Geothermal chemical characteristics and genetic model of the Qingshankou Formation in the Daqingzijing area, southern Songliao Basin
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摘要:
位于长岭凹陷鞍部的大情字井地区水热型地热资源丰富, 其中储层温度较高、岩性好、含水量高的青山口组是最佳热储层, 因此, 阐明地热水的成因模式对于该区地热资源的可持续开发利用具有重要意义。通过青山口组7口井地热水样的水化学测试, 结合收集的8组氢氧同位素数据, 研究了目标区地热水的来源及混合过程, 并分析了成因模式。结果表明, 青山口组地热水主要为部分平衡的Cl-Na型流体, 补给来源为长白山地区的大气降水和原生沉积水, 补给高程为2 347~2 370 m; 通过2 210~3 470 m的循环吸热过程形成现今温度为81.25~112.80 ℃的地热流体存储于半开放体系的青山口组碎屑岩储层中。另外, 研究区NE、NW向2组断裂系统是地热流体循环的主要导水通道, 地热流体在深循环过程中与围岩矿物发生水岩反应, 碳酸盐岩及硅酸盐矿物的溶解, 形成了以Na+、Cl-和HCO3-离子为主的地热水资源。
Abstract:Objective With high reservoir temperature, good lithology and high water content, the Qingshankou Formation is the best geothermal reservoir of Daqingzijing area, the saddle of the Changling Depression. Therefore, elucidating the genetic model of geothermal water is of great significance for the sustainable development and utilization of geothermal resources in this area.
Methods In this study, the source and mixing process of geothermal water in a target area were studied by hydrochemical testing of geothermal water samples collected from 7 wells in the Qingshankou Formation, combined with 8 groups of hydrogen and oxygen isotope data, and a genetic model was established.
Results The results show that the geothermal water of the Qingshankou Formation is mainly Cl-Na-type fluid, which is partially balanced. And the geothermal water is originated from the precipitation and primary sedimentary water in the Changbai Mountain area, with recharge elevation of 2 347-2 370 m. A geothermal fluid with a reservoir temperature of 81.25-112.80 ℃ was formed after the cyclic heat absorption process and was stored in the clastic rock reservoir of the Qingshankou Formation in a semi-open system.
Conclusion In addition, the northeast-oriented and northwest-oriented fault systems in the study area are the main water conducting channels for geothermal fluid circulation. During the deep circulation, geothermal fluid reactions with surrounding rock minerals, resulting in the dissolution of carbonate and silicate minerals, forming geothermal water resources dominated by Na+, Cl- and HCO3- ions.
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图 1 松辽盆地位置图(a)和大情字井地区构造图(b) (据文献[36]修改)
Figure 1. Location of the Songliao Basin (a) and tectonic map of the Daqingzijing area (b)
图 2 松辽盆地构造演化图(据文献[37]修改)
Q.第四系; E+N.古近系+新近系; K2.上白垩统; K1.下白垩统; J3.侏罗系; T.三叠系
Figure 2. Tectonic evolution map of the Songliao Basin
图 3 大情字井地区断裂构造纲要图(据文献[41]修改)
a.T1反射层(相当于嫩江组底界);b.T2反射层(相当于青山口组底界)
Figure 3. Outline of the fault structure in the Daqingzijing area
图 11 长岭凹陷地热水资源成因模式图(据文献[60]修改)
Figure 11. Genetic model of geothermal water resources in the Changling Sag
表 1 研究区水样测试数据
Table 1. Analysis results of geothermal water sampling in the study area
水样编号 深度/ m TDS K+ Na+ Ca+ Mg2+ Cl- SO42- HCO3- I- Br- B3+ SiO2 ρB/(mg·L-1) S1 1 484.1 14 178.9 42.4 5 303.5 41.7 19.0 7 801.1 43.7 927.5 3.2 9 3.7 30.0 S2 1 847.6 14 129.2 46.8 5 344.8 20.0 12.2 6 579.2 132.1 1 994.1 4.7 9 6.4 57.6 S3 2 030.5 9 763.4 98.9 3 348.0 31.3 43.0 3 658.4 144.1 1 439.7 2.9 1 2 53.5 S4 2 302.4 16 395.1 58.8 6 027.6 91.8 17.0 8 644.1 312.2 1 243.6 3.8 9 5.8 58.9 S5 2 240.4 19 697.8 59.6 7 081.6 110.2 13.4 8 804.7 118.1 1 510.2 4.2 7 10.7 59.5 S6 2 409.5 9 426.5 49.2 3 363.9 36.3 6.9 4 200.8 754.6 1 014.8 6.5 3 12.2 63.0 S7 2 489.8 13 846.0 82.1 4 970.0 52.7 16.3 6 490.5 905.4 1 329.0 3.2 7 13.4 63.2 水样编号 深度/m T/℃ pH值 变质系数(γNa+/γCl-) 盐化系数Cl-/(HCO3-+CO32-) 氯镁系数(γCl-/γMg2+) 脱硫系数(100×γSO42-/γCl-) S1 1 484.1 64.0 7.5 1.04 8.41 140.77 0.41 S2 1 847.6 81.4 9.0 1.25 3.29 184.89 1.46 S3 2 030.5 87.4 9.0 1.43 2.54 29.17 22.81 S4 2 302.4 93.0 7.0 1.07 6.95 174.33 2.63 S5 2 240.4 94.0 7.0 1.23 5.83 225.28 17.54 S6 2 409.5 97.8 7.0 1.24 4.14 208.74 13.09 S7 2 489.8 100.0 7.0 1.28 4.88 236.52 10.17 注:储层岩性为粉砂岩 表 2 水样的同位素测试结果
Table 2. Isotopic results of water samples
表 3 研究区地热水补给高程
Table 3. Geothermal water supply elevation in the study area
水样编号 采样高程/m 样品δD/‰ 大气降水δD/‰ K/(‰ (100 m)-1) 补给高程/m D7 1 667 -98.10 -63.30 -4.95 2 370 D8 1 657 -97.40 -63.30 -4.95 2 347 表 4 地热水热储温度
Table 4. Thermal storage temperature of geothermal water
水样编号 ρ(SiO2)/ (mg·L-1) 热储温度/℃ 石英(无蒸汽损失)地温计 石英(有蒸汽损失)地温计 SiO2计算/℃ K-Mg温标/℃ S1 30.00 79.40 83.10 81.25 94.80 S2 57.57 108.60 108.40 108.50 103.56 S3 53.50 105.00 105.40 105.20 106.90 S4 58.93 109.70 109.40 109.55 105.31 S5 59.53 110.20 109.80 110.00 109.09 S6 63.00 112.90 112.20 112.55 113.18 S7 63.23 113.20 112.40 112.80 115.61 表 5 地热水循环深度调查
Table 5. Investigated geothermal water circulation depth
水样编号 地热增温级/ (m·℃-1) SiO2热储温度/℃ 年平均气温/℃ 恒温带深度[38]/m 循环深度/m S1 29.41 81.25 4.5 25 2 282 S2 21.14 108.50 4.5 25 2 222 S3 25.71 105.20 4.5 25 2 612 S4 23.81 111.50 4.5 25 2 572 S5 24.10 110.00 4.5 25 2 572 S6 31.95 112.55 4.5 25 3 482 S7 27.47 112.80 4.5 25 3 002 -
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