408	黄铁矿	18.059	15.566	39.527	9.44	42.82	4.39	69.76	16.85	71.99
ZK1603-411	黄铁矿	18.474	15.644	40.073	9.54	43.26	4.39	77.88	20.95	77.37
ZK1603-412	黄铁矿	17.790	15.562	38.756	9.47	41.20	4.21	69.25	17.70	59.66
ZK1603-413	黄铁矿	18.552	15.613	39.395	9.48	39.72	4.05	75.00	18.52	54.87
注：Pb同位素特征参数μ为²³⁸U/²⁰⁴Pb、ω为²³²Th/²⁰⁴Pb、κ为Th/U、Δα为[α/α_m(t)-1]×1 000、Δβ为[β/β_m(t)-1]×1 000、Δγ为[γ/γ_m(t)-1]×1 000，其中α、β、γ为测定值、α_m(t)、β_m(t)、γ_m(t)为t时的地幔值，各参数使用GeoKit软件计算得到^[26-27]

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