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湟水河流域矿泉水水化学分布特征及界限指标来源分析

胡峰 刁玉山 何钟强 黄鑫 邓斌 罗安平 孟越 张子茵

胡峰,刁玉山,何钟强,等. 湟水河流域矿泉水水化学分布特征及界限指标来源分析[J]. 地质科技通报,2025,44(0):1-15 doi: 10.19509/j.cnki.dzkq.tb20240055
引用本文: 胡峰,刁玉山,何钟强,等. 湟水河流域矿泉水水化学分布特征及界限指标来源分析[J]. 地质科技通报,2025,44(0):1-15 doi: 10.19509/j.cnki.dzkq.tb20240055
HU Feng,DIAO Yushan,HE Zhongqiang,et al. Characteristics of hydrochemical distribution of mineral water in Huangshui River Catchment and source analysis of threshold value elements[J]. Bulletin of Geological Science and Technology,2025,44(0):1-15 doi: 10.19509/j.cnki.dzkq.tb20240055
Citation: HU Feng,DIAO Yushan,HE Zhongqiang,et al. Characteristics of hydrochemical distribution of mineral water in Huangshui River Catchment and source analysis of threshold value elements[J]. Bulletin of Geological Science and Technology,2025,44(0):1-15 doi: 10.19509/j.cnki.dzkq.tb20240055

湟水河流域矿泉水水化学分布特征及界限指标来源分析

doi: 10.19509/j.cnki.dzkq.tb20240055
基金项目: 青海省地质矿产开发局局计划科研和生产项目(DCY2023SW01(SK))
详细信息
    作者简介:

    胡峰:E-mail:1467364298@qq.com

    通讯作者:

    E-mail:1142712931@qq.com

Characteristics of hydrochemical distribution of mineral water in Huangshui River Catchment and source analysis of threshold value elements

More Information
  • 摘要:

    天然矿泉水不仅是宝贵的矿产资源,还能够为地表水环境系统(例如湿地与河岸带)提供补给水源,在保持生态系统多样化方面扮演重要角色。发源于青海省海晏、湟源的湟水河流域内发现了大量富锶矿泉水,少量泉水同时富含锂和偏硅酸。然而,目前对矿泉水中这些界限指标的来源及其相关水化学演化过程尚缺乏研究,同时个别采样点存在限量指标超标的情况,直接影响了矿泉水的开发利用,是目前亟待解决的问题。以青海湟水河流域为研究区,通过采集流域内天然泉水样品,采用水文地球化学分析及物质迁移模拟方法揭示矿泉水水化学特征与成因机制,这对理解湟水河流域地下水水化学演化过程具有重要意义。研究区地下水样品中大部分达到了国家饮用天然矿泉水的标准,且锶含量全部大于0.2 mg/L,少数样品富含锂和偏硅酸。水化学分析结果表明,地下水从补给区到排泄区,其水化学类型逐渐从HCO3-Ca·Mg型过渡到SO4-Na型,这是地下水在运移过程中不断溶解石膏层的结果。从Sr与HCO3、SO42-和Cl的相关性分析中可以看出,碳酸盐岩对地下水Sr含量的贡献程度有限;相反,由于Ca与Sr化学性质相似,在矿物中易发生原子交换,从而石膏层或蒸发岩类矿物中可能富集含Sr矿物,此类岩层在水岩作用下会释放一定量的Sr。地下水中锂的来源主要与古咸水湖沉积环境有关,过量的偏硅酸则来源于地热水在深循环过程中溶滤的铝硅酸盐矿物。通过物质迁移模拟分析发现,在北部流径上,地下水主要溶解石膏、石盐和伊利石,而天青石和锂辉石的溶解贡献了锶和锂;在南部流径上,石膏和石盐的溶解导致高TDS值,且去白云石化过程显著。研究成果能够为矿泉水资源的合理开发利用和保护提供科学依据。

     

  • 图 1  青海省湟水河流域水文地质图及采样点

    Figure 1.  Hydrogeological map and sampling points of Huangshui River Catchment in Qinghai Province

    图 2  青海省湟水河流域地下水样品Piper三线图

    Figure 2.  Piper's trilinear diagram of groundwater samples in Huangshui River catchment, Qinghai Province

    图 3  地下水样品Ca(a)、Mg(b)与HCO3质量浓度相关关系图;石膏与方解石的饱和指数(SI)关系图(c);Cl与Na相关关系图(d)

