Volume 43 Issue 1
Jan.  2024
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Article Contents
LUO Hua, GUO Pan, LIU Li, PAN Longke, DUAN Xianfeng, MAO Qixi, LIAO Mingfang. Fluid inclusion and C-H-O-S-Pb isotope characteristics and geological significance of lead-zinc-fluorite deposits in the Geleche area, Laifeng, Hubei Province[J]. Bulletin of Geological Science and Technology, 2024, 43(1): 39-50. doi: 10.19509/j.cnki.dzkq.tb20220242
Citation: LUO Hua, GUO Pan, LIU Li, PAN Longke, DUAN Xianfeng, MAO Qixi, LIAO Mingfang. Fluid inclusion and C-H-O-S-Pb isotope characteristics and geological significance of lead-zinc-fluorite deposits in the Geleche area, Laifeng, Hubei Province[J]. Bulletin of Geological Science and Technology, 2024, 43(1): 39-50. doi: 10.19509/j.cnki.dzkq.tb20220242

Fluid inclusion and C-H-O-S-Pb isotope characteristics and geological significance of lead-zinc-fluorite deposits in the Geleche area, Laifeng, Hubei Province

doi: 10.19509/j.cnki.dzkq.tb20220242
More Information
  • Corresponding author: LUO Hua, E-mail: 270132397@qq.com
  • Received Date: 26 May 2022
  • Accepted Date: 30 Aug 2022
  • Rev Recd Date: 29 Aug 2022
  • Objective

    Lead-zinc mineralization is widely distributed in southwestern Hubei Province, but no large deposits have been found thus far, and there is a lack of systematic studies on metallogenic systems.

    Methods

    The C-H-O-S-Pb isotope analysis and the homogenization temperature of fluid inclusions of lead-zinc-fluorite ore in the Geleche area of Laifeng were conducted.

    Results

    The results show that the homogenization temperature of fluid inclusions in fluorite and calcite is concentrated between 137-170℃, and the variation range of salinity is 11.46%-16.89%. It is a NaCl-H2O system with low temperature and medium and low salinity. The main source may be metamorphic dehydration of rock formations containing sedimentary sulfate (marine sediments). The δ34S content ranges from 9.5‰ to 11.8‰, with an average of 10.92‰. 206Pb/204Pb < 18.20, 207Pb/204Pb>15.60, and 208Pb/204Pb < 39.00, and the floating ratio is small and high μ and high ω.

    Conclusion

    The sulfur and lead sources are mainly from the Ordovician and Cambrian ore-bearing strata in the Paleozoic sedimentary basin of the upper crust. Syngenetic sedimentary diagenesis and epigenetic medium- and low-temperature hydrothermal transformation are the dominant genetic types of the Geleche mining area. Compared with the typical lead-zinc deposits in the Yangtze Platform of West Hubei and Hunan, they have great similarity and obvious differences in metallogenic fluid, Paleozoic sedimentary environment and tectonic background.

     

  • The authors declare that no competing interests exist.
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  • [1]
    段其发, 曹亮, 曾健康, 等. 湘西花垣矿集区狮子山铅锌矿床闪锌矿Rb-Sr定年及地质意义[J]. 地球科学, 2014, 39(8): 977-986.

    DUAN Q F, CAO L, ZENG J K, et al. Rb-Sr dating of sphalerites from Shizishan Pb-Zn deposit in Huayuan ore concentration area, western Hunan, and its geological significance[J]. Earth Science, 2014, 39(8): 977-986. (in Chinese with English abstract)
    [2]
    胡太平, 王敏芳, 丁振举, 等. 湘西花垣李梅铅锌矿床C、O、S、Pb同位素特征及成矿物质来源[J]. 矿床地质, 2017, 36(3): 623-642.

    HU T P, WANG M F, DING Z J, et al. C, O, S and Pb isotopic characteristics and sources of metallogenic materials of Limei Pb-Zn deposit in Huayuan County, western Hunan Province[J]. Mineral Deposits, 2017, 36(3): 623-642. (in Chinese with English abstract)
    [3]
    刘旭, 刘悟辉, 息朝庄, 等. 湖南黄沙坪铅锌多金属矿区岩浆岩地球化学特征[J]. 地质找矿论丛, 2009, 24(3): 198-205.

