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湖北宜昌产气页岩氧化溶蚀增渗的地球化学影响

余奇 刘丹青 刘方 张泽星

余奇, 刘丹青, 刘方, 张泽星. 湖北宜昌产气页岩氧化溶蚀增渗的地球化学影响[J]. 地质科技通报, 2024, 43(5): 117-130. doi: 10.19509/j.cnki.dzkq.tb20230204
引用本文: 余奇, 刘丹青, 刘方, 张泽星. 湖北宜昌产气页岩氧化溶蚀增渗的地球化学影响[J]. 地质科技通报, 2024, 43(5): 117-130. doi: 10.19509/j.cnki.dzkq.tb20230204
YU Qi, LIU Danqing, LIU Fang, ZHANG Zexing. Geochemical factors affecting oxidation dissolution and permeability enhancement of Yichang gas-producing shale in Hubei Province[J]. Bulletin of Geological Science and Technology, 2024, 43(5): 117-130. doi: 10.19509/j.cnki.dzkq.tb20230204
Citation: YU Qi, LIU Danqing, LIU Fang, ZHANG Zexing. Geochemical factors affecting oxidation dissolution and permeability enhancement of Yichang gas-producing shale in Hubei Province[J]. Bulletin of Geological Science and Technology, 2024, 43(5): 117-130. doi: 10.19509/j.cnki.dzkq.tb20230204

湖北宜昌产气页岩氧化溶蚀增渗的地球化学影响

doi: 10.19509/j.cnki.dzkq.tb20230204
基金项目: 

国家自然科学基金青年基金项目“产气页岩氧化溶蚀增渗过程中黄铁矿的影响机理研究” 41902253

详细信息
    作者简介:

    余奇, E-mail: yuqi@cug.edu.cn

    通讯作者:

    刘丹青, E-mail: liudq@cug.edu.cn

  • 中图分类号: TE37

Geochemical factors affecting oxidation dissolution and permeability enhancement of Yichang gas-producing shale in Hubei Province

More Information
  • 摘要:

    为探究湖北宜昌地区产气页岩氧化溶蚀增渗的地球化学影响因素, 以宜昌地区陡山沱组页岩为研究对象, 选取了H2O2(wB=15%)和Na2S2O8(cB=0.5 mol/L)2种氧化剂开展了氧化溶蚀实验, 探究了不同pH值、温度、地下水水化学离子浓度对氧化溶蚀效果的影响。研究结果表明, Na2S2O8氧化溶蚀效果优于H2O2, H2O2和Na2S2O8在酸性条件下氧化溶蚀效果均优于碱性条件, 碱性环境不利于2种氧化剂的氧化; 升温会促进Na2S2O8和H2O2的热分解, 分别产生H2SO4和O2, 对页岩的氧化溶蚀有积极影响。外源Na+(氯化物)的添加能促进页岩在Na2S2O8和H2O2氧化过程下Ca2+和Mg2+的释放, 增强氧化溶蚀效果; 而外源Ca2+、SO42-的添加, 容易与碳酸盐酸蚀产生的SO42-、Ca2+形成石膏沉淀, 从而引起页岩孔隙堵塞, 降低页岩渗透性; 同时, 外源Mg2+易在弱碱性环境下生成硅酸镁沉淀, 对页岩的氧化溶蚀产生负面影响。建议今后在页岩气氧化压裂开采过程中, 预先调查开采地层的水化学参数, 根据地层温度、pH值和阴阳离子来选择氧化液和开采方式。

     

  • 图 1  湖北宜昌地区地质构造简图[31]

    Nh.南华系; Z.震旦系; ∈.寒武系; O.奥陶系; S.志留系; D.泥盆系; P.二叠系; T.三叠系; J.侏罗系; K.白垩系; E.古近系

    Figure 1.  Sketch map of tectonics in the Yichang area, Hubei Province

    图 2  不同氧化剂处理页岩后质量损失(a)和离子质量浓度(b)随初始pH值的变化

    Figure 2.  Mass loss(a) and ion concentration(b) with initial pH after shale treatment with different oxidants