    Figure 3.  Plot of groundwater samples correlating Ca (a), Mg (b) with HCO3 concentration; saturation index (SI) of gypsum with calcite (c); Cl with Na (d)

    图 4  研究区地下水Sr与TDS(a)、HCO3(b)、SO42−(c)以及Cl(d)质量浓度相关关系图

    Figure 4.  Correlation of groundwater Sr with TDS (a), HCO3 (b), SO42− (c) and Cl (d) concentrations in the study area

    表  1  青海省湟水河流域地下水现场物理指标

    Table  1.   On-site physical indicators of groundwater in Huangshui River Catchment, Qinghai Province

    泉点
    编号
    地理位置 水温/℃ 感官要求
    色度/(°) 浑浊度/(°) 滋味 气味 状态
    ≤10 NTU≤1 透明
    HSQ01 湟中区李家山镇饮用天然矿泉水 6 <5 <0.5
    HSQ02 湟中区 4 <5 <0.5
    HSQ03 湟中区 6 <5 <0.5
    HSQ04 湟中区 7 <5 <0.5
    HSQ06 湟中区田家寨镇阴坡村黑沟峡 11 <5 <0.5
    HSQ07 湟中西堡葛一村 9 <5 <0.5
    HSQ08 湟中西堡葛一村 9 <5 <0.5
    HSQ09 湟中区 38 <5 <0.5
    HSQ10 湟中区田家寨子沟峡 18.5 <5 <0.5
    HSQ11 湟中区田家寨子沟峡 15.5 <5 <0.5
    HSQ12 互助县红崖子沟米子弯 9.5 <5 <0.5
    HSQ13 互助县佑宁寺矿泉水 6 <5 <0.5
    HSQ14 互助县南门峡镇西山根村 6 <5 <0.5
    HSQ15 互助县东山乡大庄村 6 <5 <0.5
    HSQ16 互助县东山乡大泉村 6 <5 <0.5
    HSQ17 互助县东山乡哈家沟村 6 <5 <0.5
    HSQ18 平安县冰岭山村 20~25 <5 <0.5
    HSQ19 平安区佛岭饮用天然矿泉水 7 <5 <0.5
    HSQ20 平安区上尧村 7 <5 <0.5
    HSQ21 平安县洪水泉乡下马圈村 9.5 <5 <0.5
    HSQ24 大通县景阳乡天然饮用矿泉水 7 <5 <0.5
    HSQ25 大通县向化乡下滩村 6 <5 <0.5
    HSQ26 大通县向化乡上滩村 5.5 <5 <0.5
    HSQ27 大通县药水庄天然饮用矿泉水 5 <5 <0.5
    HSQ30 西宁市共字桥 9 <5 <0.5
    HSQ31 城中区泉尔湾村 10 <5 <0.5 无臭微咸
    HSQ32 海晏县文迦牧场 3 <5 <0.5
    HSQ33 海晏县甘子河达玉村 51 <5 <0.5
    HSQ34 湟中区门旦峡 6 <5 <0.5
    HSQ35 湟源县加牙麻村 6 <5 <0.5
    注:NTU. nephelometric turbidity unit,是一种国际公认的浊度测量单位。
    下载: 导出CSV

    表  2  青海省湟水河流域地下水界限指标

    Table  2.   Groundwater threshold value elements of Huangshui River Basin, Qinghai Province

    泉点
    编号
    界限指标ρB/(mg·L)−1
    锂 Li锶 Sr锌 Zn硒 Se偏硅酸游离CO2溶解性总固体
    ≥0.2≥0.2≥0.2≥0.01≥25≥2501000
    HSQ010.0090.846<0.0008<0.0002512.74.07790
    HSQ020.0050.3040.001<0.000259.171.02518
    HSQ030.0110.4910.002<0.00025161.02520
    HSQ040.0110.5100.004<0.0002515.32.03670
    HSQ060.0050.3110.017<0.000257.4145846
    HSQ070.010.442<0.0008<0.000259.074.47455
    HSQ080.0110.387<0.0008<0.000259.212.23458
    HSQ090.0280.4480.004<0.0002531.31131904
    HSQ100.0110.341<0.0008<0.0002515.81321435
    HSQ110.0130.380<0.0008<0.0002517.62321496
    HSQ120.0382.4320.016<0.0002513.24.471624
    HSQ130.0040.4170.028<0.000256.063.35516
    HSQ140.010.4280.004<0.00025135.08533
    HSQ150.010.4900.003<0.000259.891.02541
    HSQ160.0160.6100.008<0.0002513.22.03705
    HSQ170.0140.7110.002<0.0002511.24.07696
    HSQ180.4472.8270.025<0.0002514.879.26713
    HSQ190.0160.702<0.0008<0.0002512.86.03693
    HSQ200.1182.1350.02<0.0002522.11414302
    HSQ210.3499.818<0.0008<0.0002516.43.355734
    HSQ240.0070.4790.002<0.0002511.35.08662
    HSQ250.0070.3130.002<0.000259.357.81442
    HSQ260.0030.3070.0008<0.000258.931.12322
    HSQ270.0040.2200.007<0.000256.321.01240
    HSQ300.0543.370<0.0008<0.0002513.63.35828
    HSQ310.0573.6030.001<0.0002512.13.053542
    HSQ320.0050.4280.007<0.0002512.91.01607
    HSQ330.0510.4370.003<0.0002545.620.1890
    HSQ340.0060.3720.004<0.0002512.53.05764
    HSQ350.0030.312<0.0008<0.000258.582.01346
    下载: 导出CSV