    LIU X, LIU W H, XI C Z, et al. Geochemical characteristics of magmatic rocks of Huangshaping lead-zinc deposit in Hunan China[J]. Contributions to Geology and Mineral Resources Research, 2009, 24(3): 198-205. (in Chinese with English abstract)
    [4]
    陈帅奇, 蒋启生, 陈渡平, 等. 湘西起车铅锌矿同位素地球化学特征[J]. 有色金属(矿山部分), 2015, 67(5): 41-47.

    CHEN S Q, JIANG Q S, CHEN D P, et al. The isotopic geochemistry characteristics of Qiche Pb-Zn deposit in western Hunan Province[J]. Nonferrous Metals(Mining Section), 2015, 67(5): 41-47. (in Chinese with English abstract)
    [5]
    朱建东, 刘源骏, 祝敬明, 等. 扬子地台东北缘鄂西铅锌矿成因类型与地学思维[J]. 资源环境与工程, 2016, 30(增刊): 145-153.

    ZHU J D, LIU Y J, ZHU J M, et al. Genesis type and geological thinking of lead-zinc deposit in western Hubei, Northeast of Yangtse Platform[J]. Resources Environment & Engineering, 2016, 30(S): 145-153. (in Chinese with English abstract)
    [6]
    徐耀鉴, 杨柳, 尹萍, 等. 湘西铅锌矿地质特征与成矿作用[J]. 世界有色金属, 2021(20): 72-74.

    XU Y J, YANG L, YIN P, et al. Geochemical characteristics and ore-forming of Pb-Zn deposit, western Hunan[J]. World Nonferrous Metals, 2021(20): 72-74. (in Chinese with English abstract)
    [7]
    周云, 段其发, 曹亮, 等. 湘西-鄂西地区铅锌矿的大范围低温流体成矿作用研究[J]. 高校地质学报, 2014, 20(2): 198-213.

    ZHOU Y, DUAN Q F, CAO L, et al. Large-scale low-temperature mineralizations in western Hunan-western Hubei lead-zinc deposits[J]. Geological Journal of China Universities, 2014, 20(2): 198-213. (in Chinese with English abstract)
    [8]
    杨绍祥, 劳可通. 湘西北铅锌矿床碳氢氧同位素特征及成矿环境分析[J]. 矿床地质, 2007, 26(3): 330-341.

    YANG S X, LAO K T. A tentative discussion on genesis of lead-zinc deposits in Northwest Hunan[J]. Mineral Deposits, 2007, 26(3): 330-341. (in Chinese with English abstract)
    [9]
    梁恩云, 刘伟, 彭能立, 等. 湘西北地区奥陶系铅锌矿化围岩的地球化学特征[J]. 桂林理工大学学报, 2015, 35(4): 694-701.

    LIANG E Y, LIU W, PENG N L, et al. Geochemistry characterics of lead-zinc mineralized wall-rock for Ordovician in the Northwest of Hunan[J]. Journal of Guilin University of Technology, 2015, 35(4): 694-701. (in Chinese with English abstract)
    [10]
    雷义均, 戴平云, 段其发, 等. 鄂西-湘西北地区铅锌矿矿源层对铅锌矿床产出定位的制约[J]. 桂林理工大学学报, 2013, 33(1): 1-6.

    LEI Y J, DAI P Y, DUAN Q F, et al. Constraints of lead-zinc source bed to lead-zinc deposits in western Hubei to northwestern Hunan[J]. Journal of Guilin University of Technology, 2013, 33(1): 1-6. (in Chinese with English abstract)
    [11]
    周云. 湘西花垣MVT型铅锌矿集区成矿作用研究[D]. 成都: 成都理工大学, 2017.

    ZHOU Y. Metallogenesis study of Huayuan MVT type Pb-Zn ore concentration area, Hunan[D]. Chengdu: Chengdu University of Technology, 2017. (in Chinese with English abstract)
    [12]
    王茂林, 王贤茂, 李小林, 等. 鄂西地区铅锌矿成矿特征、找矿模式及找矿方向[J]. 资源环境与工程, 2014, 28(3): 257-266.

    WANG M L, WANG X M, LI X L, et al. Metallogenic characteristics, prospecting model and prospecting direction of lead-zinc deposits in western Hubei[J]. Resources Environment & Engineering, 2014, 28(3): 257-266. (in Chinese with English abstract)
    [13]
    龙宝林, 刘忠明. 鄂西地区铅锌矿基本特征与找矿方向[J]. 地质与勘探, 2005, 41(3): 16-21.

