CSCD来源期刊

北大中文核心期刊

中国科技核心期刊

地学领域高质量科技期刊分级T2区（2023）

世界期刊影响力指数报告Q1区（2023）

Volume 43 Issue 3
May  2024
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Article Contents
Article Navigation >  Bulletin of Geological Science and Technology  > 2024  >  43(3): 36-47
LI Man, ZHANG Wei, LIAO Yuzhong, LIU Feng, WEI Shuaichao, HE Yujiang. Characteristics and mechanisms of fluorine enrichment in the geothermal water of south central Shandong Province[J]. Bulletin of Geological Science and Technology, 2024, 43(3): 36-47. doi: 10.19509/j.cnki.dzkq.tb20230706
Citation: LI Man, ZHANG Wei, LIAO Yuzhong, LIU Feng, WEI Shuaichao, HE Yujiang. Characteristics and mechanisms of fluorine enrichment in the geothermal water of south central Shandong Province[J]. Bulletin of Geological Science and Technology, 2024, 43(3): 36-47. doi: 10.19509/j.cnki.dzkq.tb20230706
shu

Characteristics and mechanisms of fluorine enrichment in the geothermal water of south central Shandong Province

doi: 10.19509/j.cnki.dzkq.tb20230706
  • 1.

    Institute of Hydrogeology and Environmental Geology, CAGS, Shijiazhuang 050061, China

  • 2.

    Technology Innovation Center of Geothermal & Hot Dry Rock Exploration and Development, Ministry of Natural Resources, Shijiazhuang 050061, China

More Information
    Abstract
  • Objective

    Yishu fault zone geothermal field and central Shandong uplift geothermal field are typical geothermal fields in south central Shandong Province. In order to investigated the distribution characteristics and mechanisms of fluorine enrichment in the geothermal water of the this area,

    Methods

    hydrochemical diagrams, geochemical simulations and principal component analysis were employed.

    Results

    The results show that the geothermal water in the study area is mainly Na-Ca-Cl-, Na-Ca-SO4-Cl- and Na-Cl-SO4-type water, dominated by weakly alkaline water. The predominant cation is the sodium ion, with fluorine concentration between 0.38 and 4.5 mg/L. Sodium-rich and weakly alkaline environments are faciliated to the enrichment of fluorine in the geothermal water. The fluorine concentration has significant positive correlations with the Na+, Cl- and TDS concentrations in the geothermal water. In addition, it has significant positive correlations with K+ and SO42- concentrations and significant negative correlations with Mg2+ and HCO3- concentrations in the geothermal water in the Yishu fault zone. The cation exchange effect in the geothermal water of the central Shandong uplift zone is stronger than that in the Yishu fault zone, and the reaction strength of Na+ is significantly stronger than that of Mg2+. The geothermal field of the central Shandong uplift and Yishu fault zones are both fracturing types. The thermal storage lithologies are limestone, limestone in the thermal alteration zone and ansanite in the broken belt, with strong water-rock interactions. The provenance of fluorine in the geothermal water is the dissolution reprecipitation of fluorine-containing minerals, and the fluorine concentration in the geothermal water is further increased by cation exchange and other water-rock interactions. High temperature and sodium-rich have a great influence on fluorine enrichment.

    Conclusion

    This research provides a reference for the exploitation and utilization of geothermal resources.

     

    • The authors declare that no competing interests exist.
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