    表  3  青海省湟水河流域地下水限量指标

    Table  3.   Groundwater limit indicators for Huangshui River catchment, Qinghai Province

    泉点
    编号
    限量指标ρB/(mg·L)−1
    硒 Se 锑 Sb 铜 Cu 钡Ba 铬Cr 锰 Mn 镍 Ni 银 Ag 溴酸盐 硼酸盐 氟化物 耗氧量 挥发酚 矿物油 阴离子
    合成
    洗涤剂
    总β放
    射性
    <0.05 <0.005 <1.0 <0.7 <0.05 <0.4 <0.02 <0.05 <0.01 <5 <1.5 <2.0 <0.002 <0.01 <0.05 <0.3 <1.50Bq/L
    HSQ01 <0.00025 <0.00008 <0.00009 0.287 0.007 <0.00006 <0.00007 <0.00003 / <0.20 0.223 0.87 <0.002 <0.002 <0.01 <0.05 0.22
    HSQ02 <0.00025 <0.00008 <0.00009 0.075 0.006 <0.00006 <0.00007 <0.00003 / <0.20 0.153 1.11 <0.002 <0.002 <0.01 <0.05 0.06
    HSQ03 <0.00025 <0.00008 <0.00009 0.199 0.008 <0.00006 <0.00007 <0.00003 / <0.20 0.359 0.87 <0.002 <0.002 <0.01 <0.05 0.08
    HSQ04 <0.00025 <0.00008 <0.00009 0.137 0.006 <0.00006 <0.00007 <0.00003 / <0.20 0.243 0.95 <0.002 <0.002 <0.01 <0.05 0.17
    HSQ06 <0.00025 <0.00008 0.001 0.099 0.006 0.023 0.003 <0.00003 <0.005 <0.20 0.17 0.95 <0.002 <0.002 <0.01 <0.05 0.15
    HSQ07 <0.00025 <0.00008 <0.00009 0.169 0.002 0.001 <0.00007 <0.00003 <0.005 <0.20 0.055 0.79 <0.002 <0.002 <0.01 <0.05 0.07
    HSQ08 <0.00025 <0.00008 <0.00009 0.174 0.002 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.1 0.79 <0.002 <0.002 <0.01 <0.05 0.07
    HSQ09 <0.00025 <0.00008 <0.00009 0.399 0.005 <0.00006 <0.00007 <0.00003 / 0.53 0.327 0.95 <0.002 <0.002 <0.01 <0.05 2.55
    HSQ10 <0.00025 <0.00008 <0.00009 0.229 0.005 0.005 0.001 <0.00003 <0.005 <0.20 0.281 0.71 <0.002 <0.002 <0.01 <0.05 0.29
    HSQ11 <0.00025 <0.00008 <0.00009 0.266 0.007 0.032 0.001 <0.00003 <0.005 <0.20 0.328 1.19 <0.002 <0.002 <0.01 <0.05 0.35
    HSQ12 <0.00025 <0.00008 <0.00009 0.025 0.006 0.004 <0.00007 <0.00003 <0.005 0.46 0.466 1.19 <0.002 <0.002 <0.01 <0.05 0.09
    HSQ13 <0.00025 <0.00008 <0.00009 0.071 <0.00009 0.002 <0.00007 <0.00003 <0.005 <0.20 0.142 0.95 <0.002 <0.002 <0.01 <0.05 0.07
    HSQ14 <0.00025 <0.00008 <0.00009 0.193 <0.00009 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.229 1.03 <0.002 <0.002 <0.01 <0.05 0.05
    HSQ15 <0.00025 <0.00008 <0.00009 0.034 0.002 0.003 <0.00007 <0.00003 <0.005 <0.20 0.519 1.03 <0.002 <0.002 <0.01 <0.05 <0.01