    LONG B L, LIU Z M. Basic characteristics and prognosis of Pb-Zn deposits in the western Hubei Province[J]. Geology and Prospecting, 2005, 41(3): 16-21. (in Chinese with English abstract)
    [14]
    文永华, 杜登文, 赵鹏, 等. 鹤峰-宣恩-咸丰地区铅锌矿床成矿物质来源研究[J]. 世界有色金属, 2017(23): 123-131.

    WEN Y H, DU D W, ZHAO P, et al. Study on source material source of lead-zinc deposit in Hefeng-Xuanen-Xianfeng area, Hubei Province[J]. World Nonferrous Metals, 2017(23): 123-131. (in Chinese with English abstract)
    [15]
    匡文龙, 向世超, 肖文舟, 等. 湘西北地区铅锌矿床成矿地质特征及矿床成因研究[J]. 矿床地质, 2015, 34(5): 1072-1082.

    KUANG W L, XIANG S C, XIAO W Z, et al. Metallogenic geological characteristics and genesis of lead-zinc deposits in northwestern Hunan[J]. Mineral Deposits, 2015, 34(5): 1072-1082. (in Chinese with English abstract)
    [16]
    王云峰, 杨红梅, 刘重芃, 等. 湘西唐家寨铅锌矿床锶、硫同位素及其对成矿物质来源的指示意义[J]. 中国地质, 2018, 45(3): 564-572.

    WANG Y F, YANG H M, LIU C P, et al. Strontium and sulfur isotopic characteristics of the Tangjiazhai Pb-Zn deposit in western Hunan Province, China: Denotative significance for ore-forming materials source[J]. Geology in China, 2017, 45(3): 564-572. (in Chinese with English abstract)
    [17]
    夏新阶, 付胜云. 湘西北铅锌矿床成矿模式[J]. 有色金属(矿山部分), 2010, 62(2): 35-40.

    XIA X J, FU S Y. Mineralization pattern of northwestern Hunan lead-zinc mine[J]. Nonferrous Metals(Mining Section), 2010, 62(2): 35-40. (in Chinese with English abstract)
    [18]
    蔡应雄, 杨红梅, 段瑞春, 等. 湘西-黔东下寒武统铅锌矿床流体包裹体和硫、铅、碳同位素地球化学特征[J]. 现代地质, 2014, 28(1): 29-42.

    CAI Y X, YANG H M, DUAN R C, et al. Fluid inclusions and S, Pb, C isotope geochemistry of Pb-Zn deposits hosted by Lower Cambrian in western Hunan-eastern Guizhou area[J]. Geoscience, 2014, 28(1): 29-42. (in Chinese with English abstract)
    [19]
    曹亮, 段其发, 彭三国, 等. 湘西地区铅锌矿成矿物质来源: 来自S、Pb同位素的证据[J]. 地质通报, 2017, 36(5): 834-846.

    CAO L, DUAN Q F, PENG S G, et al. Sources of metallogenic materials of lead-zinc deposits in western Hu'nan Province: Evidence from S and Pb isotopes[J]. Geological Bulletin of China, 2017, 36(5): 834-845. (in Chinese with English abstract)
    [20]
    路远发. GeoKit: 一个用VBA构建的地球化学工具软件包[J]. 地球化学, 2004, 33(5): 459-464.

    LU Y F. Geokit: A geochemical toolkit for Microsoft Excel[J]. Geochimica, 2004, 33(5): 459-464. (in Chinese with English abstract)
    [21]
    姜军胜, 郑有业, 高顺宝, 等. 西藏查藏错铜铅锌矿床成因: C-H-O-S-Pb同位素制约[J]. 地球科学, 2015, 40(6): 1006-1016.

    JIANG J S, ZHENG Y Y, GAO S B, et al. Genesis of Chazangcuo Cu-Pb-Zn deposit, Tibet: Constraints from C-H-O-S-Pb isotope geochemistry[J]. Earth Science, 2015, 40(6): 1006-1016. (in Chinese with English abstract)
    [22]
    刘文均, 卢家烂. 湘西下寒武统有机地化特征: MVT铅锌矿床有机成矿作用研究[J]. 沉积学报, 2000, 18(2): 290-297.

