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历史遗留锰矿山老窑水来源及水体污染成因解析

巫政卿 罗明明 李宁 魏世毅 李大星 皮景 欧任文

巫政卿, 罗明明, 李宁, 魏世毅, 李大星, 皮景, 欧任文. 历史遗留锰矿山老窑水来源及水体污染成因解析[J]. 地质科技通报, 2024, 43(5): 225-234. doi: 10.19509/j.cnki.dzkq.tb20230334
引用本文: 巫政卿, 罗明明, 李宁, 魏世毅, 李大星, 皮景, 欧任文. 历史遗留锰矿山老窑水来源及水体污染成因解析[J]. 地质科技通报, 2024, 43(5): 225-234. doi: 10.19509/j.cnki.dzkq.tb20230334
WU Zhengqing, LUO Mingming, LI Ning, WEI Shiyi, LI Daxing, PI Jing, OU Renwen. Identification of the sources of old kiln water and the causes of water pollution in the historical manganese mine[J]. Bulletin of Geological Science and Technology, 2024, 43(5): 225-234. doi: 10.19509/j.cnki.dzkq.tb20230334
Citation: WU Zhengqing, LUO Mingming, LI Ning, WEI Shiyi, LI Daxing, PI Jing, OU Renwen. Identification of the sources of old kiln water and the causes of water pollution in the historical manganese mine[J]. Bulletin of Geological Science and Technology, 2024, 43(5): 225-234. doi: 10.19509/j.cnki.dzkq.tb20230334

历史遗留锰矿山老窑水来源及水体污染成因解析

doi: 10.19509/j.cnki.dzkq.tb20230334
基金项目: 

湖南省自然资源厅地质调查项目 2022002

湖南省科技厅重大科技攻关项目 2023ZJ1090

国家自然科学基金项目 42172276

详细信息
    作者简介:

    巫政卿, E-mail: 593086206@qq.com

    通讯作者:

    罗明明, E-mail: luomingming@cug.edu.cn

  • 中图分类号: X523

Identification of the sources of old kiln water and the causes of water pollution in the historical manganese mine

More Information
  • 摘要:

    历史遗留矿山的老窑水防治是矿山水环境治理中的难点。选取中国锰三角地区的典型锰矿区为研究对象,以查明老窑水的来源及水体污染成因。综合利用矿山水文地质调查、气象水文分析、水化学与同位素溯源等技术方法对老窑水来源和特征污染物进行了识别,并分析了矿区的水体污染成因模式。结果表明:研究区老窑水动态对降雨响应灵敏,老窑水主要来源于巷道和优势径流通道汇集的大气降水和含水层中的地下水;矿区矿井水、巷道水中的特征污染物为硫酸锰,矿山排水的特征污染物为硫酸钠,硫酸锰主要由硫铁矿氧化和菱锰矿溶解而形成;矿山固体废弃物淋滤入渗和老窑水的混合是区内地下水的主要污染方式,而地表水主要受矿山固体废弃物淋滤汇流、巷道口排水和矿山排水的污染。研究成果为矿山水环境治理提供了水量形成和水质演化的科学依据。

     

  • 图 1  研究区水文地质略图及采样点分布

    Q.第四系; ∈3-4ls.寒武系娄山关组; ∈3g.寒武系高台组; ∈2q.寒武系清虚洞组; ∈1-2s.寒武系石牌组; ∈1n.寒武系牛蹄塘组; Z2dy.震旦系灯影组; Z1d.震旦系陡山沱组; Nh2n南华系南沱组; Nh1d.南华系大塘坡组; Nh1g.南华系古城组; Qbw.青白口系五强溪组; Qbm.青白口系马底驿组

    Figure 1.  Schematic hydrogeological map and sampling points in study area

    图 2  研究区水文地质剖面图(地层代号详见正文)

    Figure 2.  Hydrogeological cross-section of the study area

    图 3  研究区水体氘氧同位素分布图

    Figure 3.  Distribution plots of δD vs. δ18O of water in the study area

    图 4  2022年研究区矿井水位和排水量与降雨量响应关系图

    Figure 4.  Plots of rainfall with water level in mine pit and mine drainage of the study area at 2022

    图 5  研究区各水样典型水化学指标质量浓度箱线图

    Figure 5.  Box line graph of chemical index concentration of water samples in the study area

    图 6  矿区各水样水化学Piper三线图

    Figure 6.  Piper diagram of water chemistry of water samples in the mining area

    图 7  矿区水体离子比值趋势图

    Figure 7.  Trends of ion ratio of water samples in the mining area

    图 8  矿区地下水污染模式概念图(地层代号见正文)

    a.矿山固体废弃物淋滤入渗污染模式示意图;b.断裂带导水入渗淋滤污染模式示意图

    Figure 8.  Conceptual diagram of groundwater pollution pattern in the mining area

    图 9  矿区地表水污染模式概念图

    Figure 9.  Conceptual diagram of surface water pollution pattern in the mining area

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出版历程
  • 收稿日期:  2023-06-12
  • 录用日期:  2023-07-30
  • 修回日期:  2023-07-29

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