    HSQ16 <0.00025 <0.00008 <0.00009 0.036 0.002 0.002 <0.00007 <0.00003 <0.005 <0.20 0.395 1.11 <0.002 <0.002 <0.01 <0.05 <0.01
    HSQ17 <0.00025 <0.00008 <0.00009 0.086 <0.00009 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.661 1.03 <0.002 <0.002 <0.01 <0.05 0.05
    HSQ18 <0.00025 <0.00008 <0.00009 0.099 0.005 0.431 0.077 <0.00003 <0.005 2.82 1.11 0.95 <0.002 <0.002 <0.01 <0.05 6.8
    HSQ19 <0.00025 <0.00008 <0.00009 0.204 0.007 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.428 1.11 <0.002 <0.002 <0.01 <0.05 0.03
    HSQ20 <0.00025 <0.00008 <0.00009 0.044 0.005 0.305 0.012 <0.00003 <0.005 1.96 1.97 1.43 <0.002 <0.002 <0.01 <0.05 <0.01
    HSQ21 <0.00025 <0.00008 0.001 0.229 0.009 0.031 0.002 <0.00003 <0.005 2.51 1.86 2.3 <0.002 <0.002 <0.01 <0.05 <0.01
    HSQ24 <0.00025 <0.00008 <0.00009 0.154 0.006 <0.00006 <0.00007 <0.00003 / <0.20 0.13 0.95 <0.002 <0.002 <0.01 <0.05 0.06
    HSQ25 <0.00025 <0.00008 <0.00009 0.156 <0.00009 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.114 0.63 <0.002 <0.002 <0.01 <0.05 <0.01
    HSQ26 <0.00025 <0.00008 <0.00009 0.193 <0.00009 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.075 0.95 <0.002 <0.002 <0.01 <0.05 <0.01
    HSQ27 <0.00025 <0.00008 <0.00009 0.197 <0.00009 0.001 <0.00007 <0.00003 <0.005 <0.20 0.092 0.87 <0.002 <0.002 <0.01 <0.05 0.16
    HSQ30 <0.00025 <0.00008 <0.00009 0.63 0.014 0.05 <0.00007 <0.00003 <0.005 0.29 0.789 1.03 <0.002 <0.002 <0.01 <0.05 0.04
    HSQ31 <0.00025 <0.00008 <0.00009 0.009 0.018 <0.00006 <0.00007 <0.00003 / 1.41 0.826 0.95 <0.002 <0.002 <0.01 <0.05 0.28
    HSQ32 <0.00025 <0.00008 <0.00009 0.048 <0.00009 0.002 <0.00007 <0.00003 <0.005 <0.20 0.175 3.01 <0.002 <0.002 <0.01 <0.05 0.17
    HSQ33 <0.00025 <0.00008 <0.00009 0.131 <0.00009 0.058 <0.00007 <0.00003 <0.005 0.44 2.94 1.35 <0.002 <0.002 <0.01 <0.05 0.24
    HSQ34 <0.00025 <0.00008 <0.00009 0.156 0.007 <0.00006 <0.00007 <0.00003 / <0.20 0.146 0.95 <0.002 <0.002 <0.01 <0.05 0.17
    HSQ35 <0.00025 <0.00008 <0.00009 0.152 <0.00009 <0.00006 <0.00007 <0.00003 <0.005 <0.20 0.145 1.19 <0.002 <0.002 <0.01 <0.05 <0.01
    下载: 导出CSV

    表  4  青海省湟水河流域地下水主要常量组分及水化学类型

    Table  4.   Main constant components and hydrochemical types of groundwater in huangshui River Catchment, Qinghai Province

