Volume 43 Issue 5
Sep.  2024
Turn off MathJax
Article Contents
SHAN Wenhao, WANG Lin, WU Xiang'en, YANG Yuqi, WANG Juhuizi, CAI Yuye. Kinetic characteristics of methane hydrate in functionalized multi-walled carbon nanotubes and L-leucine compounding system[J]. Bulletin of Geological Science and Technology, 2024, 43(5): 161-169. doi: 10.19509/j.cnki.dzkq.tb20230215
Citation: SHAN Wenhao, WANG Lin, WU Xiang'en, YANG Yuqi, WANG Juhuizi, CAI Yuye. Kinetic characteristics of methane hydrate in functionalized multi-walled carbon nanotubes and L-leucine compounding system[J]. Bulletin of Geological Science and Technology, 2024, 43(5): 161-169. doi: 10.19509/j.cnki.dzkq.tb20230215

Kinetic characteristics of methane hydrate in functionalized multi-walled carbon nanotubes and L-leucine compounding system

doi: 10.19509/j.cnki.dzkq.tb20230215
More Information
  • Author Bio:

    SHAN Wenhao, E-mail: 1774626776@qq.com

  • Corresponding author: WU Xiang'en, E-mail: 361724081@qq.com
  • Received Date: 20 Apr 2023
  • Accepted Date: 13 Jul 2023
  • Rev Recd Date: 06 Jul 2023
  • Objective

    Accelerated the generation of natural gas hydrate is crucial for advancing hydrate-based technologies such as gas storage, gas separation, and CO2 capture.

    Methods

    The kinetic characteristics of methane hydrate generated with the wB=0.05% functionalized (hydroxylated, carboxylated, and aminated) multi-walled carbon nanotubes(MWCNT) system, and in combination with the wB=1.0% L-leucine were investigated through constant temperature and constant volume methods.

    Results

    The combination of multiwalled carbon nanotubes and carboxylated and hydroxylated multiwalled carbon nanotubes with L-leucine, significantly reduced the induction time for natural gas hydrate nucleation to approximately 25, 22, and 13 minutes, respectively. This promotion effect is comparable to that of the typical promoter sodium dodecyl sulfate, and the promotion effect is better than that of a single additive system. The methane storage density of the compounded system reached 136-142 mg/g. Analysis of both the average and instantaneous methane uptake rates indicated that multiwalled carbon nanotubes had minimal impact on the growth kinetics of methane hydrate during the growth phase. The growth of methane hydrate in both the compounded and L-leucine systems were similar, characterized by a rapid increase in uptake rate to a peak value, followed by a rapid decrease and eventual completion of the growth phase.

    Conclusion

    A comprehensive analysis suggests that the combination of MWCNTs and L-leucine synergistically enhances the nucleation rate of methane hydrate, whereas the process and rate of the growth phase are predominantly influenced by L-leucine. This study presents a new idea for exploring the differentiation mechanism of different types of additives in enhancing the kinetics of methane hydrate generation.

     

  • The authors declare that no competing interests exist.
  • loading
  • [1]
    SLOAN E D, KOH C A. Clathrate hydrates of natural gases[M]. Boca Raton, FL: CRC Press, 2008.
    [2]
    BOSWELL R, COLLETT T S. Current perspectives on gas hydrate resources[J]. Energy & Environmental Science, 2011, 4(4): 1206-1215.
    [3]
    郁桂刚, 欧文佳, 吴翔, 等. 天然气水合物分解动力学研究进展[J]. 地质科技通报, 2023, 42(3): 175-188. doi: 10.19509/j.cnki.dzkq.tb20210668

    YU G G, OU W J, WU X, et al. Research advances on the dissociation dynamics of natural gas hydrates[J]. Bulletin of Geological Science and Technology, 2023, 42(3): 175-188. (in Chinese with English abstract) doi: 10.19509/j.cnki.dzkq.tb20210668
    [4]
    宁伏龙, 方翔宇, 李彦龙, 等. 天然气水合物开采储层出砂研究进展与思考[J]. 地质科技通报, 2020, 39(1): 137-148. doi: 10.19509/j.cnki.dzkq.2020.0115

