Citation: | SHU Zhiguo, SHU Yi, CHEN Miankun, PENG Wei, LIU Haotian, XIAO Xiong. Lithofacies heterogeneity and reservoir pore development characteristics of continental shale: A case study of the Dongyuemiao shale of the Ziliujing Formation in the Sichuan Basin[J]. Bulletin of Geological Science and Technology, 2024, 43(2): 1-15. doi: 10.19509/j.cnki.dzkq.tb20220446 |
After the exploration break through of the Well Fuye 10 in the Fuxing area of the Sichuan Basin, shale oil and gas from the Dongyuemiao section of the Jurassic Ziliujing Formation showed good exploration potential. The Dongyuemiao shale is characterized by unique shell limestone interlayers, high clay mineral content (up to 60%), various reservoir pore types, and strong vertical heterogeneity.
Taking the Well Xingye X as an example, combined with logging data, core observation, argon ion polishing scanning electron microscopy (SPE), and other technical means, the lithofacies characteristics and pore development characteristics of continental shale in the Dongyuemiao section were emphatically analysed.
In this study, the principle of continental shale lithofacies division of "interlayer+mineral three-terminalelements" was established, and the continental shale of the Dongyuemiao section was vertically divided into 6 lithofacies: shell rhythmic mixed shale facies, silt shell interbedded clay shale facies, silt lithic interbedded mixed shale facies, lithic limestone facies, lithic interbedded mixed shale facies, and lithic interbedded clay shale facies. Through argon ion polishing and scanning electron microscopy (SEM), it was found that this set of continental shale mainly develops special complex organic clay pores, of which the lithic interbedded clay shale facies was the most developed type of organic pore, while the lithic limestone facies organic pores were not developed, mainly develop intragranular dissolved pores. The mercury intrusion nitrogen adsorption joint measurement results revealed that there was no significant difference in the pore size distribution of the six lithofacies shales.
Comprehensive analysis revealed that the interaction between organic matter and clay minerals during the diagenetic evolution process was the main factor influencing the pore development of continental shale in the Dongyuemiao section.
[1] |
贾承造, 邹才能, 李建忠, 等. 中国致密油评价标准、主要类型、基本特征及资源前景[J]. 石油学报, 2012, 33(3): 343-350. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201203000.htm
JIA C Z, ZOU C N, LI J Z, et al. Evaluation criteria, main types, basic characteristics and resource prospects of tight oil in China[J]. Journal of Petroleum, 2012, 33(3): 343-350. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201203000.htm
|
[2] |
张林晔, 李钜源, 李政, 等. 北美页岩油气研究进展及对中国陆相页岩油气勘探的思考[J]. 地球科学进展, 2014, 29(6): 700-711. https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ201406008.htm
ZHANG L Y, LI J Y, LI Z, et al. Research progress of shale oil and gas in North America and consideration on continental shale oil and gas exploration in China[J] Progress in Earth Science, 2014, 29(6): 700-711. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ201406008.htm
|
[3] |
黎茂稳, 金之钧, 董明哲, 等. 陆相页岩形成演化与页岩油富集机理研究进展[J]. 石油实验地质, 2020, 42(4): 489-505. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD202004004.htm
LI M W, JIN Z J, DONG M Z, et al. Research progress on formation and evolution of continental shale and shale oil enrichment mechanism[J]. Petroleum Experimental Geology, 2020, 42(4): 489-505. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD202004004.htm
|
[4] |
金之钧, 王冠平, 刘光祥, 等. 中国陆相页岩油研究进展与关键科学问题[J]. 石油学报, 2021, 42(7): 821-835. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB202107001.htm
JIN Z J, WANG G P, LIU G X, et al. Research progress and key scientific issues of continental shale oil in China[J]. Journal of Petroleum, 2021, 42(7): 821-835. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB202107001.htm
|
[5] |
傅成玉. 非常规油气资源勘探开发[M]. 北京: 中国石化出版社, 2015.