    泉点
    编号
    主要常量组分ρB/(mg·L)−1
    Sr 重碳
    酸根
    硫酸根 氯化物 硝酸根 pH 碳酸根 亚硝酸根 磷酸根 氟化物 总硬度 水化学类型
    HSQ01 0.846 137 32.9 17.7 1.45 427 61.9 42 65.6 7.63 <0.05 0 <0.016 <0.051 0.223 477.89 HCO3-Ca·Mg
    HSQ02 0.304 61.6 49.7 0.53 1.53 279 84.2 19.4 5.9 8.03 <0.05 0 <0.016 <0.051 0.153 358.63 HCO3·SO4-Mg·Ca
    HSQ03 0.491 84.9 25.7 4.76 0.46 365 17.1 4.91 12.6 8.12 <0.05 0 <0.016 <0.051 0.359 317.89 HCO3-Ca·Mg
    HSQ04 0.510 128 20.8 15.7 0.85 377 63.3 35.4 41.5 7.65 <0.05 0 <0.016 <0.051 0.243 405.52 HCO3-Ca
    HSQ06 0.311 135 53 3.84 2.47 559 82.4 2.53 2.71 6.86 <0.05 0 <0.016 <0.051 0.17 556.31 HCO3-Mg·Ca
    HSQ07 0.442 59.6 34.9 4.68 2.05 278 44.4 11.4 14.4 7.81 <0.05 0 <0.016 <0.051 0.055 292.47 HCO3-Mg·Ca
    HSQ08 0.387 58.8 37.1 6.41 2.19 284 39.6 10.8 13.2 7.85 <0.05 0 <0.016 <0.051 0.1 299.57 HCO3-Mg·Ca
    HSQ09 0.448 330 91.6 9.49 2.35 1412 34.8 7.07 0.748 6.77 <0.05 0 <0.016 <0.051 0.327 1202.35 HCO3-Ca·Mg
    HSQ10 0.341 270 59.9 5.16 2.21 1051 39.1 2.44 1.86 6.41 <0.05 0 <0.016 <0.051 0.281 921.09 HCO3-Mg·Ca
    HSQ11 0.380 269 61.1 6.34 2.47 1090 39 2.46 0.772 6.41 <0.05 0 <0.016 <0.051 0.328 924.20 HCO3-Mg·Ca
    HSQ12 2.432 162 81.9 187 18.7 412 524 174 47.9 7.4 <0.05 0 <0.016 <0.051 0.466 740.78 SO4-Na
    HSQ13 0.417 93.8 23.5 2.84 3.08 228 139 7.45 0.557 7.6 <0.05 0 <0.016 <0.051 0.142 331.15 HCO3-Mg·Ca
    HSQ14 0.428 92.6 22 8.61 1.95 338 32.3 12.3 17 7.62 <0.05 0 <0.016 <0.051 0.229 321.99 HCO3-Mg·Ca
    HSQ15 0.490 57.1 25.5 51.6 3.06 326 41.9 21.3 14.4 7.96 <0.05 0 <0.016 <0.051 0.519 247.58 HCO3-Mg·Na·Ca
    HSQ16 0.610 65.7 36.9 77.7 3.87 411 56.5 60.5 18.4 7.78 <0.05 0 <0.016 <0.051 0.395 315.89 HCO3-Mg·Na·Ca
    HSQ17 0.711 84.1 34.9 42.4 3.38 415 39.2 33.6 49.1 7.64 <0.05 0 <0.016 <0.051 0.661 353.57 HCO3-Mg·Ca
    HSQ18 2.827 508 364 677 18.1 3148 1394 292 <0.016 7.02 <0.05 0 <0.016 <0.051 1.11 2766.38 HCO3·SO4-Na·Mg·Ca
    HSQ19 0.702 87.7 33.4 41.7 12 378 85.7 28.9 12.9 7.78 <0.05 0 <0.016 <0.051 0.428 356.63 HCO3-Ca·Mg
    HSQ20 2.135 720 150 155 43.8 2185 898 102 <0.016 7.17 <0.05 0 <0.016 <0.051 1.97 2414.86 HCO3·SO4-Ca·Mg
    HSQ21 9.818 490 156 870 276 239 3212 450 56.1 7.65 <0.05 0 <0.016 <0.051 1.86 1864.66 SO4-Na
    HSQ24 0.479 123 20 23.7 3.55 344 74.3 33.1 43.7 7.57 <0.05 0 <0.016 <0.051 0.13 389.21 HCO3-Ca
    HSQ25 0.313 61.6 26.5 7.91 2.24 289 25.9 5.43 6.86 7.17 <0.05 0 <0.016 <0.051 0.114 262.89 HCO3-Mg·Ca
    HSQ26 0.307 47.7 20.8 3.94 1.82 217 20.2 3.58 4.43 7.7 <0.05 0 <0.016 <0.051 0.075 204.79 HCO3-Ca·Mg
    HSQ27 0.220 31 16.8 1.25 1.7 164 11.5 2.6 4.72 7 <0.05 0 <0.016 <0.051 0.092 146.68 HCO3-Mg·Ca
    HSQ30 3.370 79.6 58.9 63.9 6.33 328 161 62.1 49.7 7.68 <0.05 0 <0.016 <0.051 0.789 441.20 HCO3-Mg·Ca
    HSQ31 3.603 214 302 497 10.5 427 1081 837 92.7 7.81 <0.05 0 <0.016 <0.051 0.826 1781.08 Cl-Na·Mg
    HSQ32 0.428 107 19.1 15 3.89 358 33.6 15.7 28.2 8.13 <0.05 0 <0.016 <0.051 0.175 345.42 HCO3-Ca
    HSQ33 0.437 120 55.2 14.4 9.4 533 95 6.23 <0.016 7.18 <0.05 0 <0.016 <0.051 2.94 525.73 HCO3-Ca·Mg
    HSQ34 0.372 99.1 61.1 2.84 0.65 475 106 5.32 11.9 7.52 <0.05 0 <0.016 <0.051 0.146 499.26 HCO3·SO4-Ca·Mg
    HSQ35 0.312 62.8 10.4 3.18 4.04 216 23.8 5.21 11.4 7.84 <0.05 0 <0.016 <0.051 0.145 199.68 HCO3-Ca
    下载: 导出CSV