    NING F L, FANG X Y, LI Y L, et al. Research status and perspective on wellbore sand production from hydrate reservoirs[J]. Bulletin of Geological Science and Technology, 2020, 39(1): 137-148. (in Chinese with English abstract) doi: 10.19509/j.cnki.dzkq.2020.0115
    [5]
    VELUSWAMY H P, WONG A J H, BABU P, et al. Rapid methane hydrate formation to develop a cost effective large scale energy storage system[J]. Chemical Engineering Journal, 2016, 290: 161-173. doi: 10.1016/j.cej.2016.01.026
    [6]
    BABU P, NAMBIAR A, HE T B, et al. A review of clathrate hydrate based desalination to strengthen energy-water nexus[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(7): 8093-8107.
    [7]
    LÜ Y N, WANG S S, SUN C Y, et al. Desalination by forming hydrate from brine in cyclopentane dispersion system[J]. Desalination, 2017, 413: 217-222. doi: 10.1016/j.desal.2017.03.025
    [8]
    BABU P, LINGA P, KUMAR R, et al. A review of the hydrate based gas separation(HBGS) process for carbon dioxide pre-combustion capture[J]. Energy, 2015, 85: 261-279. doi: 10.1016/j.energy.2015.03.103
    [9]
    LIU Y, GUO K H, LIANG D Q, et al. Effects of magnetic fields on HCFC-141b refrigerant gas hydrate formation[J]. Science in China Series B(Chemistry), 2003, 46(4): 407-415.
    [10]
    巫术胜, 肖睿, 黄冲, 等. 四丁基溴化铵水合物在空调蓄冷中的应用研究[J]. 制冷学报, 2006, 27(6): 48-51.

    WU S S, XIAO R, HUANG C, et al. Research on clathrate hydrate of tetra-n-butylammonium bromide as cold-storage material in air-conditioning[J]. Journal of Refrigeration, 2006, 27(6): 48-51. (in Chinese with English abstract)
    [11]
    ZHENG J J, CHONG Z R, QURESHI M F, et al. Carbon dioxide sequestration via gas hydrates: A potential pathway toward decarbonization[J]. Energy & Fuels, 2020, 34(9): 10529-10546.
    [12]
    MIMACHI H, TAKAHASHI M, TAKEYA S, et al. Effect of long-term storage and thermal history on the gas content of natural gas hydrate pellets under ambient pressure[J]. Energy & Fuels, 2015, 29(8): 4827-4834.
    [13]
    VELUSWAMY H P, KUMAR A, SEO Y, et al. A review of solidified natural gas(SNG) technology for gas storage via clathrate hydrates[J]. Applied Energy, 2018, 216: 262-285.
    [14]
    杨亮. 甲烷水合物生成的静态强化技术[D]. 广州: 华南理工大学, 2013.

    YANG L. Static enhancement technology of methane hydrate formation[D]. Guangzhou: South China University of Technology, 2013. (in Chinese with English abstract)
    [15]
    OHMURA R, KASHIWAZAKI S, SHIOTA S, et al. Structure-I and structure-H hydrate formation using water spraying[J]. Energy & Fuels, 2002, 16(5): 1141-1147.
    [16]
    邵子越, 申小冬, 李延霞, 等. 生物胶对二氧化碳水合物生成动力学影响实验研究[J]. 低碳化学与化工, 2023, 48(2): 155-161.