    LIU W J, LU J L. Characteristics of organic geochemistry of Lower Cambrian in western Hunan: Mineralization study on MVT lead-zinc ore deposits[J]. Acta Sedimentologica Sinica, 2000, 18(2): 290-297. (in Chinese with English abstract)
    [23]
    于皓丞, 邱昆峰, 孙志佳, 等. 新疆阿合奇地区色帕巴衣铅矿床成因: 地质、地球化学研究的启示[J]. 地质科技情报, 2017, 36(2): 20-28.

    YU H C, QIU K F, SUN Z J, et al. Metallogenic model for the Sepabayi lead deposit in Akqi area, Xinjiang: Constraints from geology and geochemistry[J]. Geological Science and Technology Information, 2017, 36(2): 20-28. (in Chinese with English abstract)
    [24]
    郎兴海, 邓煜霖, 王旭辉, 等. 西藏雄村矿区Ⅲ号矿体硫、铅同位素特征及成矿物质来源[J]. 地质科技情报, 2018, 37(4): 1-9.

    LANG X H, DENG Y L, WANG X H, et al. Geochemical characteristics of sulfur and lead isotope compositions and implications for the sources of metals from No. Ⅲ ore body in Xiongcun Mining area, Tibet[J]. Geological Science and Technology Information, 2018, 37(4): 1-9. (in Chinese with English abstract)
    [25]
    徐书奎. 豫西寺家沟金矿床氢氧硫同位素特征及地质意义[J]. 地质科技情报, 2017, 36(5): 143-147.

    XU S K. Hydrogen, oxygen and sulfur isotopic characteristics and geological significance of Sijiagou gold deposit, western Henan[J]. Geological Science and Technology Information, 2017, 36(5): 143-147. (in Chinese with English abstract)
    [26]
    李振红, 赵亚辉, 周厚祥, 等. 硫同位素地质特征及其在湖南省铜矿床成矿物质来源示踪中的应用[J]. 华南地质与矿产, 2018, 34(1): 72-77.

    LI Z H, ZHAO Y H, ZHOU H X, et al. Sulfur isotopic characteristics of copper deposits in Hunan Province[J]. Geology and Mineral Resources of South China, 2018, 34(1): 72-77. (in Chinese with English abstract)
    [27]
    OHMOTO H, RYE R D. Isotopes of sulfur and carbon[C]//Barnes H L. Geochemistry of hydrothermal ore deposits: 2nd Edition. New York: John Wiley and Sons, 1979: 509-567.
    [28]
    龚志愚, 赵生贵, 姜志勇, 等. 高罗背斜铅锌矿基本特征和找矿标志[J]. 资源环境与工程, 2012, 26(6): 576-581.

    GONG Z Y, ZHAO S G, JIANG Z Y, et al. Basic characteristics and prospecting criteria of lead-zinc mine in Gaoluo anticline[J]. Resources Environment & Engineering, 2012, 26(6): 576-581. (in Chinese with English abstract)
    [29]
    彭能立, 梁恩云, 刘伟, 等. 湘西北洛塔矿田铅锌矿床与典型MVT铅锌矿床的对比研究[J]. 南方金属, 2014(4): 5-14.

    PENG N L, LIANG E Y, LIU W, et al. A comparative study of Luota Ore Field lead-zinc deposits in the Northwest of Hunan Province with typical MVT lead-zinc deposits[J]. Southern Metals, 2014(4): 5-14. (in Chinese with English abstract)
    [30]
    朱炳泉. 壳幔化学不均一性与块体地球化学边界研究[J]. 地学前缘, 1998(1): 73-83.

    ZHU B Q. Study on chemical heterogeneities of mantlecrustal systems and geochemical boundaries of blocks[J]. Earth Science Frontiers, 1998(1): 73-83. (in Chinese with English abstract)
    [31]
    ZARTMAN R E, DOE B R. Plumbotectonics: The model[J]. Tectonophysics, 1981, 75: 135-162. doi: 10.1016/0040-1951(81)90213-4
    [32]
    吴开兴, 胡瑞忠, 毕献武, 等. 矿石铅同位素示踪成矿物质来源综述[J]. 地质地球化学, 2002, 30(3): 73-81.