    表  5  研究区HSQ27→HSQ15→HSQ12流径上水化学演化模拟结果

    Table  5.   Simulation results of hydrochemical evolution on the flow path HSQ27→HSQ15→HSQ12 in the study area

    矿物名称 化学式 摩尔转移量/(mol·L−1
    HSQ27→HSQ15 HSQ15→HSQ12
    钠长石 NaAlSi3O8 1.81×10−3 −1.92×10−3
    方解石 CaCO3 4.07×101 4.29×101
    天青石 SrSO4 0 1.01×10−5
    玉髓 SiO2 0 0
    白云石 CaMg(CO3)2 −4.07×101 −4.29×101
    萤石 CaF2 6.46×10−6 −3.09×10−5
    石膏 CaSO4·2H2O 7.10×10−5 3.80×10−3
    石盐 NaCl 3.77×10−4 3.01×10−3
    伊利石 K0.6Mg0.25Al1.8Al0.5Si3.5 1.63×102 1.72×102
    高岭石 Al2Si2O5(OH)4 −1.38×102 −1.46×102
    白云母 KAl3Si3O10(OH)2 1.84×10−3 −1.54×10−3
    菱锶矿 SrCO3 −2.07×10−6 0
    CO2 CO2 4.07×101 4.29×101
    钾长石 KAlSi3O8 −9.77×101 −1.03×102
    锂辉石 LiAlSi2O6 1.44×10−6 1.21×10−6
    下载: 导出CSV

    表  6  研究区HSQ02→HSQ10→HSQ20→HSQ18流径上水化学演化模拟结果

    Table  6.   Simulation results of hydrochemical evolution on the flow paths HSQ02→HSQ10→HSQ20→HSQ18 in the study area

    矿物名称 化学式 摩尔转移量/(mol·L−1
    HSQ02→HSQ10 HSQ10→HSQ20 HSQ20→HSQ18
    钠长石 NaAlSi3O8 3.21×10−4 3.88×10−3 1.75×10−2
    方解石 CaCO3 2.62×10−3 1.50×10−3 0
    天青石 SrSO4 2.81×10−6 2.45×10−5 7.94×10−6
    玉髓 SiO2 −7.60×101 −1.10×102 0
    白云石 CaMg(CO3)2 1.49×10−3 6.18×10−3 −9.58×10−3
    萤石 CaF2 6.13×10−6 5.20×10−5 −2.27×10−5
    石膏 CaSO4·2H2O 1.28×10−4 9.36×10−3 5.20×10−3
    石盐 NaCl −1.04×10−4 2.89×10−3 5.40×10−3
    伊利石 K0.6Mg0.25Al1.8Al0.5Si3.5 0 0 7.24×10−2
    高岭石 Al2Si2O5(OH)4 3.80×101 5.49×101 −8.69×10−2
    白云母 KAl3Si3O10(OH)2 −3.80×101 −5.49×101 1.69×10−2
    菱锶矿 SrCO3 0 0 0
    CO2 CO2 1.02×10−2 2.19×10−2 3.51×10−2
    钾长石 KAlSi3O8 3.80×101 5.49×101 −6.10×10−2
    锂辉石 LiAlSi2O6 9.88×10−7 1.73×10−5 4.79×10−5
    下载: 导出CSV
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