FU C Y. Exploration and development of unconventional oil and gas resources[M] Beijing: SINOPEC Press, 2015. (in Chinese)
|
[6] |
孙焕泉, 周德华, 赵培荣, 等. 中国石化地质工程一体化发展方向[J]. 油气藏评价与开发, 2021, 11(3): 269-280. https://www.cnki.com.cn/Article/CJFDTOTAL-KTDQ202103001.htm
SUN H Q, ZHOU D H, ZHAO P R, et al. Development direction of SINOPEC geological engineering integration[J]. Oil and Gas Reservoir Evaluation and Development, 2021, 11(3): 269-280. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-KTDQ202103001.htm
|
[7] |
BOHACS K M, CARROLL A R, NEAL J E, et al. Lake-basin type, source potential, and hydrocarbon character: An integrated sequence stratigraphic geochemical framework[J]. AAPG Studies in Geology, 2000, 46: 3-34.
|
[8] |
CHAMBERLAIN C P, WAN X, GRAHAM S A, et al. Stable isotopic evidence for climate and basin evolution of the Late Cretaceous Songliao Basin, China[J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2013, 385(3): 106-124.
|
[9] |
DOEBBERT A C, CARROLL A R, MULCH A, et al. Geomorphic controls on lacustrine isotopic compositions: Evidence from the Laney Member, Green River Formation, Wyoming[J]. Geological Society of America Bulletin, 2010, 122: 236-252. doi: 10.1130/B26522.1
|
[10] |
马义权, 刘惠民, 张守鹏, 等. 济阳坳陷细粒混积岩类型与湖盆演化的耦合关系[J]. 地球科学, 2020, 45(10): 3633-3644. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX202010010.htm
MA Y Q, LIU H M, ZHANG S P, et al. Coupling relationship between types of fine-grained migmatites and lake basin evolution in Jiyang Depression[J] Earth Science, 2020, 45(10): 3633-3644. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX202010010.htm
|
[11] |
付小平, 杨滔. 川东北地区下侏罗统自流井组陆相页岩储层孔隙结构特征[J]. 石油实验地质, 2021, 43(4): 589-598. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD202104005.htm
FU X P, YANG T. Pore structure characteristics of continental shale reservoir of Lower Jurassic Ziliujing Formation in Northeast Sichuan[J] Petroleum Experimental Geology, 2021, 43(4): 589-598. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD202104005.htm
|
[12] |
张顺, 刘惠民, 王永诗, 等. 陆相页岩储集空间微观组合类型及成因[J]. 地质评论, 2019, 65(4): 203-204. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP2019S1099.htm
ZHANG S, LIU H M, WANG Y S, et al. Types and genesis of spatial micro assemblages of continental shale reservoirs[J]. Geological Review, 2019, 65(4): 203-204. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP2019S1099.htm
|
[13] |
俞雨溪, 罗晓容, 雷裕红, 等. 陆相页岩孔隙结构特征研究: 以鄂尔多斯盆地延长组页岩为例[J]. 天然气地球科学, 2016, 27(4): 716-726. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201604017.htm
YU Y X, LUO X R, LEI Y H, et al. Study on pore structure characteristics of continental shale: Taking shale of Yanchang Formation in Ordos Basin as an example[J]. Natural Gas Geoscience, 2016, 27(4): 716-726. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201604017.htm
|
[14] |
郭旭升, 赵永强, 张文涛, 等. 四川盆地元坝地区千佛崖组页岩油气富集特征与主控因素[J]. 石油实验地质, 2021, 43(5): 749-757. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD202105004.htm
GUO X S, ZHAO Y Q, ZHANG W T, et al. Oil and gas enrichment characteristics and main controlling factors of Qianfoya Formation shale in Yuanba area, Sichuan Basin[J]. Petroleum Experimental Geology, 2021, 43(5): 749-757. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD202105004.htm
|
[15] |
LOUCKS R G, RUPPEL S C. Mississippian Barnett shale: Lithofacies and depositional setting of a deep-water shale-gas succession in the Fort Worth Basin, Texas[J]. AAPG Bulletin, 2007, 91(4): 579-601. doi: 10.1306/11020606059
|
[16] |
MITRA A, WARRINGTON D S, SOMMER A. Application of lithofacies models to characterize unconventional shale gas reservoirs and identify optimal completion intervals: SPE 2010[A]//Anon. Proceedings of SPE Western Regional Meeting in Anaheim[C]. [S. l.]: SPE, 2010: 132513.
|
[17] |
MICHALZIK D. Lithofacies, diagenetic spectra and sedimentary cycles of Messinian(Late Miocene) evaporites in SE Spain[J]. Sedimentary Geology, 1996, 106(3): 203-222.
|
[18] |
WANG G C, CARR T R. Marcellus shale lithofacies prediction by multiclass neural network classification in the Appalachian Basin[J]. Mathematical Geosciences, 2012, 44(8): 975-1004. doi: 10.1007/s11004-012-9421-6
|
[19] |
BRUNER K R, WALKER-MILANI M, SMOSNA R. Lithofacies of the Devonian Marcellus shale in the eastern Appalachian Basin, U.S. A[J]. Journal of Sedimentary Research, 2015, 85: 937-954. doi: 10.2110/jsr.2015.62
|
[20] |
CLARKSON C R, SOLANO N, BUSTIN R M, et al. Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion[J]. Fuel, 2013, 103(1): 606-616.