    WU K X, HU R Z, BI X W, et al. Ore lead isotopes as a tracer for ore-forming material sources: A review[J]. Geology-Geochemistry, 2002, 30(3): 73-81. (in Chinese with English abstract)
    [33]
    张海坤, 胡鹏, 曹亮, 等. 印度尼西亚戴里Sedex型铅锌矿集区成矿流体特征及成矿物质来源: 流体包裹体及同位素地球化学证据[J]. 地质科技通报, 2020, 39(3): 170-177. doi: 10.19509/j.cnki.dzkq.2020.0318

    ZHANG H K, HU P, CAO L, et al. Characteristics of mineralization fluids and mineralization material sources of the Sedex-type Dairi Pb-Zn ore concentration area in Indonesia: Evidence from fluid inclusions and isotopic geochemistry[J]. Bulletin of Geological Science and Technology, 2020, 39(3): 170-177. (in Chinese with English abstract) doi: 10.19509/j.cnki.dzkq.2020.0318
    [34]
    LI Z K, LI J W, ZHAO X F, et al. Crustal extension Ag-Pb-Zn veins in the Xiong'ershan district, southern North China Craton: Constraints from the Shagou deposit[J]. Economic Geology, 2013, 108: 1703-1729. doi: 10.2113/econgeo.108.7.1703
    [35]
    方喜林, 万传杰. 湖北恩施高罗地区矿产远景调查报告[R]. 武汉: 湖北省地质调查院, 2015.

    FANG X L, WAN C J. Investigation report on mineral prospecting in Gaoluo area, Enshi, Hubei Province[R]. Wuhan: Hubei Geological Survey, 2015. (in Chinese with English abstract)
    [36]
    罗华, 张旭, 何仁亮, 等. 湖北省1: 5万宣恩县、洗马坪、高罗、沙道沟幅区域地质调查报告[R]. 武汉: 湖北省地质调查院, 2015.

    LUO H, ZHANG X, HE R L, et al. 1: 50000 regional geological survey report of Xuan'en County, Ximaping, Gaoluo and Shadaogou in Hubei Province[R]. Wuhan: Hubei Geological Survey, 2015. (in Chinese with English abstract)
    [37]
    李朋, 吴龙, 杜小锋, 等. 湖北省1: 5万岳武坝、恩施县、见天坝、芭蕉、大集场幅区域地质调查报告[R]. 武汉: 湖北省地质调查院, 2017.

    LI P, WU L, DU X F, et al. 1: 50000 regional geological survey report of Yuewuba, Enshi County, Jiantianba, Bajiao and Dajichang in Hubei Province[R]. Wuhan: Hubei Geological Survey, 2015. (in Chinese with English abstract)
    [38]
    王晗昳, 何谋惷, 丁振举, 等. 湖南凤凰铅锌矿床成矿流体特征及成矿机制[J]. 地质科技通报, 2020, 39(6): 103-111. doi: 10.19509/j.cnki.dzkq.2020.0610

    WANG H Y, HE M C, DING Z J, et al. Ore-forming fluid characteristics and metallogenic mechanism of Fenghuang Pb-Zn deposit, Hunan Province[J]. Bulletin of Geological Science and Technology, 2020, 39(6): 103-111. (in Chinese with English abstract) doi: 10.19509/j.cnki.dzkq.2020.0610
    [39]
    韩培光, 吴冬妹, 彭小桂, 等. 宣恩县腾家湾铅锌矿基本特征、成矿规律与找矿意义[J]. 资源环境与工程, 2007, 21(2): 112-117.

    HAN P G, WU D M, PENG X G, et al. The Tengjiawan lead-zinc deposit in Xuan'en County of Hubei its features metallogenic pattern and propecting[J]. Resources Environment & Engineering, 2007, 21(2): 112-117. (in Chinese with English abstract)
    [40]
    马元, 祝敬明, 张汉金, 等. 扬子地台东北缘鄂西铅锌矿地质特征、成矿规律与找矿方向研究[R]. 武汉: 湖北省地质调查院, 2008.

    MA Y, ZHU J M, ZHANG H J, et al. Geological characteristics, metallogenic regularity and prospecting direction of Pb-Zn deposits in western Hubei, Northeast margin of Yangtze Platform[R]. Wuhan: Hubei Geological Survey, 2008. (in Chinese with English abstract)
    [41]
    彭能立, 刘伟, 梁恩云, 等. 湘西地区北洛塔和花垣铅锌矿田对比研究[J]. 地质找矿论丛, 2016, 31(2): 190-198.

    PENG N L, LIU W, LIANG E Y, et al. A comparative study of Luota and Huayuan lead-zinc ore field in the Northwest Hunan Province[J]. Contributions to Geology and Mineral Resources Research, 2016, 31(2): 190-198. (in Chinese with English abstract)
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