    SHAO Z Y, SHEN X D, LI Y X, et al. Experimental study of influence of biological gums on formation kinetics of carbon dioxide hydrates[J]. Low-Carbon Chemistry and Chemical Engineering, 2023, 48(2): 155-161. (in Chinese with English abstract)
    [17]
    KUMAR A, BHATTACHARJEE G, KULKARNI B D, et al. Role of surfactants in promoting gas hydrate formation[J]. Industrial & Engineering Chemistry Research, 2015, 54(49): 12217-12232.
    [18]
    WANG F, LIU G Q, MENG H L, et al. Improved methane hydrate formation and dissociation with nanosphere-based fixed surfactants As promoters[J]. ACS Sustainable Chemistry & Engineering, 2016, 4(4): 2107-2113.
    [19]
    LO C, ZHANG J S, SOMASUNDARAN P, et al. Investigations of surfactant effects on gas hydrate formation via infrared spectroscopy[J]. Journal of Colloid and Interface Science, 2012, 376(1): 173-176.
    [20]
    BHATTACHARJEE G, LINGA P. Amino acids as kinetic promoters for gas hydrate applications: A mini review[J]. Energy & Fuels, 2021, 35(9): 7553-7571.
    [21]
    VELUSWAMY H P, KUMAR A, KUMAR R, et al. An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application[J]. Applied Energy, 2017, 188: 190-199.
    [22]
    LIU Y, CHEN B Y, CHEN Y L, et al. Methane storage in a hydrated form as promoted by leucines for possible application to natural gas transportation and storage[J]. Energy Technology, 2015, 3(8): 815-819.
    [23]
    SHANKER PANDEY J, JOULJAMAL DAAS Y, PAUL KARCZ A, et al. Methane hydrate formation behavior in the presence of selected amino acids[J]. Journal of Physics(Conference Series), 2020, 1580(1): 012003.
    [24]
    VELUSWAMY H P, LEE P Y, PREMASINGHE K, et al. Effect of biofriendly amino acids on the kinetics of methane hydrate formation and dissociation[J]. Industrial & Engineering Chemistry Research, 2017, 56(21): 6145-6154.
    [25]
    PRASAD P S R, SAI KIRAN B. Clathrate hydrates of greenhouse gases in the presence of natural amino acids: Storage, transportation and separation applications[J]. Scientific Reports, 2018, 8(1): 8560.
    [26]
    NASHED O, PARTOON B, LAL B, et al. Review the impact of nanoparticles on the thermodynamics and kinetics of gas hydrate formation[J]. Journal of Natural Gas Science and Engineering, 2018, 55: 452-465.
    [27]
    RAHMATI-ABKENAR M, MANTEGHIAN M, PAHLAVANZADEH H. Experimental and theoretical investigation of methane hydrate induction time in the presence of triangular silver nanoparticles[J]. Chemical Engineering Research and Design, 2017, 120: 325-332.
    [28]
    PAHLAVANZADEH H, REZAEI S, KHANLARKHANI M, et al. Kinetic study of methane hydrate formation in the presence of copper nanoparticles and CTAB[J]. Journal of Natural Gas Science and Engineering, 2016, 34: 803-810.
    [29]
    ALIABADI M, RASOOLZADEH A, ESMAEILZADEH F, et al. Experimental study of using CuO nanoparticles as a methane hydrate promoter[J]. Journal of Natural Gas Science and Engineering, 2015, 27: 1518-1522.
    [30]
    ABDI-KHANGHAH M, ADELIZADEH M, NASERZADEH Z, et al. Methane hydrate formation in the presence of ZnO nanoparticle and SDS: Application to transportation and storage[J]. Journal of Natural Gas Science and Engineering, 2018, 54: 120-130.
    [31]
    CHARI V D, SHARMA D V S G K, PRASAD P S R, et al. Methane hydrates formation and dissociation in nano silica suspension[J]. Journal of Natural Gas Science and Engineering, 2013, 11: 7-11.
    [32]
    PARK S S, LEE S B, KIM N J. Effect of multi-walled carbon nanotubes on methane hydrate formation[J]. Journal of Industrial and Engineering Chemistry, 2010, 16(4): 551-555.
    [33]
    GOVINDARAJ V, MECH D, PANDEY G, et al. Kinetics of methane hydrate formation in the presence of activated carbon and nano-silica suspensions in pure water[J]. Journal of Natural Gas Science and Engineering, 2015, 26: 810-818.
    [34]
    KIM N J, PARK S S, KIM H T, et al. A comparative study on the enhanced formation of methane hydrate using CM-95 and CM-100 MWCNTs[J]. International Communications in Heat and Mass Transfer, 2011, 38(1): 31-36.
    [35]
    WANG F, LUO S J, FU S F, et al. Methane hydrate formation with surfactants fixed on the surface of polystyrene nanospheres[J]. Journal of Materials Chemistry A, 2015, 3(16): 8316-8323.
    [36]
    KAKATI H, MANDAL A, LAIK S. Promoting effect of Al2O3/ZnO-based nanofluids stabilized by SDS surfactant on CH4++C2H6+C3H8 hydrate formation[J]. Journal of Industrial and Engineering Chemistry, 2016, 35: 357-368.
    [37]
    WANG F, MENG H L, GUO G, et al. Methane hydrate formation promoted by-SO3--coated graphene oxide anosheets[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(8): 6597-6604.
    [38]
    张雪艳, 周诗岽, 姬浩洋, 等. 氧化石墨烯/纳米石墨颗粒与SDS复配对CO2水合物生成特性的影响[J]. 天然气化工(C1化学与化工), 2021, 46(2): 53-58.

    ZHANG X Y, ZHOU S D, JI H Y, et al. Effect of GO/GN and SDS compound system on formation characteristics of CO2 hydrate[J]. Natural Gas Chemical Industry(C1 Chemistry and Chemical Engineering), 2021, 46(2): 53-58. (in Chinese with English abstract)
    [39]
    PENG D Y, ROBINSON D B. A new two-constant equation of state[J]. Industrial & Engineering Chemistry Fundamentals, 1976, 15(1): 59-64.
    [40]
    CASCO M E, SILVESTRE-ALBERO J, RAMÍREZ-CUESTA A J, et al. Methane hydrate formation in confined nanospace can surpass nature[J]. Nature Communications, 2015, 6: 6432.
    [41]
    DENNING S, MAJID A A A, LUCERO J M, et al. Methane hydrate growth promoted by microporous zeolitic imidazolate frameworks ZIF-8 and ZIF-67 for enhanced methane storage[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(27): 9001-9010.
    [42]
    NGUYEN N N, NGUYEN A V. Hydrophobic effect on gas hydrate formation in the presence of additives[J]. Energy & Fuels, 2017, 31: 10311-10323.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article Views(171) PDF Downloads(38) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return