|
[21] |
CURTIS M E, CARDOTT B J, SONDERGELD C H, et al. Development of organic porosity in the Woodford Shale with increasing thermal maturity[J]. International Journal of Coal Geology, 2012, 103: 26-31. doi: 10.1016/j.coal.2012.08.004
|
[22] |
CHALMERS G R, BUSTIN R M, POWER I M. Characterization of gas shale pore systems by porosimetry, pycnometry, surface area, and field emission scanning electron microscopy/transmission electron microscopy image analyses: Examples from the Barnett, Woodford, Haynesville, Marcellus, and Doig Units[J]. AAPG Bulletin, 2012, 96(6): 1099-1119. doi: 10.1306/10171111052
|
[23] |
SHU Y, LU Y H, HU Q H, et al. Geochemical, petrographic and reservoir characteristics of the transgressive systems tract of Lower Silurian black shale in Jiaoshiba area, southwest China[J]. Marine and Petroleum Geology, 2021, 129: 105014. doi: 10.1016/j.marpetgeo.2021.105014
|
[24] |
杨巍, 陈国俊, 吕成福, 等. 鄂尔多斯盆地东南部延长组长7段富有机质页岩孔隙特征[J]. 天然气地球科学, 2015, 26(3): 418-426. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201503004.htm
YANG W, CHEN G J, LÜ C F, et al. Pore characteristics of organic rich shale in Chang 7 Member of Yanchang Formation in the southeast of Ordos Basin[J]. Natural Gas Geoscience, 2015, 26(3): 418-426. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201503004.htm
|
[25] |
王香增, 刘国恒, 黄志龙, 等. 鄂尔多斯盆地东南部延长组长7段泥页岩储层特征[J]. 天然气地球科学, 2015, 26(7): 1385-1394. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201507022.htm
WANG X Z, LIU G H, HUANG Z L, et al. Characteristics of shale reservoirs in Chang 7 Member of Yanchang Formation in the southeast of Ordos Basin[J] Natural Gas Geoscience, 2015, 26(7): 1385-1394. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201507022.htm
|
[26] |
王香增, 范柏江, 张丽霞, 等. 陆相页岩气的储集空间特征及赋存过程: 以鄂尔多斯盆地陕北斜坡构造带延长探区延长组长7段为例[J]. 石油与天然气地质, 2015, 36(4): 651-659. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201504016.htm
WANG X Z, FAN B J, ZHANG L X, et al Reservoir space characteristics and occurrence process of continental shale gas: Take Chang 7 Member of Yanchang exploration area of Shanbei slope structural belt in Ordos Basin as an example[J] Oil and Gas Geology, 2015, 36(4): 651-659. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201504016.htm
|
[27] |
王香增, 张丽霞, 李宗田, 等. 鄂尔多斯盆地延长组陆相页岩孔隙类型划分方案及其油气地质意义[J]. 石油与天然气地质, 2016, 37(1): 1-7. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201601002.htm
WANG X Z, ZHANG L X, LI Z T, et al. Pore type classification scheme of continental shale of Yanchang Formation in Ordos Basin and its petroleum geological significance[J] Oil and Gas Geology, 2016, 37(1): 1-7. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201601002.htm
|
[28] |
康积伦, 王家豪, 马强, 等. 准噶尔盆地吉木萨尔凹陷芦草沟组细粒湖底扇沉积及其页岩油储层意义[J]. 地质科技通报, 2022, 41(5): 82-93. doi: 10.19509/j.cnki.dzkq.2022.0074
KANG J L, WANG J H, MA Q, et al. Fine-grain sublacustrine fan deposits and their significance of shale oil reservoirs in the Lucaogou Formation in Jimusar Sag, Junggar Basin[J]. Bulletin of Geological Science and Technology, 2022, 41(5): 82-93. (in Chinese with English abstract) doi: 10.19509/j.cnki.dzkq.2022.0074
|
[29] |
曾宏斌, 王芙蓉, 罗京, 等. 基于低温氮气吸附和高压压汞表征潜江凹陷盐间页岩油储层孔隙结构特征[J]. 地质科技通报, 2021, 40(5): 242-252. doi: 10.19509/j.cnki.dzkq.2021.0022
ZENG H B, WANG F R, LUO J, et al. Characterization of pore structure characteristics of intersalt shale oil reservoirs in Qianjiang Sag based on low-temperature nitrogen adsorption and high-pressure mercury injection[J]. Bulletin of Geological Science and Technology, 2021, 40(5): 242-252. (in Chinese with English abstract) doi: 10.19509/j.cnki.dzkq.2021.0022
|
[30] |
