地球物质科学的基本原理: 固体地球科学中的热力学研究历史与展望

王超; 渠淼; 喻慧阳

doi:10.19509/j.cnki.dzkq.tb20230210

地球物质科学的基本原理: 固体地球科学中的热力学研究历史与展望

doi: 10.19509/j.cnki.dzkq.tb20230210

王超^{a, b, ,},
渠淼^{a, b},
喻慧阳^c

a.
西北大学大陆动力学国家重点实验室, 西安 710069
b.
西北大学地质学系, 西安 710069
c.
西北大学马克思主义学院, 西安 710069

基金项目:

国家自然科学基金项目 42272054

国家自然科学基金项目 42030307

大陆动力学国家重点实验室(西北大学)团队重点项目

详细信息

通讯作者:
王超, E-mail: chaowang@nwu.edu.cn

中图分类号: P5
计量
- 文章访问数: 410
- PDF下载量: 108
- 被引次数: 0
出版历程
- 收稿日期: 2023-04-19
- 录用日期: 2023-07-05
- 修回日期: 2023-06-09

Principle of Earth materials: A historical perspective of thermodynamics of the Earth

WANG Chao^{a, b
, ,},
QU Miao^{a, b},
YU Huiyang^c

a.
State Key Laboratory of Continental Dynamics, Northwest University, Xi'an 710069, China
b.
Department of Geology, Northwest University, Xi'an 710069, China
c.
School of Marxism, Northwest University, Xi'an 710069, China

More Information

Corresponding author: WANG Chao, E-mail: chaowang@nwu.edu.cn

摘要

摘要:
地球是一种物质和能量结合的存在形式。地球及其他行星的形成和运作过程实际上是物质和能量状态的演化历史。研究物质的科学是物理和化学, 描述物质自然规律的语言是数学, 这属于热力学的研究范畴。从19世纪中叶开尔文利用热力学理论计算地球年龄开始, 热力学在地球科学领域的应用已有100多年历史, 它在阐释地球和行星演化过程的基本逻辑与规律方面发挥了核心作用, 引起了固体地球科学发展史中的许多重要变革。近20年来, 随着物理、化学和计算机科学的不断发展, 经典热力学和非平衡热力学在地球物质科学中的应用进一步发展, 成为地球物质研究的基本原理体系。通过研究地球物质的形成与演化条件来揭示地球结构、动力学和演化过程的地球热力学学科已经形成。未来地球热力学的发展需要与地球物理、地球化学理论和实验相结合, 在热力学数据库发展的基础上, 建立合适的热力学模型来解决实际的地球科学问题。另外, 地球热力学的进一步发展需要与相应的课程教学相结合、加强热力学在地球科学中的课程建设是当前的一项重要任务。热力学是地球物理、地球化学、地质学等多学科交叉研究的纽带和桥梁。如何从热力学的视角认识地球及其演变过程将会是一个永恒课题。
- 地球物质科学 /
- 热力学 /
- 非平衡热力学 /
- 地球系统科学
Abstract: <p>Earth is a combination of material and energy. The evolution of Earth and planets is a history of the transfer of matter and energy. Materials science is codified into physics and chemistry, while mathematics is the language that describes the law of nature, which belongs to the field of thermodynamics.</p></sec><sec><title>Significance
Thus, thermodynamics, consisting of physics, chemistry and mathematics, can unravel the principles of earth materials. Since the middle of the 19th century, Kelvin used thermodynamic theory to calculate the age of the Earth, and thermodynamics has been applied in the field of earth science for more than 100 years, which has provided a vital theoretical framework for understanding the planet's formation and evolution. Its application revolutionized the development of earth science.
Progress
In the past 20 years, with the development of physics, chemistry and computer science, the application and development of classical thermodynamics and nonequilibrium thermodynamics in earth matter science have further improved and become the fundamental principal system of earth material research. The thermodynamics of earth have been studied to determine the structure, dynamics and evolution of earth by studying the formation and evolution of earth materials. Thermodynamics links geophysics, geochemistry and geology. However, new thermodynamic models, databases, and methods for teaching and learning about thermodynamics in earth science need to be developed.
Conclusions and Prospects
It is foreseeable that understanding the earth and its evolution from the perspective of thermodynamics will be a permanent issue. Thermodynamics will exert its power in unknown fields such as planetary science, earth's internal evolution as well as earth systems science, driving people to make new observations and theories about nature.
- Earth materials /
- thermodynamics /
- non-equilibrium thermodynamics /
- Earth system
注释:

所有作者声明不存在利益冲突。

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图 1 地球系统中的热力学示意图(其指示不同体系之间的能量转化关系(左侧实线)和效应(右侧虚线)(据文献[1]修改))

Figure 1. A planetary thermodynamic view of the Earth system, with its cascades of energy conversion(left, solid lines) and its effects(right, dashed lines)

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图 2 KFMASH体系P-T视剖面图(据文献[15]修改)

chl.绿泥石; bi.黑云母; st.十字石; g.石榴石; ky.蓝晶石; sill.夕线石

Figure 2. P-T pseudosection in KFMASH(+mu+q+H₂O) for a "common" pelite composition: Al₂O₃=41.89, MgO=18.19, FeO=27.29, and K₂O=12.63(in mol%).Water activity=1

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图 3 岩浆储库中不同过程MCS模拟的岩浆主量元素变化图解(详见文献[20])

FC.分离结晶; AFC.部分混染分离结晶; R₂FC.补给分离结晶; S₂FC.同化混染分离结晶; R₂AFC.补给混染分离结晶

Figure 3. Results of MCS simulations for five cases(FC, AFC, R₂FC, S₂FC, and R₂AFC) shown in SiO₂(%) magma melt versus TiO₂(a), Al₂O₃(b), Fe₂O₃(c), FeO(d), MgO(e), and CaO(f)

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图 4 地幔矿物的热容(C_P)^[22]

capv.立方CaSiO₃钙钛矿; ri.林伍德石; ak.阿基墨石; hpcpx.高压单斜辉石; ol.橄榄石; opx.斜方辉石; cpx.单斜辉石; sp.尖晶石; gt.石榴石; fp.铁方镁石; wa.瓦兹利石; st.斯石英; nal.新型六方铝相; bg.布里奇曼石

Figure 4. Heat capacity C_P. The lines representing phase transitions are suppressed so as not to obscure the properties of narrow phase transitions.HeFESTo was computed on a regular pressure-temperature grid with spacings of 0.01 GPa and 1 K

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图 5 地球科学中的主要热力学数据库和模拟软件(修改自文献[45])

Figure 5. Map showing the principal thermodynamic databases and modelling tools in earth science

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图 6 石榴石生长理论模型^[66]

a.石榴石开始在相互连接且流体充填的空间平衡生长，允许一定的连续元素通量(左图)。稀土元素通过分数平衡结晶进入石榴石(中图)。石榴石中的REE浓度遵循右图中的粗体黑线；b.岩石的渗透性下降，导致孔隙空间的封闭和反应岩石区域的隔离(左图)。此阶段的石榴石生长导致石榴石(中图)中的REE快速减少，这导致HREE谷(右图)的发展；c.由于岩石发生脱水反应，岩石渗透性增加(左图)。渗透性的增加重新发生流体渗透，从而补充可用于石榴石生长的稀土元素(中图)。石榴石中的稀土含量返回到初始连续背景元素通量(右图)；d.上述步骤的重复以及钛铁矿-金红石的转变导致样品中观察到的复杂REE环带和REE分配模式

Figure 6. Conceptual model of garnet growth

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