CSCD来源期刊

北大中文核心期刊

中国科技核心期刊

地学领域高质量科技期刊分级T2区（2023）

世界期刊影响力指数报告Q1区（2023）

Volume 43 Issue 4
Jul.  2024
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Article Contents
Article Navigation >  Bulletin of Geological Science and Technology  > 2024  >  43(4): 128-140
ZHENG Xiaoxuan, TIAN Jixian, TIAN Cong, JIANG Zhengwen, YANG Lei, HE Qiufang, XUE Honglei. Evaluation of the characteristics of biogenic gas production based on the CDOM spectral characteristics of shales[J]. Bulletin of Geological Science and Technology, 2024, 43(4): 128-140. doi: 10.19509/j.cnki.dzkq.tb20230652
Citation: ZHENG Xiaoxuan, TIAN Jixian, TIAN Cong, JIANG Zhengwen, YANG Lei, HE Qiufang, XUE Honglei. Evaluation of the characteristics of biogenic gas production based on the CDOM spectral characteristics of shales[J]. Bulletin of Geological Science and Technology, 2024, 43(4): 128-140. doi: 10.19509/j.cnki.dzkq.tb20230652
shu

Evaluation of the characteristics of biogenic gas production based on the CDOM spectral characteristics of shales

doi: 10.19509/j.cnki.dzkq.tb20230652
  • 1.

    Chongqing Key Laboratory of Karst Environment, School of Geographic Sciences, Southwest University, Chongqing 400715, China

  • 2.

    Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China

  • 3.

    Research Institute of Exploration and Development, Qinghai Oilfield Company, PetroChina, Dunhuang Gansu 736202, China

  • 4.

    Yantai Penglai District Agricultural Technology Promotion Center, Yantai Shandong 265600, China

More Information
    Abstract
  • Objective

    The composition and degradability of dissolved organic matter (DOM) play a critical role in evaluating biogenic gas production during shale gas exploration. A simple and effective method needs to be developed to assess the composition, functional groups and microbial activity of DOM, which will provide crucial valuable information concerning the gas production mechanism in the field of biogenic shale gas.

    Methods

    Shale samples were collected from depths of 1 219 m to 1 309 m from the ST1 exploration well located at the edge of the Sebei No.1 gas field in the Qaidam Basin. According to the 3D fluorescence of the extraction and emission matrix (EEM) and the UV visible absorption spectrum characteristics of chromophoric dissolved organic matter (CDOM), the composition, functional group and degradation characteristics of CDOM were analysed to determine the distribution of methanol formation substrates.

    Results

    The DOM in the samples mainly consisted of the small molecular tryptophan-like fluorescent components C1 and C3, which are readily degradable by biotic processes and account for 70.54% of the total fluorescence intensity. The fluorescence components, fluorescence parameters (HIX, BIX), and absorbance ratios (E253/E203, SUVA254) confirmed that the core layers at depths of 1 219-1 222 m and 1 285-1 301 m were potential effective gas-generating formations. These layers contain low amounts of humified organic matter, weak aromaticity and high amounts of methanol functional groups. The active gas-generating formations are generally consistent with those in previous reports.

    Conclusion

    The results indicated that the CDOM spectrum is a valuable method for exploring the methanol formation substrate distribution and microbial activity. The CDOM-EEM method has the potential to serve as an effective indicator of the methanol formation characteristics of DOM in mud shale and provides an effective and essential way to assess geochemical-based gas production capacity in hydrocarbon source rocks.

     

    • The authors declare that no competing interests exist.
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    • References(68)
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