蔡振家, 雷裕红, 罗晓容, 等. 鄂尔多斯盆地东南部延长组7段页岩有机孔发育特征及其影响因素[J]. 石油与天然气地质, 2020, 41(2): 367-379. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202002014.htm
CAI Z J, LEI Y H, LUO X R, et al. Development characteristics and influencing factors of organic pores in shale of Member 7 of Yanchang Formation in the southeast of Ordos Basin[J]. Petroleum and Natural Gas Geology, 2020, 41(2): 367-379. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202002014.htm
|
[31] |
胡文瑄, 姚素平, 陆现彩, 等. 典型陆相页岩油层系成岩过程中有机质演化对储集性的影响[J]. 石油与天然气地质, 2019, 40(5): 947-956. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201905001.htm
HU W X, YAO S P, LU X C, et al. The influence of organic matter evolution on reservoir property during diagenesis of typical continental shale oil layer series[J]. Petroleum and Natural Gas Geology, 2019, 40(5): 947-956. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201905001.htm
|
[32] |
高凤琳, 宋岩, 梁志凯, 等. 陆相页岩有机质孔隙发育特征及其成因: 以松辽盆地长岭断陷沙河子组页岩为例[J]. 石油学报, 2019, 40(9): 1030-1044. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201909002.htm
GAO F L, SONG Y, LIANG Z K, et al. Pore development characteristics and genesis of organic matter in continental shale: Taking Shahezi Formation shale in Changling fault depression of Songliao Basin as an example[J]. Journal of Petroleum, 2019, 40(9): 1030-1044. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201909002.htm
|
[33] |
曹香妮, 姜振学, 朱德宇, 等. 川东北地区自流井组陆相页岩岩相类型及储层发育特征[J]. 天然气地球科学, 2019, 30(12): 1782-1793. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201912012.htm
CAO X N, JIANG Z X, ZHU D Y, et al. Lithofacies types and reservoir development characteristics of continental shale of Ziliujing Formation in northeastern Sichuan[J]. Natural Gas Geoscience, 2019, 30(12): 1782-1793. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201912012.htm
|
[34] |
姜涛, 金之均, 刘光祥, 等. 四川盆地元坝地区自流井组页岩储层孔隙结构特征[J]. 2021, 42(4): 909-918.
JIANG T, JIN Z J, LIU G X, et al. Pore structure characteristics of Ziliujing Formation shale reservoir in Yuanba area, Sichuan Basin[J] 2021, 42(4): 909-918. (in Chinese with English abstract)
|
[35] |
刘忠宝, 胡宗全, 刘光祥, 等. 陆相页岩源-储耦合特征及发育模式: 以四川盆地侏罗系自流井组为例[J]. 2021, 27(3): 271-280.
LIU Z B, HU Z Q, LIU G X, et al. Source reservoir coupling characteristics and development mode of continental shale: Take the Jurassic Ziliujing Formation in Sichuan Basin as an example[J] 2021, 27(3): 271-280. (in Chinese with English abstract)
|
[36] |
CAO T T, SONG Z G, WANG S B, et al. Characteristics the pore structure in the Silurian and Permian shales of the Sichuan Basin, China[J]. Marine and Petroleum Geology, 2015, 61: 410-150.
|
[37] |
杨超, 张金川, 李婉君, 等. 辽河坳陷沙三、沙四段泥页岩微观孔隙特征及其成藏意义[J]. 石油与天然气地质, 2014, 35(2): 286-294. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201402020.htm
YANG C, ZHANG J C, LI W J, et al. Micro pore characteristics and reservoir forming significance of shales in the Third and Fourth Members of Shahejie Formation in Liaohe Depression[J]. Petroleum and Natural Gas Geology, 2014, 35(2): 286-294. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201402020.htm
|
[38] |
管全中, 董大忠, 王淑芳, 等. 海相和陆相页岩储层微观结构差异性分析[J]. 天然气地球科学, 2016, 27(3): 524-531. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201603019.htm
GUAN Q Z, DONG D Z, WANG S F, et al. Analysis of the difference between the microstructure of marine and continental shale reservoirs[J]. Natural Gas Geoscience, 2016, 27(3): 524-531. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201603019.htm
|
[39] |
EHRENBERG S N, WALDERHAUG O, BJERLYKKE K. Carbonate porosity creation bymesogenetic dissolution: Reality or illusion?[J]. AAPG Bulletin, 2012, 96(2): 217-225.