    图 3  不同氧化剂氧化页岩后质量损失(a)、pH(b)、Ca2+(c)及Mg2+质量浓度(d)随温度的变化

    Figure 3.  Mass loss(a), pH(b), Ca2+ concentration(c), Mg2+ concentration(d) changes with temperature after shale oxidation with different oxidants

    图 4  不同氧化剂氧化页岩后质量损失(a)、Eh值(b)、Fe2+(c)、Ca2+和Mg2+质量浓度(d)随外源Na+质量浓度的变化

    Figure 4.  Mass loss(a), Eh(b), Fe2+ concentration(c), Ca2+ concentration and Mg2+ concentration(d) changes with the exogenous Na+ concentration after shale oxidation with different oxidants

    图 5  不同氧化剂氧化页岩后质量损失(a)、Eh值和pH值(b)、Fe2+(c)、Ca2+和Mg2+质量浓度(d)随外源Ca2+质量浓度的变化

    Figure 5.  Mass loss(a), Eh and pH(b), Fe2+ concentration(c), Ca2+ concentration and Mg2+ concentration(d) changes with the exogenous Ca2+ concentration after shale oxidation with different oxidants

    图 6  不同氧化剂氧化页岩后质量损失(a)、Ca2+和Mg2+质量浓度(b)随外源Mg2+质量浓度的变化

    Figure 6.  Mass loss(a), Ca2+ concentration and Mg2+ concentration(b) changes with the exogenous Mg2+ concentration after shale oxidation with different oxidants

    图 7  不同氧化剂氧化页岩后质量损失(a)、Ca2+和Mg2+质量浓度(b)随外源SO42-质量浓度的变化

    Figure 7.  Mass loss(a), Ca2+ concentration and Mg2+ concentration(b) changes with the exogenous SO42- concentration after shale oxidation with different oxidants

    图 8  原岩及氧化后固体产物XRD分析图

    Q.石英; D.白云石; P.黄铁矿; A.钠长石; I.伊利石; Ch.绿泥石; G.石膏

    Figure 8.  XRD analysis of original rock and oxidized solid products

    图 9  酸性条件下产气页岩氧化溶蚀增渗机理作用图

    Figure 9.  Oxidation dissolution and permeability mechanism action diagram of gas producing shale under acidic conditions

    图 10  碱性条件下产气页岩氧化溶蚀增渗机理作用图

    Figure 10.  Oxidation dissolution and permeability mechanism action diagram of gas producing shale under alkaline conditions

    图 11  高温下产气页岩氧化溶蚀增渗机理作用图(仅考虑分解产物造成的一次反应)

    Figure 11.  Oxidation dissolution and permeability mechanism diagram of gas producing shale at high temperature(only considering the first reaction caused by decomposition products)

    表  1  湘鄂西区海相地层水化学参数统计

    Table  1.   Statistical table of chemical parameters in marine formation water in western Hunan and Hubei Provinces ρB/(mg·L-1)

    储层 井号 Na+ Ca2+ Mg2+ Cl- SO42- HCO3- 矿化度 水型
    震旦系 宜3 1 597.90 568.45 201.98 1 156.11 3 786.30 166.43 7 460.50 SO4-Na
    宜4 1 746.16 534.93 179.88 1 138.98 3 954.10 175.95 7 730.27 SO4-Na
    宜7 1 590.27 538.69 194.54 1 083.88 3 783.06 153.77 7 348.37 SO4-Na
    宜8 1 675.00 550.00 203.00 1 238.00 3 749.00 245.00 7 660.00 SO4-Na
    均值(ρ) 1 652.33 548.02 194.85 1 154.24 3 818.12 185.29 7 549.79 SO4-Na
    下载: 导出CSV

    表  2  实验设计

    Table  2.   Experimental design

    组别 pH值 温度/℃ 阴阳离子 质量浓度ρB
    A 1,2,3,7,9,11 25
    B 25,45,60
    C 25 Na+ 0,0.5ρρ,1.5ρ,2ρ
    Ca2+
    Mg2+
    SO42-
    下载: 导出CSV
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  • 收稿日期:  2023-04-17
  • 录用日期:  2023-07-19
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