|
[40] |
LABANI M M, REZAEE R, SAEEDI A, et al. Evaluation of pore size spectrum of gas shale reservoirs using low pressure nitrogen adsorption, gas expansion and mercury porosimetry: A case study from the Perth and Canning Basins, western Australia[J]. Journal of Petroleum Science Engineering, 2013, 112: 7-16.
|
[41] |
LOUCKS R G, REED R M, RUPPEL S C, et al. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores[J]. AAPG Bulletin, 2012, 96(6): 1071-1098.
|
[42] |
汪虎, 何治亮, 张永贵, 等. 四川盆地海相页岩储层微裂缝类型及其对储层物性影响[J]. 石油与天然气地质, 2019, 40(1): 41-49. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201901006.htm
WANG H, HE Z L, ZHANG Y G, et al. Types of microfractures in marine shale reservoirs in Sichuan Basin and their effects on reservoir physical properties[J]. Petroleum and Natural Gas Geology, 2019, 40(1): 41-49. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201901006.htm
|
[43] |
ROSS D J K, MARC-BUSTIN R. The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs[J]. Marine and Petroleum Geology, 2009, 26: 916-927.
|
[44] |
DING W, LI C, LI C, et al. Fracture development in shale and its relationship to gas accumulation[J]. Geoscience Frontiers, 2012, 3(1): 97-105.
|
[45] |
舒志国, 周林, 李雄, 等. 四川盆地东部复兴地区侏罗系自流井组东岳庙段陆相页岩凝析气藏地质特征及勘探开发前景[J]. 石油与天然气地质, 2021, 42(1): 212-223. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202101019.htm
SHU Z G, ZHOU L, LI X, et al Geological characteristics and exploration and development prospects of continental shale condensate gas reservoirs in Dongyuemiao section of Jurassic Ziliujing Formation in Fuxing area, eastern Sichuan Basin[J]. Petroleum and Natural Gas Geology, 2021, 42(1): 212-223. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202101019.htm
|
[46] |
胡德高, 舒志国, 郭战峰, 等. 川东复兴地区侏罗系(涪页10HF井)发现国内首个页岩凝析气藏[J]. 中国地质, 2021, 48(6): 1980-1981. https://www.cnki.com.cn/Article/CJFDTOTAL-DIZI202106025.htm
HU D G, SHU Z G, GUO Z F, et al. Discovery of the first shale condensate gas reservoir in China in the Jurassic System (Well Fuye 10HF) in Fuxing area of eastern Sichuan[J]. Geology of China, 2021, 48(6): 1980-1981. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-DIZI202106025.htm
|
[47] |
蔡进功, 宋明水, 卢龙飞, 等. 烃源岩中有机黏粒复合体: 天然的生烃母质[J]. 海洋地质与第四纪地质, 2013, 33(3): 123-131. https://www.cnki.com.cn/Article/CJFDTOTAL-HYDZ201303017.htm
CAI J G, SONG M S, LU L F, et al. Organic clay particle complex in hydrocarbon source rock: Natural hydrocarbon generating parent material[J]. Marine Geology and Quaternary Geology, 2013, 33(3): 123-131. (in Chinese with English abstract) https://www.cnki.com.cn/Article/CJFDTOTAL-HYDZ201303017.htm
|
[48] |
王行信, 万玉兰. 有机黏土复合体在石油生成中的意义[J]. 中国海上油气, 1993, 7(2): 27-33.
WANG X X, WAN Y L. Significance of organic clay complex in petroleum generation[J]. China Offshore Oil and Gas, 1993, 7(2): 27-33. (in Chinese with English abstract)
|
[49] |
王行信, 蔡进功. 有机黏土复合体与油气[M]. 北京: 石油工业出版社, 2006.
WANG X X, CAI J G. Organic clay complex and oil and gas[M]. Beijing: Petroleum Industry Press, 2006. (in Chinese)
|
[50] |
余和中, 谢锦龙, 王行信, 等. 有机黏土复合体与油气生成[J]. 地学前缘, 2006, 13(4): 274-281.
YU H Z, XIE J L, WANG X X, et al. Organic clay complexes and hydrocarbon generation[J]. Geoscience Frontier, 2006, 13(4): 274-281. (in Chinese with English abstract)
|
[51] |
王行信. 用有机黏土化学研究生油理论[J]. 海相油气地质, 1996, 1(4): 33-39.
WANG X X. Study on oil generation theory by organic clay chemistry[J]. Marine Oil and Gas Geology, 1996, 1(4): 33-39. (in Chinese with English abstract)
|